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Unified catalytic oxidation–adsorption desulfurization for aromatic sulfur compounds with cyclohexanone peroxide over Ti-HMS

  • Xingqi Lin
  • Xingye Zeng
  • Rujin Zhou
  • Hanlu Wang
Article
  • 15 Downloads

Abstract

Three kinds of Ti-HMS zeolites have been synthesized by using different templates, and their catalytic performance was investigated in deep oxidation-adsorption desulfurization process. Various analysis techniques have been applied to investigate physical and chemical properties of the catalysts. Using cyclohexanone peroxide as an oxidant, the catalytic performance results show that Ti-HMS-12 exhibits highest desulfurization performance (99.9%) without solvents. Dibenzothiophene (DBT) was almost completely oxidized to the more polar DBT sulfone, which could be subsequently adsorbed on the Ti-HMS-12, achieving a unified processes of oxidative-adsorption desulfurization process. Furthermore, the catalyst was recycled for five runs with slight decreases in the catalytic performance and can be easily regenerated by methanol washing.

Keywords

Ti-HMS Solvent Adsorption Oxidation Desulfurization 

Notes

Acknowledgements

This work was supported by the Training Program for Outstanding Young Teachers in Universities in Guangdong Province (Grant No. YQ2015116), and Maoming Public Service Platform for transformation upgrading and Technological Innovation of Petrochemical Industry (2016B020211002), the National Natural Science Foundation of China (Grant No. 21403038), the Natural Science Foundation of Guangdong Province (Grant No. 2015A030313892).

Supplementary material

11144_2018_1520_MOESM1_ESM.docx (2.3 mb)
Supplementary material 1 (DOCX 2355 kb)

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Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2018

Authors and Affiliations

  • Xingqi Lin
    • 1
  • Xingye Zeng
    • 1
  • Rujin Zhou
    • 1
  • Hanlu Wang
    • 1
  1. 1.College of Chemical EngineeringGuangdong University of Petrochemical TechnologyMaomingPeople’s Republic of China

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