Microwave-assisted hydrothermal synthesis of BiOCl/Bi2WO6 nanocomposites for the enhancement of photocatalytic efficiency

  • Phattranit DumrongrojthanathEmail author
  • Thankamon Saksoong
  • Panudda Patiphatpanya
  • Anukorn Phuruangrat
  • Somchai Thongtem
  • Titipun ThongtemEmail author


In this research, BiOCl/Bi2WO6 nanocomposites were successfully synthesized by a microwave-assisted hydrothermal method. Phase, morphology and optical properties of the as-synthesized products were investigated by X-ray powder diffraction, Raman spectroscopy, X-ray photoelectron spectroscopy, field emission scanning electron microscopy and photoluminescence (PL) spectroscopy. The as-synthesized products were BiOCl/Bi2WO6 nanocomposites composed of Bi2WO6 microflowers mixed with BiOCl nanoplates. The photocatalytic properties of BiOCl/Bi2WO6 nanocomposites were estimated through photodegradation of rhodamine B and salicylic acid as organic models in wastewater. The 80 wt% BiOCl/Bi2WO6 nanocomposites presented the highest photocatalytic efficiency and were certified for the lowest photonic emission by PL analysis. There was a trivial loss of activity even after four re-cycle tests. A mechanism for photocatalysis by BiOCl/Bi2WO6 nanocomposites was also proposed.


BiOCl/Bi2WO6 nanocomposites Microwave-assisted hydrothermal synthesis Photocatalysis 



We wish to thank Chiang Mai University (CMU) Thailand for financial support through the CMU Research Fund, and Center of Excellence in Materials Science and Technology, CMU for financial support under the administration of Materials Science Research Center, Faculty of Science, CMU, Thailand.


  1. 1.
    Y. Ma, Z. Chen, D. Qu, J. Shi, Appl. Surf. Sci. 361, 63 (2016)CrossRefGoogle Scholar
  2. 2.
    S. Wang, X. Yang, X. Zhang, X. Ding, Z. Yang, K. Dai, H. Chen, Appl. Surf. Sci. 391, 194 (2017)CrossRefGoogle Scholar
  3. 3.
    Z.S. Liu, B.T. Wu, J.N. Niu, P.Z. Feng, Y.B. Zhu, Mater. Res. Bull. 63, 187 (2015)CrossRefGoogle Scholar
  4. 4.
    T. Jiang, J. Li, Y. Gao, L. Li, T. Lu, L. Pan, J. Colloid Interface Sci. 490, 812 (2017)CrossRefGoogle Scholar
  5. 5.
    X.C. Song, W.T. Li, W.Z. Huang, H. Zhou, Y.F. Zheng, H.Y. Yin, Mater. Chem. Phys. 160, 251 (2015)CrossRefGoogle Scholar
  6. 6.
    P. Dumrongrojthanath, T. Thongtem, A. Phuruangrat, S. Thongtem, Superlattices Microstruct. 54, 71 (2013)CrossRefGoogle Scholar
  7. 7.
    P. Dumrongrojthanath, T. Thongtem, A. Phuruangrat, S. Thongtem, Mater. Lett. 154, 180 (2015)CrossRefGoogle Scholar
  8. 8.
    R. Sharma, Uma, S. Singh, A. Verma, M. Khanuja, J. Photochem. Photobiol. B Biol. 162, 266 (2016)CrossRefGoogle Scholar
  9. 9.
    C. Pan, J. Xu, Y. Chen, Y. Zhu, Appl. Catal. B 115–116, 314 (2012)CrossRefGoogle Scholar
  10. 10.
    K. Li, Y. Liang, J. Yang, Q. Gao, Y. Zhu, S. Liu, R. Xu, X. Wu, J. Alloys Compd. 695, 238 (2017)CrossRefGoogle Scholar
  11. 11.
    R. Li, H. Ren, W. Ma, S. Hong, L. Wu, Y. Huang, Catal. Commun. 106, 1 (2018)CrossRefGoogle Scholar
  12. 12.
    Z. Jiang, X. Liang, Y. Liu, T. Jing, Z. Wang, X. Zhang, X. Qin, Y. Dai, B. Huang, Appl. Catal. B 211, 252 (2017)CrossRefGoogle Scholar
  13. 13.
    P. Patiphatpanya, A. Phuruangrat, S. Thongtem, T. Thongtem, Mater. Lett. 209, 264 (2017)CrossRefGoogle Scholar
  14. 14.
    X. Meng, Z. Zhang, J. Photochem. Photobiol. A Chem. 310, 33 (2015)CrossRefGoogle Scholar
  15. 15.
    H. Huang, R. Cao, S. Yu, K. Xu, W. Hao, Y. Wang, F. Dong, T. Zhang, Y. Zhang, Appl. Catal. B 219, 526 (2017)CrossRefGoogle Scholar
  16. 16.
    Y. Li, Y. Zhao, G. Wu, H. Ma, J. Zhao, Mater. Res. Bull. 101, 39 (2018)CrossRefGoogle Scholar
  17. 17.
    S. Zhua, C. Yang, F. Li, T. Li, M. Zhang, W. Cao, Mol. Catal. 435, 33 (2017)CrossRefGoogle Scholar
  18. 18.
    X. Meng, Z. Zhang, Mater. Lett. 225, 152 (2018)CrossRefGoogle Scholar
  19. 19.
    J. Ma, S. Liu, G. Qi, Mater. Res. Bull. 95, 146 (2017)CrossRefGoogle Scholar
  20. 20.
    Y. Mi, H. Li, Y. Zhang, R. Zhang, W. Hou, Appl. Surf. Sci. 423, 1062 (2017)CrossRefGoogle Scholar
  21. 21.
    W. Yang, B. Ma, W. Wang, Y. Wen, D. Zeng, B. Shan, Phys. Chem. Chem. Phys. 15, 19387 (2013)CrossRefGoogle Scholar
  22. 22.
    A. Rizzuti, M. Dassisti, P. Mastrorilli, M.C. Sportelli, N. Cioffi, R.A. Picca, E. Agostinelli, G. Varvaro, R. Caliandro, J. Nanopart. Res. 17, 1 (2015)CrossRefGoogle Scholar
  23. 23.
    X. Meng, Z. Zhang, J. Mol. Catal. A Chem. 423, 533 (2016)CrossRefGoogle Scholar
  24. 24.
    X. Meng, Z. Zhang, Int. J. Photoenergy, Article ID 630476 (2015)Google Scholar
  25. 25.
    Powder Diffract. File, JCPDS-ICDD, 12 Campus Bld., Newtown Square, PA 19073-3273, USA (2001)Google Scholar
  26. 26.
    F. Dong, Y. Sun, M. Fu, Z. Wu, S.C. Lee, J. Hazard. Mater. 219–220, 26 (2012)CrossRefGoogle Scholar
  27. 27.
    S. Fang, Y. Zhou, H. Cui, Z. Li, S. Xu, L. Wang, J. Mater. Sci.: Mater. Electron. 28, 14575 (2017)Google Scholar
  28. 28.
    X. Fan, X. Yue, J. Luo, C. Wang, J. Nanopart. Res. 18, 1 (2016)CrossRefGoogle Scholar
  29. 29.
    J. Shen, J. Xue, Z. Chen, J. Ni, B. Tang, G. He, H. Chen, J. Mater. Sci. 53, 4848 (2018)CrossRefGoogle Scholar
  30. 30.
    A. Phuruangrat, A. Maneechote, P. Dumrongrojthanath, N. Ekthammathat, S. Thongtem, T. Thongtem, Mater. Lett. 159, 289 (2015)CrossRefGoogle Scholar
  31. 31.
    Z. Li, X. Meng, Z. Zhang, Catal. Today 315, 67 (2018)CrossRefGoogle Scholar
  32. 32.
    L. Lin, M. Huang, L. Long, Z. Sun, W. Zheng, D. Chen, Ceram. Int. 40, 11493 (2014)CrossRefGoogle Scholar
  33. 33.
    W. An, W. Cui, Y. Liang, J. Hu, Li Liu. Appl. Surf. Sci. 351, 1131 (2015)CrossRefGoogle Scholar
  34. 34.
    Q.W. Cao, X. Cui, Y.F. Zheng, X.C. Song, J. Alloys Compd. 670, 12 (2016)CrossRefGoogle Scholar
  35. 35.
    L. Chen, H. Hua, Q. Yang, C. Hu, Appl. Surf. Sci. 327, 62 (2015)CrossRefGoogle Scholar
  36. 36.
    Z. Wu, L. Chen, C. Xing, D. Jiang, J. Xie, M. Chen, Dalton Trans. 42, 12980 (2013)CrossRefGoogle Scholar
  37. 37.
    P. Dumrongrojthanath, A. Phuruangrat, S. Thongtem, T. Thongtem, J. Iran. Chem. Soc. (2018)Google Scholar

Copyright information

© Springer Nature B.V. 2019

Authors and Affiliations

  • Phattranit Dumrongrojthanath
    • 1
    Email author
  • Thankamon Saksoong
    • 1
  • Panudda Patiphatpanya
    • 1
  • Anukorn Phuruangrat
    • 2
  • Somchai Thongtem
    • 3
    • 4
  • Titipun Thongtem
    • 1
    • 4
    Email author
  1. 1.Department of Chemistry, Faculty of ScienceChiang Mai UniversityChiang MaiThailand
  2. 2.Department of Materials Science and Technology, Faculty of SciencePrince of Songkla UniversityHat YaiThailand
  3. 3.Department of Physics and Materials Science, Faculty of ScienceChiang Mai UniversityChiang MaiThailand
  4. 4.Materials Science Research Center, Faculty of ScienceChiang Mai UniversityChiang MaiThailand

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