Research on Chemical Intermediates

, Volume 39, Issue 6, pp 2663–2677 | Cite as

An investigation of carbon steel corrosion inhibition in hydrochloric acid medium by an environmentally friendly green inhibitor

  • M. Larif
  • A. Elmidaoui
  • A. Zarrouk
  • H. Zarrok
  • R. Salghi
  • B. Hammouti
  • H. Oudda
  • F. Bentiss
Article

Abstract

The inhibition effect of polyphenols extracted from olive mill wastewater (PP) on carbon steel in 1.0 M HCl solution was studied. Inhibition efficiency of PP was carried out by using chemical (weight loss method) and electrochemical techniques [potentiodynamic polarization and electrochemical impedance spectroscopy (EIS)]. The effect of temperature and immersion time on the corrosion behavior of carbon steel in 1.0 M HCl with addition of an extract was also studied. The results show that PP acts as a very good inhibitor, and the inhibition efficiency increases with the concentration of PP and decreases with rising temperature. Polarization curves show that PP behaves as a mixed-type inhibitor in hydrochloric acid. Data, obtained from EIS measurements, were analyzed to model the corrosion inhibition process through an appropriate equivalent circuit model; a constant phase element has been used. EIS shows that charge-transfer resistance increases and the capacitance of double layer decreases with the inhibitor concentration, confirming the adsorption process mechanism. The activation energy as well as other thermodynamic parameters for the inhibition process were calculated. The adsorption of PP obeys the Langmuir adsorption isotherm.

Keywords

Polyphenols Steel Acid medium Corrosion inhibition Polarisation EIS 

References

  1. 1.
    F. Bentiss, M. Traisnel, M. Lagrene’e, Corros. Sci. 42, 127 (2000)CrossRefGoogle Scholar
  2. 2.
    H. Zarrok, H. Oudda, A. Zarrouk, R. Salghi, B. Hammouti, M. Bouachrine, Der Pharm. Chem. 3, 576 (2011)Google Scholar
  3. 3.
    M. Mihit, K. Laarej, H. Abou El Makarim, L. Bazzi, R. Salghi, B. Hammouti, Arabian J. Chem. 3, 55 (2010)CrossRefGoogle Scholar
  4. 4.
    M. Mihit, L. Bazzi, R. Salghi, B. Hammouti, S. El Issami, E. Ait Addi, ISJAEE 62, 173 (2008)Google Scholar
  5. 5.
    K. Barouni, L. Bazzi, R. Salghi, M. Mihit, B. Hammouti, A. Albourine, S. El Issami, Mater. Lett. 62, 3325 (2008)CrossRefGoogle Scholar
  6. 6.
    S. El Issami, L. Bazzi, M. Mihit, B. Hammouti, S. Kertit, E. Ait Addi, R. Salghi, Pigment Resin. Tech. 36, 161 (2007)CrossRefGoogle Scholar
  7. 7.
    M. Mihit, R. Salghi, S. El Issami, L. Bazzi, B. Hammouti, E. Ait Addi, S. Kertit, Pigment Resin Technol. 35, 151 (2006)CrossRefGoogle Scholar
  8. 8.
    H. Zarrok, S.S. Al-Deyab, A. Zarrouk, R. Salghi, B. Hammouti, H. Oudda, M. Bouachrine, F. Bentiss, Int. J. Electrochem. Sci. 7, 4047 (2012)Google Scholar
  9. 9.
    H. Zarrok, H. Oudda, A. El Midaoui, A. Zarrouk, B. Hammouti, M. Ebn Touhami, A. Attayibat, S. Radi, R. Touzani, Res. Chem. Intermed. (2012). doi: 10.1007/s11164-012-0525-x Google Scholar
  10. 10.
    H. Zarrok, R. Salghi, A. Zarrouk, B. Hammouti, H. Oudda, Lh. Bazzi, L. Bammou, S.S. Al-Deyab, Der Pharm. Chem. 4, 407 (2012)Google Scholar
  11. 11.
    A. Ghazoui, R. Saddik, N. Benchat, B. Hammouti, M. Guenbour, A. Zarrouk, M. Ramdani, Der Pharm. Chem. 4, 352 (2012)Google Scholar
  12. 12.
    A. Zarrouk, B. Hammouti, H. Zarrok, R. Salghi, A. Dafali, Lh. Bazzi, L. Bammou, S.S. Al-Deyab, Der Pharm. Chem. 4, 337 (2012)Google Scholar
  13. 13.
    D.D.N. Singh, T.B. Singh, B. Gaur, Corros. Sci. 37, 1005 (1995)CrossRefGoogle Scholar
  14. 14.
    L. Afia, R. Salghi, L. Bammou, El. Bazzi, B. Hammouti, L. Bazzi, A. Bouyanzer, J. Saudi Chem. Soc. (2011). doi: 10.1016/j.jscs.2011.05.008
  15. 15.
    L. Afia, R. Salghi, El. Bazzi, A. Zarrok, B. Hammouti, M. Bouri, H. Zarrouk, L. Bazzi, L. Bammou. Res. Chem. Intermed. (2012) doi: 10.1007/s11164-012-0496-y
  16. 16.
    D. Ben Hmamou, R. Salghi, Lh. Bazzi, B. Hammouti, S.S. Al-Deyab, L. Bammou, L. Bazzi, A. Bouyanzer, Int. J. Electrochem. Sci. 7, 1303 (2012)Google Scholar
  17. 17.
    D. Ben Hmamou, R. Salghi, A. Zarrouk, B. Hammouti, S.S. Al-Deyab, Lh. Bazzi, H. Zarrok, A. Chakir, L. Bammou, Int. J. Electrochem. Sci. 7, 2361 (2012)Google Scholar
  18. 18.
    L. Bammou, B. Chebli, R. Salghi, L. Bazzi, B. Hammouti, M. Mihit, H. El Idrissi, Green Chem. Lett. Rev. 3, 173 (2010)CrossRefGoogle Scholar
  19. 19.
    E. Mokhtar, E. Ouariachi, J. Paolini, A. Bouyanzer, P. Tomi, B. Hammouti, R. Salghi, L. Majidi, J. Costa, J. Med. Plants Res. 5, 5773 (2011)Google Scholar
  20. 20.
    L. Bammou, M. Mihit, R. Salghi, L. Bazzi, A. Bouyanzer, B. Hammouti, Int. J. Electrochem. Sci. 6, 1454 (2011)Google Scholar
  21. 21.
    O. Ouachikh, A. Bouyanzer, M. Bouklah, J.-M. Desjobert, J. Costa, B. Hammouti, L. Majidi, Surf. Rev. Lett. 16, 49 (2009)CrossRefGoogle Scholar
  22. 22.
    D. Zerga, M. Sfaira, Z. Rais, M. Ebn Touhami, M. Taleb, B. Hammouti, B. Imelouane, A. Elbachiri, Mater. Tech. 97, 297 (2009)CrossRefGoogle Scholar
  23. 23.
    N. Lahhit, A. Bouyanzer, J.M. Desjobert, B. Hammouti, R. Salghi, J. Costa, C. Jama, F. Bentiss, L. Majidi, Port. Electrochim. Acta 29, 127 (2011)CrossRefGoogle Scholar
  24. 24.
    S. Rekkab, H. Zarrok, R. Salghi, A. Zarrouk, Lh. Bazzi, B. Hammouti, Z. Kabouche, R. Touzani, M. Zougagh, J. Mater. Environ. Sci. 3, 613 (2012)Google Scholar
  25. 25.
    J.J. Macheix, A. Fleuriet, J.A. Billot, Fruit phenolics (CRC Press Inc., Boca Raton, 1990)Google Scholar
  26. 26.
    M. Lebrini, F. Bentiss, N. Chihib, C. Jama, J.P. Hornez, M. Lagrenée, Corros. Sci. 50, 2914 (2008)CrossRefGoogle Scholar
  27. 27.
    E. McCafferty, Corros. Sci. 47, 3202 (2005)CrossRefGoogle Scholar
  28. 28.
    M. Bouklah, N. Benchat, A. Aouniti, B. Hammouti, M. Benkaddour, M. Lagrenée, H. Vezin, F. Bentiss, Prog. Org. Coat. 51, 118 (2004)CrossRefGoogle Scholar
  29. 29.
    M.S. Morad, Corros. Sci. 42, 1307 (2000)CrossRefGoogle Scholar
  30. 30.
    A.R.S. Priya, V.S. Muralidharam, A. Subramania, Corrosion 64, 541 (2008)CrossRefGoogle Scholar
  31. 31.
    P. Bommersbach, C. Alemany-Dumont, J.P. Millet, B. Normand, Electrochim. Acta 51, 4011 (2006)CrossRefGoogle Scholar
  32. 32.
    K. Jutner, Electrochim. Acta 10, 1501 (1990)CrossRefGoogle Scholar
  33. 33.
    U. Rammelt, G. Reinhard, Corros. Sci. 27, 373 (1987)CrossRefGoogle Scholar
  34. 34.
    J. Pang, A. Briceno, S. Chander, J. Electrochem. Soc. 137, 3447 (1990)CrossRefGoogle Scholar
  35. 35.
    Z. Stoynov, Electrochim. Acta 35, 1493 (1990)CrossRefGoogle Scholar
  36. 36.
    J.R. Macdonald, J. Electroanal. Chem. 223, 25 (1987)CrossRefGoogle Scholar
  37. 37.
    D.A. Lopez, S.N. Simison, S.R. de Sanchez, Electrochim. Acta 48, 845 (2003)CrossRefGoogle Scholar
  38. 38.
    J.W. Schultze, K. Wippermann, Electrochim. Acta 32, 823 (1987)CrossRefGoogle Scholar
  39. 39.
    F. Bentiss, M. Lebrini, M. Lagrenee, M. Traisnel, A. Elfarouk, H. Vezin, Electrochim. Acta 52, 6865 (2007)CrossRefGoogle Scholar
  40. 40.
    S. Martinez, M. Metikoš-Hukovic′, J. Appl. Electrochem. 33(137), 1 (2003)Google Scholar
  41. 41.
    E. McCafferty, N. Hackerman, J. Electrochem. Soc. 119, 146 (1972)CrossRefGoogle Scholar
  42. 42.
    H. Fischer, Werkst. Korros. 23, 445 (1972)CrossRefGoogle Scholar
  43. 43.
    A. Popova, E. Sokolova, S. Raicheva, M. Christov, Corros. Sci. 45, 33 (2003)CrossRefGoogle Scholar
  44. 44.
    M.S. Morad, Corros. Sci. 50, 436 (2008)CrossRefGoogle Scholar
  45. 45.
    L. Larabi, O. Benali, Y. Harek, Mater. Lett. 61, 3287 (2007)CrossRefGoogle Scholar
  46. 46.
    T. Szauer, A. Brandt, Electrochim. Acta 26, 1253 (1981)CrossRefGoogle Scholar
  47. 47.
    L. Valek, S. Martinez, Mater. Lett. 61, 148 (2007)CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media B.V. 2012

Authors and Affiliations

  • M. Larif
    • 1
  • A. Elmidaoui
    • 1
  • A. Zarrouk
    • 2
  • H. Zarrok
    • 1
  • R. Salghi
    • 3
  • B. Hammouti
    • 2
  • H. Oudda
    • 1
  • F. Bentiss
    • 4
  1. 1.Laboratoire des procèdes de séparation, Faculté des SciencesUniversité Ibn TofailKénitraMorocco
  2. 2.LCAE-URAC18, Faculté des SciencesUniversité Mohammed 1erOujdaMorocco
  3. 3.Equipe de Génie de l’Environnement et Biotechnologie, ENSAUniversité Ibn ZohrAgadirMorocco
  4. 4.Laboratoire de Chimie de Coordination et d’Analytique (LCCA), Faculté des SciencesUniversité Chouaib DoukkaliEl JadidaMorocco

Personalised recommendations