Research on Chemical Intermediates

, Volume 36, Issue 6–7, pp 749–759 | Cite as

The electrochemical properties of Li/TEGDME/MoS2 cells using multi-wall carbon nanotubes as a conducting agent

  • Jeong-Hui Kwon
  • Hyo-Jun Ahn
  • Min-Sang Jeon
  • Ki-Won Kim
  • In-Shup Ahn
  • Jou-Hyeon Ahn
  • Guoxiu Wang
  • Ho-Suk Ryu
Article

Abstract

We investigated the first charge–discharge behavior and cycling property of Li batteries using MoS2 electrodes with multi-wall carbon nanotubes (MWNT) as a conducting agent. The MoS2 electrode was prepared using MWNT as the conducting agent. The battery gave a high first discharge capacity of 440 mAhg−1 with a plateau potential region at 1.1 V. The Li/MoS2 battery using MWNT showed a higher discharge capacity compared to acetylene black. After ten cycles of the battery using MWNT, the discharge capacity decreased to 120 mAhg−1, which corresponded to 30% of the first discharge capacity. Adding a carbon nanotube into the MoS2 electrode improved the first discharge behavior, but did not affect the cycling property of the Li/MoS2 cell.

Keywords

Molybdenum disulfide (MoS2Multi-wall carbon nanotube (MWNT) Conducting agent Battery 

Notes

Acknowledgments

This research was supported by the Basic Science Research Program (2009-0071729) and by WCU program (R32-20093) through the National Research Foundation of Korea funded by the Ministry of Education, Science and Technology.

References

  1. 1.
    C. Rudowicz, I. Stefaniuk, R. Dziembaj, H. Ohta, M. Molenda, S. Okubo, M. Yoshida, Res. Chem. Intermed. 33(8), 853 (2007)CrossRefGoogle Scholar
  2. 2.
    Y. Miki, D. Nakazato, H. Ikuta, T. Uchida, M. Wakihara, J. Power Sour. 54, 508 (1995)CrossRefGoogle Scholar
  3. 3.
    F.C. Lama, K. Brandt, J. Power Sour. 24, 195 (1988)CrossRefGoogle Scholar
  4. 4.
    K. Kumal, T. Ikeya, K. Ishihara, T. Iwahori, N. Imanishi, Y. Takeda, O. Yamamoto, J. Power Sour. 70, 235 (1998)CrossRefGoogle Scholar
  5. 5.
    C.M. Julien, S.I. Saikh, G.A. Nazri, Mat. Sci. Eng. B15, 73 (1992)Google Scholar
  6. 6.
    J.H. Kwon, H.S. Ryu, K.W. Kim, J.H. Ahn, Y.S. Jeong, K.W. Lee, H.J. Ahn, Trans. Korean Hydrogen New Energy Soc. 20(3), 238 (2009)Google Scholar
  7. 7.
    K. Kumal, T. Ikeya, K. Ishihara, T. Iwahori, N. Imanishi, Y. Takeda, O. Yamamoto, J. Power Sour. 70, 235 (1998)CrossRefGoogle Scholar
  8. 8.
    H.S. Ryu, S.W. Lee, K.W. Kim, J.H. Ahn, K.K. Cho, G.B. Cho, H.J. Ahn, Mat. Sci. Forum 534, 1509 (2007)CrossRefGoogle Scholar
  9. 9.
    Y.J. Choi, K.W. Kim, H.J. Ahn, J.H. Ahn, J. Alloys Compd. 449, 313 (2008)CrossRefGoogle Scholar
  10. 10.
    S.C. Han, M.S. Song, H. Lee, H.S. Kim, H.J. Ahn, J.Y. Lee, J. Electrochem. Soc. 150, A889 (2003)CrossRefGoogle Scholar
  11. 11.
    B.H. Jeon, J.H. Yeon, K.M. Kim, I.J. Chung, J. Power Sour. 109, 89 (2002)CrossRefGoogle Scholar
  12. 12.
    S.S. Jeong, Y.J. Choi, K.K. Kim, Mat. Sci. Forum 510, 1106 (2006)CrossRefGoogle Scholar
  13. 13.
    J.S. Chung, H.J. Sohn, J. Power Sour. 108, 226 (2002)CrossRefGoogle Scholar
  14. 14.
    L.X. Yuan, J.K. Feng, X.P. Ai, Y.L. Cao, S.L. Chen, H.X. Yang, Electrochem. Commun. 8, 610 (2006)CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media B.V. 2010

Authors and Affiliations

  • Jeong-Hui Kwon
    • 1
  • Hyo-Jun Ahn
    • 1
  • Min-Sang Jeon
    • 1
  • Ki-Won Kim
    • 1
  • In-Shup Ahn
    • 1
  • Jou-Hyeon Ahn
    • 2
  • Guoxiu Wang
    • 3
  • Ho-Suk Ryu
    • 4
  1. 1.School of Materials Science and Engineering, ReCAPTGyeongsang National UniversityJinjuRepublic of Korea
  2. 2.Department of Chemical & Biological EngineeringGyeongsang National UniversityJinjuRepublic of Korea
  3. 3.Department of Chemistry and Forensic ScienceUniversity of TechnologySydneyAustralia
  4. 4.PRC for Nano-Morphic Biological Energy Conversion and StorageGyeongsang National UniversityJinjuRepublic of Korea

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