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Research on Chemical Intermediates

, Volume 45, Issue 5, pp 2869–2885 | Cite as

Relationship between (micro)structure and functional (photocatalytic and adsorption) properties of anatase–mordenite nanocomposite

  • Elena DomoroshchinaEmail author
  • Andrey Orekhov
  • Vladimir Chernyshev
  • Galina Kuz’micheva
  • Galina Kravchenko
  • Vera Klechkovskaya
  • Larisa Pirutko
Article
  • 18 Downloads

Abstract

Anatase–mordenite nanocomposite was synthesized in situ and characterized by X-ray diffraction analysis, Brunauer–Emmett–Teller measurements, infrared (IR) spectroscopy, electron diffraction measurements, energy-dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, and scanning and transmission electron microscopy. It was found that X-ray-amorphous anatase located in the zeolite micropores resulted in a decrease in the specific surface of anatase–mordenite compared to the initial mordenite. Anatase-containing nanoparticles in anatase–mordenite showed round shape and formed nano-associates and conglomerates. The water content in the zeolite cavities in anatase–mordenite was lower compared to mordenite. Anatase–mordenite nanocomposite exhibited higher photocatalytic activity in the model decomposition reaction of methyl orange under ultraviolet (UV) radiation and higher adsorption capacity for extraction of P(V) and As(V) ions from aqueous environment in the dark compared to the initial mordenite or anatase due to an increase in the content of active OH-groups on the nanocomposite surface compared to mordenite and an increase in the specific surface compared to anatase.

Keywords

Nanocomposite Microstructure X-ray diffraction Scanning/transmission electron microscopy Photocatalytic and adsorption properties 

Notes

Acknowledgements

The authors express their gratitude to the National Research Centre “Kurchatov Institute” and the Shared Research Center at IC for the opportunity to carry out the electron microscopy measurements, as well as ESRF for the access to ID22 station, experiment MA-3313. This work was supported by the Russian Academy of Sciences and Federal Agency of Scientific Organizations (project no. 0303-2016-0006), Ministry of Education and Science of the Russian Federation (grant no. RFMEFI61616X0069), and Russian Foundation for Basic Research (project no. 15-03-01289).

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Copyright information

© Springer Nature B.V. 2019

Authors and Affiliations

  1. 1.Federal State Budget Educational Institution of Higher Education«MIREA - Russian Technological University»MoscowRussia
  2. 2.Shubnikov Institute of Crystallography of Federal Scientific Research Centre ‘Crystallography and Photonics’Russian Academy of SciencesMoscowRussia
  3. 3.National Research Center ‘Kurchatov Institute’MoscowRussia
  4. 4.Lomonosov Moscow State UniversityMoscowRussia
  5. 5.Boreskov Institute of CatalysisNovosibirskRussia

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