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Fe-Sb mixed oxide with high performance for the selective catalytic reduction NO with NH3

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Abstract

Fe-Sb mixed metal oxides were tested as potential catalysts of selective catalytic reduction of NO with NH3 (NH3-SCR). The novel catalyst FeSbOδ showed high catalytic activity and N2 selectivity in the temperature range from 200 to 400 °C. XRD results hinted that a new phase of FeSbO4 was formed in the Fe-Sb based catalysts. NH3-TPD, H2-TPR and in situ DRIFTS results also suggested that there is a synergetic effect between Fe and Sb species. The effect not only increases the acidity of the catalyst surface, but also enhances the redox properties of the catalysts, and all of these enhancements were responsible for the high NH3-SCR performance.

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Acknowledgements

We gratefully acknowledge the financial support of Science Foundation of Fujian Province (No. 2017J01568).

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Authors and Affiliations

  1. School of Materials Science and Engineering, Beijing Institute of Fashion Technology, Beijing, 100029, China

    Zhe Wang & Xiuyan Li

  2. Fujian Indoor Environmental Engineering Technology Research Center, Fujian University of Technology, Fuzhou, 350118, China

    Ronghui Shi

  3. Chemical Safety Institute of Fujian University of Technology, Fuzhou, 350118, China

    Ronghui Shi

Authors
  1. Zhe Wang
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  2. Xiuyan Li
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  3. Ronghui Shi
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Correspondence to Ronghui Shi.

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Wang, Z., Li, X. & Shi, R. Fe-Sb mixed oxide with high performance for the selective catalytic reduction NO with NH3. Reac Kinet Mech Cat 127, 437–447 (2019). https://doi.org/10.1007/s11144-019-01568-y

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  • DOI: https://doi.org/10.1007/s11144-019-01568-y

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