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Optimization of the transfer hydrogenation reaction of acetophenone on Ni@MOF-5 nanoparticles using response surface methodology

  • Azadeh Nemati Chelavi
  • Vahid Zare-Shahabadi
  • Soheil SayyahiEmail author
  • Hossein Anaraki-Ardakani
Article
  • 23 Downloads

Abstract

In this study, the transfer hydrogenation reduction of acetophenone using supported nickel on MOF as catalyst was investigated. BBD and RSM were employed to investigate the effect of the experimental parameters such as Ni content, catalyst content, temperature, and reaction time. Optimum reaction conditions for the formation of 1-phenylethanol were 45% mol of Ni content, 0.11 g of catalyst, reaction temperature at 83 °C, and reaction time 90 min. The catalyst was characterized by FESEM, EDX, FT-IR, XRD, and H2-TPR techniques. The catalyst-free reaction phase was analyzed by AAS, and fortunately, no leaching of nickel was detected.

Keywords

Transfer hydrogenation Ni@MOF-5 Acetophenone Experimental design 

Notes

Acknowledgements

We gratefully acknowledge the funding support received for this project from the Mahshahr Branch, Islamic Azad University, Iran.

Supplementary material

11164_2019_3959_MOESM1_ESM.docx (122 kb)
Supplementary material 1 (DOCX 122 kb)

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Copyright information

© Springer Nature B.V. 2019

Authors and Affiliations

  • Azadeh Nemati Chelavi
    • 1
  • Vahid Zare-Shahabadi
    • 1
  • Soheil Sayyahi
    • 1
    Email author
  • Hossein Anaraki-Ardakani
    • 1
  1. 1.Department of Chemistry, Mahshahr BranchIslamic Azad UniversityMahshahrIran

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