The electrochemical properties of Li/TEGDME/MoS2 cells using multi-wall carbon nanotubes as a conducting agent
- 342 Downloads
- 12 Citations
Abstract
We investigated the first charge–discharge behavior and cycling property of Li batteries using MoS2 electrodes with multi-wall carbon nanotubes (MWNT) as a conducting agent. The MoS2 electrode was prepared using MWNT as the conducting agent. The battery gave a high first discharge capacity of 440 mAhg−1 with a plateau potential region at 1.1 V. The Li/MoS2 battery using MWNT showed a higher discharge capacity compared to acetylene black. After ten cycles of the battery using MWNT, the discharge capacity decreased to 120 mAhg−1, which corresponded to 30% of the first discharge capacity. Adding a carbon nanotube into the MoS2 electrode improved the first discharge behavior, but did not affect the cycling property of the Li/MoS2 cell.
Keywords
Molybdenum disulfide (MoS2) Multi-wall carbon nanotube (MWNT) Conducting agent BatteryNotes
Acknowledgments
This research was supported by the Basic Science Research Program (2009-0071729) and by WCU program (R32-20093) through the National Research Foundation of Korea funded by the Ministry of Education, Science and Technology.
References
- 1.C. Rudowicz, I. Stefaniuk, R. Dziembaj, H. Ohta, M. Molenda, S. Okubo, M. Yoshida, Res. Chem. Intermed. 33(8), 853 (2007)CrossRefGoogle Scholar
- 2.Y. Miki, D. Nakazato, H. Ikuta, T. Uchida, M. Wakihara, J. Power Sour. 54, 508 (1995)CrossRefGoogle Scholar
- 3.F.C. Lama, K. Brandt, J. Power Sour. 24, 195 (1988)CrossRefGoogle Scholar
- 4.K. Kumal, T. Ikeya, K. Ishihara, T. Iwahori, N. Imanishi, Y. Takeda, O. Yamamoto, J. Power Sour. 70, 235 (1998)CrossRefGoogle Scholar
- 5.C.M. Julien, S.I. Saikh, G.A. Nazri, Mat. Sci. Eng. B15, 73 (1992)Google Scholar
- 6.J.H. Kwon, H.S. Ryu, K.W. Kim, J.H. Ahn, Y.S. Jeong, K.W. Lee, H.J. Ahn, Trans. Korean Hydrogen New Energy Soc. 20(3), 238 (2009)Google Scholar
- 7.K. Kumal, T. Ikeya, K. Ishihara, T. Iwahori, N. Imanishi, Y. Takeda, O. Yamamoto, J. Power Sour. 70, 235 (1998)CrossRefGoogle Scholar
- 8.H.S. Ryu, S.W. Lee, K.W. Kim, J.H. Ahn, K.K. Cho, G.B. Cho, H.J. Ahn, Mat. Sci. Forum 534, 1509 (2007)CrossRefGoogle Scholar
- 9.Y.J. Choi, K.W. Kim, H.J. Ahn, J.H. Ahn, J. Alloys Compd. 449, 313 (2008)CrossRefGoogle Scholar
- 10.S.C. Han, M.S. Song, H. Lee, H.S. Kim, H.J. Ahn, J.Y. Lee, J. Electrochem. Soc. 150, A889 (2003)CrossRefGoogle Scholar
- 11.B.H. Jeon, J.H. Yeon, K.M. Kim, I.J. Chung, J. Power Sour. 109, 89 (2002)CrossRefGoogle Scholar
- 12.S.S. Jeong, Y.J. Choi, K.K. Kim, Mat. Sci. Forum 510, 1106 (2006)CrossRefGoogle Scholar
- 13.J.S. Chung, H.J. Sohn, J. Power Sour. 108, 226 (2002)CrossRefGoogle Scholar
- 14.L.X. Yuan, J.K. Feng, X.P. Ai, Y.L. Cao, S.L. Chen, H.X. Yang, Electrochem. Commun. 8, 610 (2006)CrossRefGoogle Scholar