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CeO2 promoting allyl alcohol synthesis from glycerol direct conversion over MoFe/CeO2 oxide catalysts: morphology and particle sizes dependent

  • Hai Lan
  • Jia Zeng
  • Biao Zhang
  • Yi Jiang
Article
  • 24 Downloads

Abstract

MoFe-N, MoFe/c–CeO2, MoFe/p1–CeO2, and MoFe/p2–CeO2 (where N, c, and p stand for non-supported, nanocube, and nanoparticle) oxide catalysts were designed for gas-glycerol direct catalytic conversion into allyl alcohol. The catalysts also were characterized by XRD, TEM, BET, H2-TPR, and NH3-TPD. Mo–Fe oxides were highly dispersed on the surface of c-CeO2 and p-CeO2 supports, different with the MoFe-N consist of crystalline Fe2(MoO4)3 and Fe2O3 crystalline phase. The support effect and special natural property of CeO2 significantly improve the allyl alcohol selectivity from gas-glycerol over MoFe/CeO2. The p-CeO2 with low particle sizes and crystalline degree was superior to high-crystalline nanocube c-CeO2 to promote its interaction with the MoFe oxide active components, and improve the surface acid site concentration and reducibility of MoFe/CeO2 as well as catalytic activity and stability for allyl alcohol synthesis from gas-glycerol without any extra hydrogen donors. Over the MoFe/p2–CeO2, the glycerol conversion reached 97.1%, and the selectivity of allyl alcohol, ethanol, propanoic acid, and acrylic acid were 23.3%, 8.6%, 12.6%, and 7.8%, respectively, yielding allyl alcohol of 22.6%.

Keywords

Mo–Fe oxides Allyl alcohol Glycerol CeO2 support effect Biomass resource 

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Copyright information

© Springer Nature B.V. 2018

Authors and Affiliations

  1. 1.Department of Applied Chemistry, School of Materials Science and EngineeringChongqing JiaoTong UniversityChongqingPeople’s Republic of China
  2. 2.Chengdu Institute of Organic ChemistryChinese Academy of ScienceChengduPeople’s Republic of China
  3. 3.Chongqing Academy of Environmental ScienceChongqingPeople’s Republic of China

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