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New application of decaniobate salt as basic solid in the synthesis of 4H-pyrans by microwave assisted multicomponent reactions

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Abstract

This study focuses on the search of new applications of polyoxometalates known as decaniobate ions [Nb10O28]6−. The decaniobates can be used as basic solid catalysts in multicomponent reactions to obtain good yields to 4H-pyrans (> 95%) under microwave radiation and solvent-free conditions, using several aldehydes with different electron-withdrawing or electron donor substituents. The synthesis of (TMA)6 [Nb10O28]6H2O was performed following a simple protocol (HPNb), which was modified to decrease the number of hexaniobate species that are formed as impurities (HPNb-HF).

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Acknowledgements

We thank COLCIENCIAS for the financial support under Project No. 110965843004. EN, GPR and AGS thank to UNLP, CONICET, MYNCIT and ERANET-1.

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Authors and Affiliations

  1. Escuela de Ciencias Químicas, Facultad de Ciencias, Universidad Pedagógica y Tecnológica de Colombia UPTC, Avenida Central del Norte, Tunja, Boyacá, Colombia

    Luisa F. Gutierrez, Hugo A. Rojas, Jairo A. Cubillos & José J. Martínez

  2. Departamento de Química, Centro de Investigación y Desarrollo en Ciencias Aplicadas “Dr. J.J. Ronco” (CINDECA), Facultad de Ciencias Exactas, UNLP-CCT-CONICET, Calles 47 No 257, B1900 AJK, La Plata, Argentina

    Eliana Nope, Ángel G. Sathicq & Gustavo P. Romanelli

Authors
  1. Luisa F. Gutierrez
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  2. Eliana Nope
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  3. Hugo A. Rojas
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  4. Jairo A. Cubillos
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  5. Ángel G. Sathicq
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  6. Gustavo P. Romanelli
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  7. José J. Martínez
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Correspondence to Gustavo P. Romanelli or José J. Martínez.

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Gutierrez, L.F., Nope, E., Rojas, H.A. et al. New application of decaniobate salt as basic solid in the synthesis of 4H-pyrans by microwave assisted multicomponent reactions. Res Chem Intermed 44, 5559–5568 (2018). https://doi.org/10.1007/s11164-018-3440-y

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  • DOI: https://doi.org/10.1007/s11164-018-3440-y

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