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Research on Chemical Intermediates

, Volume 46, Issue 1, pp 871–890 | Cite as

Synthesis and electrochemical capacitor characterization of new copolyimides containing thiazole ring and their composites with conductive polymer

  • Somaye Shahrivari
  • Elaheh KowsariEmail author
  • Abbas ShockraviEmail author
  • Ali Ehsani
Article
  • 35 Downloads

Abstract

In this research work, copolyimides (PIa,b) were synthesized by chemical routs. We used perylene-3,4,9,10-tetracarboxylic dianhydride and synthesized diamines (DAa,b) containing thiazole ring as monomers to obtain PIa,b which were characterized by 1HNMR and FTIR spectroscopies. We prepared POAP/PIa and POAP/PIb by depositing poly ortho amino phenol (POAP) as conductive polymer on the surface of PIa,b via in situ electropolymerization. To evaluate the effect of the PIa,b in terms of the electrochemical performance of composites, we used galvanostatic charge/discharge, cyclic voltammetry, and electrochemical impedance spectroscopy. The specific capacitance of 207.2 and 322.4 F/g are obtained for POAP/PIa and POAP/PIb, respectively. All these evidences prove that POAP/PI composites have long cycle life as well as high specific capacitance, which are indicative for being a good candidate in terms of application in supercapacitors.

Graphic abstract

Keywords

Thiazole diamine Copolyimides Supercapacitor POAP 

Notes

Acknowledgements

The authors wish to gratefully thank the Research Affairs Division at Amirkabir University of Technology (AUT, Iran) and Kharazmi University (KHU, Iran).

Supplementary material

11164_2019_3995_MOESM1_ESM.docx (1.1 mb)
Supplementary material 1 (DOCX 1157 kb)

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Copyright information

© Springer Nature B.V. 2019

Authors and Affiliations

  1. 1.Faculty of Chemistry, Department of Organic –Polymer ChemistryKharazmi UniversityTehranIran
  2. 2.Department of ChemistryAmirkabir University of TechnologyTehranIran
  3. 3.Department of Chemistry, Faculty of ScienceUniversity of QomQomIran

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