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Reaction Kinetics, Mechanisms and Catalysis

, Volume 128, Issue 2, pp 1097–1109 | Cite as

Catalytic oxidation of isoamyl alcohol on modified ZSM-5 molecular sieve catalysts prepared by different methods

  • Beibei He
  • Mengran Zhang
  • Binxia ZhaoEmail author
  • Linxue Liu
  • Wenbin Guan
  • Naining Hu
Article
  • 25 Downloads

Abstract

Cr-modified ZSM-5 molecular sieve catalysts were prepared by the methods of hydrothermal technique [Cr-ZSM-5(H)], ion-exchange [Cr-ZSM-5(E)] and impregnation [Cr-ZSM-5(I)], the catalytic performance of the prepared catalysts in the process of isoamyl alcohol to isovaleric acid was investigated, and their physicochemical properties were characterized by XRD, FT-IR, BET, SEM and TG. The results showed that the catalyst Cr-ZSM-5(H) exhibited higher activity with isoamyl alcohol conversion of 44.97%, isovaleric acid selectivity of 78.78% and isovaleric acid yield of 35.43%, superior to Cr-ZSM-5(E) and Cr-ZSM-5(I), because of its suitable pore diameter, slower deposition rate, and more Cr-incorporation.

Keywords

ZSM-5 Catalyst Isoamyl alcohol Isovaleric acid Cr 

Notes

Acknowledgements

This work was supported by the key research and development program of Shaanxi, China (2018GY-067).

Supplementary material

11144_2019_1686_MOESM1_ESM.docx (109 kb)
Supplementary material 1 (DOCX 110 kb)

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Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2019

Authors and Affiliations

  • Beibei He
    • 1
  • Mengran Zhang
    • 2
  • Binxia Zhao
    • 1
    Email author
  • Linxue Liu
    • 1
  • Wenbin Guan
    • 3
  • Naining Hu
    • 1
  1. 1.School of Chemical EngineeringNorthwest UniversityXi’anChina
  2. 2.School of Urban Planning and Municipal EngineeringXi’an Polytechnic UniversityXi’anChina
  3. 3.Shaanxi Coal Chemical Technology Engineering Centre Co.Xi’anChina

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