Research on Chemical Intermediates

, Volume 40, Issue 2, pp 801–815 | Cite as

Study of a cysteine derivative as a corrosion inhibitor for carbon steel in phosphoric acid solution

  • H. Zarrok
  • A. Zarrouk
  • R. Salghi
  • B. Hammouti
  • M. Elbakri
  • M. Ebn Touhami
  • F. Bentiss
  • H. Oudda
Article

Abstract

Inhibition of corrosion of carbon steel in phosphoric acid solution by use of l-cysteine methyl ester hydrochloride has been investigated by measurement of weight loss and use of electrochemical methods. The efficiency of inhibition was increased by increasing the concentration of the inhibitor and reduced by increasing the temperature. Polarization studies revealed that this compound behaves as mixed-type inhibitor. Electrochemical impedance spectroscopy showed that dissolution of the steel occurs as a result of charge-transfer. Adsorption of the inhibitor obeyed the Langmuir adsorption isotherm. Kinetic and thermodynamic data were calculated and are discussed.

Keywords

l-Cysteine Carbon steel H3PO4 Inhibition corrosion Polarisation curves EIS 

References

  1. 1.
    T. Sydberger, S. Nordin, Corrosion 34, 16 (1978)CrossRefGoogle Scholar
  2. 2.
    H. Zarrok, H. Oudda, A. Zarrouk, R. Salghi, B. Hammouti, M. Bouachrine, Der. Pharm. Chem. 3, 576 (2011)Google Scholar
  3. 3.
    H. Zarrok, R. Salghi, A. Zarrouk, B. Hammouti, H. Oudda, Lh Bazzi, L. Bammou, S.S. Al-Deyab, Der. Pharm. Chem. 4, 407 (2012)Google Scholar
  4. 4.
    H. Zarrok, S.S. Al-Deyab, A. Zarrouk, R. Salghi, B. Hammouti, H. Oudda, M. Bouachrine, F. Bentiss, Int. J. Electrochem. Sci. 7, 4047 (2012)Google Scholar
  5. 5.
    D. Ben Hmamou, R. Salghi, A. Zarrouk, H. Zarrok, B. Hammouti, S.S. Al-Deyab, M. Bouachrine, A. Chakir, M. Zougagh, Int. J. Electrochem. Sci. 7, 5716 (2012)Google Scholar
  6. 6.
    A. Zarrouk, B. Hammouti, S.S. Al-Deyab, R. Salghi, H. Zarrok, C. Jama, F. Bentiss, Int. J. Electrochem. Sci. 7, 5997 (2012)Google Scholar
  7. 7.
    A. Zarrouk, H. Zarrok, R. Salghi, B. Hammouti, S.S. Al-Deyab, R. Touzani, M. Bouachrine, I. Warad, T.B. Hadda, Int. J. Electrochem. Sci. 7, 6353 (2012)Google Scholar
  8. 8.
    A. Zarrouk, M. Messali, H. Zarrok, R. Salghi, A. Al-Sheikh Ali, B. Hammouti, S.S. Al-Deyab, F. Bentiss, Int. J. Electrochem. Sci. 7, 6998 (2012)Google Scholar
  9. 9.
    H. Zarrok, A. Zarrouk, R. Salghi, Y. Ramli, B. Hammouti, S.S. Al-Deyab, E.M. Essassi, H. Oudda, Int. J. Electrochem. Sci. 7, 8958 (2012)Google Scholar
  10. 10.
    D. Ben Hmamou, R. Salghi, A. Zarrouk, H. Zarrok, S.S. Al-Deyab, O. Benali, B. Hammouti, Int. J. Electrochem. Sci. 7, 8988 (2012)Google Scholar
  11. 11.
    A. Zarrouk, M. Messali, M.R. Aouad, M. Assouag, H. Zarrok, R. Salghi, B. Hammouti, A. Chetouani, J. Chem. Pharm. Res. 4, 3427 (2012)Google Scholar
  12. 12.
    H. Zarrok, H. Oudda, A. El Midaoui, A. Zarrouk, B. Hammouti, M. Ebn Touhami, A. Attayibat, S. Radi, R. Touzani, Res. Chem. Intermed (2012) doi:10.1007/s11164-012-0525-x
  13. 13.
    A. Zarrouk, B. Hammouti, H. Zarrok, R. Salghi, A. Dafali, Lh Bazzi, L. Bammou, S.S. Al-Deyab, Der. Pharm. Chem. 4, 337 (2012)Google Scholar
  14. 14.
    A. Zarrouk, A. Dafali, B. Hammouti, H. Zarrok, S. Boukhris, M. Zertoubi, Int. J. Electrochem. Sci. 5, 46 (2010)Google Scholar
  15. 15.
    A. Zarrouk, T. Chelfi, A. Dafali, B. Hammouti, S.S. Al-Deyab, I. Warad, N. Benchat, M. Zertoubi, Int. J. Electrochem. Sci. 5, 696 (2010)Google Scholar
  16. 16.
    A. Zarrouk, I. Warad, B. Hammouti, A. Dafali, S.S. Al-Deyab, N. Benchat, Int. J. Electrochem. Sci. 5, 1516 (2010)Google Scholar
  17. 17.
    A. Zarrouk, B. Hammouti, R. Touzani, S.S. Al-Deyab, M. Zertoubi, A. Dafali, S. Elkadiri, Int. J. Electrochem. Sci. 6, 4939 (2011)Google Scholar
  18. 18.
    A. Zarrouk, B. Hammouti, H. Zarrok, S.S. Al-Deyab, M. Messali, Int. J. Electrochem. Sci. 6, 6261 (2011)Google Scholar
  19. 19.
    Lin Wang, Corros. Sci. 48, 608 (2006)CrossRefGoogle Scholar
  20. 20.
    X. Li, S. Deng, H. Fu, G. Mu, Corros. Sci. 52, 1167 (2010)CrossRefGoogle Scholar
  21. 21.
    X. Li, S. Deng, H. Fu, Corros. Sci. 53, 3704 (2011)CrossRefGoogle Scholar
  22. 22.
    L. Tang, X. Li, G. Mua, L. Li, G. Liu, Appl. Surf. Sci. 253, 2367 (2006)CrossRefGoogle Scholar
  23. 23.
    M. Benabdellah, R. Touzani, A. Dafali, B. Hammouti, S. El Kadiri, Mat. Lett. 61, 1197 (2007)CrossRefGoogle Scholar
  24. 24.
    M. Benabdellah, A. Aouniti, A. Dafali, B. Hammouti, M. Benkaddour, A. Yahyi, A. Ettouhami, Appl. Surf. Sci. 252, 8341 (2006)CrossRefGoogle Scholar
  25. 25.
    X. Li, S. Deng, H. Fu, Mat. Chem. Phys. 115, 815 (2009)CrossRefGoogle Scholar
  26. 26.
    H. Zarrok, A. Zarrouk, B. Hammouti, R. Salghi, C. Jama, F. Bentiss, Corros. Sci. 64, 243 (2012)CrossRefGoogle Scholar
  27. 27.
    V. Ramesh Saliyan, A.V. Adhikari, Corros. Sci. 50, 55 (2008)CrossRefGoogle Scholar
  28. 28.
    G.N. Mu, X.H. Li, Q. Qu, J. Zhou, Corros. Sci. 48, 445 (2006)CrossRefGoogle Scholar
  29. 29.
    S. Issaadi, T. Douadi, A. Zouaoui, S. Chafaa, M.A. Khan, G. Bouet, Corros. Sci. 53, 1484 (2011)CrossRefGoogle Scholar
  30. 30.
    K.F. Khaled, M.M. Al-Qahtani, Mater. Chem. Phys. 113, 150 (2009)CrossRefGoogle Scholar
  31. 31.
    C. Cao, Corros. Sci. 38, 2073 (1996)CrossRefGoogle Scholar
  32. 32.
    J. Cruz, T. Pandiyan, E.G. Ochoa, J. Electroanal. Chem. 583, 8 (2005)CrossRefGoogle Scholar
  33. 33.
    D.A. Lopez, S.N. Simison, S.R. de Sanchez, Corros. Sci. 47, 735 (2005)CrossRefGoogle Scholar
  34. 34.
    J.W. Schultze, K. Wippermann, Electrochim. Acta 32, 823 (1987)CrossRefGoogle Scholar
  35. 35.
    S. Martinez, M. Metikoš-Hukovic′, J. Appl. Electrochem. 33, 137 (2003)CrossRefGoogle Scholar
  36. 36.
    M. Behpour, S.M. Ghoreishi, N. Mohammadi, N. Soltani, M. Salavati-Niasari, Corros. Sci. 52, 4046 (2010)CrossRefGoogle Scholar
  37. 37.
    E. McCafferty, N. Hackerman, J. Electrochem. Soc. 119, 146 (1972)CrossRefGoogle Scholar
  38. 38.
    B. Hammouti, A. Zarrouk, S.S. Al-Deyab, I. Warad, Oriental J. Chem. 27, 23 (2011)Google Scholar
  39. 39.
    L.B. Tang, G.N. Mu, G.H. Liu, Corros. Sci. 45, 2251 (2003)CrossRefGoogle Scholar
  40. 40.
    R. Solmaz, G. Kardas, M. Culha, B. Yazıcı, M. Erbil, Electrochim. Acta 53, 5941 (2008)CrossRefGoogle Scholar
  41. 41.
    I. El Ouali, B. Hammouti, A. Aouniti, Y. Ramli, M. Azougagh, E.M. Essassi, M. Bouachrine, J. Mater. Environ. Sci. 1, 1 (2010)Google Scholar
  42. 42.
    M. Sahin, S. Bilgic, H. Yilmaz, Appl. Surf. Sci. 195, 1 (2002)CrossRefGoogle Scholar
  43. 43.
    E. Machnikova, K.H. Whitmire, N. Hackerman, Electrochim. Acta 53, 6024 (2008)CrossRefGoogle Scholar
  44. 44.
    M.S. Morad, Corros. Sci. 50, 436 (2008)CrossRefGoogle Scholar
  45. 45.
    A.K. Satapathy, G. Gunasekaran, S.C. Sahoo, K. Amit, P.V. Rodrigues, Corros. Sci. 51, 2848 (2009)CrossRefGoogle Scholar
  46. 46.
    O. Olivares, N.V. Likhanova, B. Gomez, J. Navarrete, M.E. Llanos-Serrano, E. Arce, J.M. Hallen, Appl. Surf. Sci. 252, 2894 (2006)CrossRefGoogle Scholar
  47. 47.
    S.A. Umoren, I.B. Obot, E.E. Ebenso, N.O. Obi-Egbedi, Desalination 247, 561 (2009)CrossRefGoogle Scholar
  48. 48.
    A. Popova, E. Sokolova, S. Raicheva, M. Christov, Corros. Sci. 45, 33 (2003)CrossRefGoogle Scholar
  49. 49.
    E.A. Noor, J. Appl. Electrochem. 39, 1465 (2009)CrossRefGoogle Scholar
  50. 50.
    G. Mu, X. Li, G. Liu, Corros. Sci. 47, 1932 (2005)CrossRefGoogle Scholar
  51. 51.
    J.M. Thomas, W.J. Thomas, Introduction to the principles of heterogeneous catalysis, 5th edn. (Academic Press, London, 1981), p. 14Google Scholar

Copyright information

© Springer Science+Business Media Dordrecht 2013

Authors and Affiliations

  • H. Zarrok
    • 1
  • A. Zarrouk
    • 2
  • R. Salghi
    • 3
    • 5
  • B. Hammouti
    • 2
  • M. Elbakri
    • 3
    • 5
  • M. Ebn Touhami
    • 3
    • 5
  • F. Bentiss
    • 4
  • H. Oudda
    • 1
  1. 1.Laboratoire Des Procèdes de Séparation, Faculté Des SciencesUniversité Ibn TofailKénitraMorocco
  2. 2.LCAE-URAC18, Faculté Des SciencesUniversité Mohammed IerOujdaMorocco
  3. 3.Equipe de Génie de L’Environnement Et de Biotechnologie, ENSAUniversité Ibn ZohrAgadirMorocco
  4. 4.Laboratoire de Chimie de Coordination Et D’Analytique (LCCA), Faculté Des SciencesUniversité Chouaib DoukkaliEl JadidaMorocco
  5. 5.Laboratoire D’électrochimie, de Corrosion Et D’environnement, Faculté Des SciencesUniversité Ibn TofailKenitraMorocco

Personalised recommendations