Research on Chemical Intermediates

, Volume 42, Issue 4, pp 3303–3314 | Cite as

1,3-Disulfonic acid benzimidazolium chloride as an efficient and recyclable ionic liquid catalyst for the synthesis of 3,4-dihydropyrimidine-2-(1H)-ones/thiones

Article

Abstract

1,3-Disulfonic acid benzimidazolium chloride ionic liquid ([Dsbim]Cl) was prepared, characterized and applied as an efficient, homogeneous and recyclable catalyst for the synthesis of 3,4-dihydropyrimidine-2-(1H)-ones/thiones through the one-pot three-component condensation of aromatic aldehydes, urea/thiourea and ethyl acetoacetate under solvent-free conditions. The key advantages of this novel protocol are its short reaction time, high yields, mild and clean conditions, practical simplicity and its capacity for reuse several times without a noticeable decrease in catalytic activity.

Keywords

1,3-Disulfonic acid benzimidazolium chloride Ionic liquid Solvent-free 3,4-Dihydropyrimidine-2-(1H)-ones 

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Copyright information

© Springer Science+Business Media Dordrecht 2015

Authors and Affiliations

  1. 1.Department of Chemistry, Lamerd BranchIslamic Azad UniversityLamerdIran

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