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Fe3O4@PEG core/shell nanoparticles as magnetic nanocatalyst for acetylation of amines and alcohols using ultrasound irradiations under solvent-free conditions

  • Hojat Veisi
  • Ahmad Nikseresht
  • Afsaneh Rostami
  • Saba Hemmati
Article
  • 16 Downloads

Abstract

Ultrasound irradiation was used to prepare one-pot Fe3O4@PEG core/shell nanostructure for the first time. The morphology, structure, and physicochemical properties were specified by different analytical techniques including field emission scanning electron microscopy, Fourier transform infrared spectroscopy, energy-dispersive X-ray spectroscopy, transmission electron microscopy, X-ray powder diffraction, and vibrating sample magnetometer. For acetylation of phenols, alcohols, and amines, the synthesized Fe3O4@PEG core/shell nanoparticles were used as an efficient heterogeneous and green catalyst with acetic anhydride under sonication applying mild reaction conditions. Different electron-withdrawing and electron-donating substrates indicate a prominent yield of desired products with the merit of reusability of Fe3O4@PEG nanocatalyst and magnetic separation.

Graphical Abstract

Keywords

PEGylation Core/shell Magnetic Ultrasonic Acetylation Amine Alcohol 

Notes

Acknowledgements

We are thankful to Payame Noor University, Tehran, Iran, for partial support of this work.

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Copyright information

© Springer Nature B.V. 2018

Authors and Affiliations

  • Hojat Veisi
    • 1
  • Ahmad Nikseresht
    • 1
  • Afsaneh Rostami
    • 1
  • Saba Hemmati
    • 1
  1. 1.Department of ChemistryPayame Noor UniversityTehranIran

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