Refractories and Industrial Ceramics

, Volume 56, Issue 3, pp 267–270 | Cite as

Titanium Nitride Synthesis in the Presence of Iodine

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A method is proposed for synthesizing titanium nitride by nitriding titanium metal powder with nitrogen in the presence of iodine vapor, and results are given for its application. It is shown that iodine significantly reduces the nitriding reaction activation energy. It is established that TiN forms even at 250°C. It is detected that the size of TiN crystal blocks formed depends on temperature. A nitriding mechanism is proposed.

Keywords

titanium nitride nitriding iodine iodide transport crystal structure parameters 
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References

  1. 1.
    G. V. Samsonov, Nitrides [in Russian], Naukova Dumka, Kiev (1969).Google Scholar
  2. 2.
    L. Tom, Transition Metal Carbides and Nitrides [in Russian], Mir, Moscow 91974).Google Scholar
  3. 3.
    G. V. Samsonov and I. M. Vinitskii, Refractory Compounds [in Russian], Metallurgiya, Moscow (1986).Google Scholar
  4. 4.
    Yu. Yu. Tret’yakov, Plasmachemical Reactions and Processes [in Russian], Nakua, Moscow (1977).Google Scholar
  5. 5.
    G. V. Samsonov, O. P. Kulik, and V. S. Polishchuk, Nitride Preparation and Analysis Methods [in Russian], Naukova Dumka, Kiev, (1978).Google Scholar
  6. 6.
    G. G. Gnesin, I. I. Osipova, G. D. Rontal’, et al., Ceramic Tool Materials [in Russian], Tekhnika, Kiev (1991).Google Scholar
  7. 7.
    Xiaowei Yin, I. Gotman, L. Klinger, and E. Y. Gutmanas, “Formation of titanium carbide on graphite via powder immersion reaction assisted coating,” Mater. Sci. Eng., A, No. 396, 107 – 114 (2005).Google Scholar
  8. 8.
    S. P. Bogdanov, “Intensification of solid phase reaction by iodine transport,” Fiz. Khim. Stekla, 39(4), 638 – 642 (2013).Google Scholar
  9. 9.
    S. P. Bogdanov, “Synthesis of solid solutions in iodine metal systems by iodine transport,” Fiz. Khim. Stekla, 39(4), 643 – 648 (2013).Google Scholar
  10. 10.
    S. P. Bogdanov, “Iodide transport – method of synthesis of inorganic materials,” Smart Nanocomposites, 5(1), 1 – 8 (2014).Google Scholar
  11. 11.
    L. M. Kovba and V. K. Trunov, x-ray Phase Analysis [in Russian], MGU, Moscow (1969).Google Scholar
  12. 12.
    S. P. Bogdanov, “Effect of boron impurity on the crystal structure of cBN,” Fiz. Khim. Stekla, 34(2), 281 – 288 (2008).Google Scholar
  13. 13.
    R. F. Rolsten, Iodided Metals and Metal Iodides [in Russian], Metallurgiya, Moscow (1968).Google Scholar
  14. 14.
    S. P. Bogdanov, “Preparation of coatings on powders by iodine transport,” Fiz. Khim. Stekla, 37(2), 229 – 237 (2011).Google Scholar
  15. 15.
    S. P. Bogdanov, “Iodine-transport method of preparing coatings on powders,” Izv. SPbGTI (TU), No. 16 (42), 24 – 28 (2012).Google Scholar

Copyright information

© Springer Science+Business Media New York 2015

Authors and Affiliations

  1. 1.FGBOU VPO St. Petersburg State Technological UniversitySt. PetersburgRussia

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