Research on Chemical Intermediates

, Volume 40, Issue 3, pp 1201–1221 | Cite as

Adsorption and corrosion inhibitive properties of piperidine derivatives on mild steel in phosphoric acid medium

  • A. Ousslim
  • K. Bekkouch
  • A. Chetouani
  • E. Abbaoui
  • B. Hammouti
  • A. Aouniti
  • A. Elidrissi
  • F. Bentiss
Article

Abstract

The present study describes the inhibition effect of 4-benzyl piperidine (P1), 1,6-bis(4-benzylpiperidine-1-carboxamide)hexane (P2) and bis(4-benzylpiperidine)thiuram disulfide (P3) towards the corrosion of mild steel in 5.5 M H3PO4 solution using weight loss measurements and polarization technique. The influence of inhibitor concentration and temperature on the inhibitory behavior of P2 and P3 was investigated. Meanwhile, the inhibition efficiency (IE) was found to depend on the molecule structure and the concentration of piperidine derivatives. The IE for 10−3 M P2 and P2 in 5.5 M H3PO4 is around 90 %. Polarization studies clearly revealed that all the compounds used act as mixed-type inhibitors. Adsorption isotherms were fitted by the Langmuir isotherm. Adsorption energies (\( \Updelta {\text{G}}^\circ_{\text{ads}} \) and \( \Updelta {\text{H}}^\circ_{\text{ads}} \)) and kinetic parameters were evaluated. Significant correlations are obtained between inhibition efficiency with the calculated chemical indexes, indicating that the variation of inhibition with structure of the inhibitor may be explained in terms of electronic properties.

Keywords

Corrosion Inhibitor Piperidine Mild steel Phosphoric acid Adsorption Quantum chemical 

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Copyright information

© Springer Science+Business Media Dordrecht 2013

Authors and Affiliations

  • A. Ousslim
    • 1
    • 2
  • K. Bekkouch
    • 2
  • A. Chetouani
    • 1
    • 3
  • E. Abbaoui
    • 1
  • B. Hammouti
    • 1
  • A. Aouniti
    • 1
  • A. Elidrissi
    • 1
  • F. Bentiss
    • 4
  1. 1.Laboratory of Applied Chemistry and Environment (LCAE-URAC18), Faculté des SciencesUniversité Mohammed PremierOujdaMorocco
  2. 2.Laboratoire de Chimie Solide Minérale, Faculté des SciencesUniversité Mohammed PremierOujdaMorocco
  3. 3.Laboratoire de Chimie PhysiqueCentre Régionale des Métiers de l’Education et de Formation (CRMEF)OujdaMorocco
  4. 4.Laboratoire de Chimie de Coordination et d’Analytique (LCCA), Faculté des SciencesUniversité Chouaib DoukkaliEl JadidaMorocco

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