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Research on Chemical Intermediates

, Volume 43, Issue 2, pp 829–841 | Cite as

Silica nanosphere–graphene oxide (SiO2–GO) hybrid catalyzed facile synthesis of functionalized quinoxaline derivatives

  • Praveen V. Shitre
  • Rajkumar R. Harale
  • Bhaskar R. Sathe
  • Murlidhar S. ShingareEmail author
Article

Abstract

Herein, fabrication of spherical SiO2 nanoparticles (5 ± 0.2 nm) with uniform size is followed by their homogeneous distribution on graphene oxide (SiO2–GO) by using a simple in situ one-step method. These as synthesized catalytic materials are further characterized by transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FTIR), energy dispersive spectroscopy (EDS), X-ray diffraction (XRD), and others. This spectroscopic characterization demonstrated that GO acted as a good supportive substrate for controlling the size and activity of SiO2 nanospheres with their cooperation towards catalytic reactions. The optimized hybrid exhibited high catalytic activity for the synthesis of functionalized quinoxalines. Significantly, the as-synthesised SiO2–GO nanohybrid catalysed reaction, for the first time, was shown to be highly efficient in mild conditions (i.e., room temperature, air) with excellent product yield (92 %) and good recyclability (up to four cycles) at room temperature.

Graphical Abstract

Keywords

SiO2 nanospheres Graphene oxide (GO) SiO2–GO nanohybrid Functionalized quinoxaline Cyclocondensation reaction 

Notes

Acknowledgments

An Emeritus Scientist Fellowship awarded to MSS by the Council of Scientific and Industrial Research, New Delhi (Project vide NO. 21(0919)/12/EMR-II Dated 25-04-2013) is gratefully acknowledged. The authors are grateful to the UGC for the award of a Teacher fellowship. The authors are also grateful to the Department of Chemistry, Dr. B. A. Marathwada University, Aurangabad, for providing the laboratory facilities. We also thank SAIF Division, CDRI, Lucknow, for providing analytical data.

Supplementary material

11164_2016_2667_MOESM1_ESM.docx (280 kb)
Supplementary material 1 (DOCX 279 kb)

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Copyright information

© Springer Science+Business Media Dordrecht 2016

Authors and Affiliations

  • Praveen V. Shitre
    • 1
  • Rajkumar R. Harale
    • 1
  • Bhaskar R. Sathe
    • 1
  • Murlidhar S. Shingare
    • 1
    Email author
  1. 1.Department of ChemistryDr. Babasaheb Ambedkar Marathwada UniversityAurangabadIndia

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