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Reaction Kinetics, Mechanisms and Catalysis

, Volume 126, Issue 2, pp 601–610 | Cite as

Ketonization kinetics of stearic acid

  • Dmitry Yu. MurzinEmail author
  • Andreas Bernas
  • Johan Wärnå
  • Jukka Myllyoja
  • Tapio Salmi
Article
  • 70 Downloads

Abstract

The ketonization of stearic acid was investigated in a stainless steel reactor under catalyst-free conditions. The reaction was selective towards formation of 18-pentatriacontanone following quasi-zero kinetics. A reaction mechanism explaining such behavior is discussed.

Keywords

Ketonization Thermal Kinetics Stearic acid 

References

  1. 1.
    Srivastava A, Prasad R (2000) Renew Sust Energy Rev 4:111–133CrossRefGoogle Scholar
  2. 2.
    Bozell JJ, Petersen GR (2010) Green Chem 12:539–554CrossRefGoogle Scholar
  3. 3.
    Alonso DM, Bond JQ, Dumesic JA (2010) Green Chem 12:1493–1513CrossRefGoogle Scholar
  4. 4.
    Murzin DYu, Simakova IL (2013) In: Schlögl R, Niemantsverdriet JW (eds) Comprehensive inorganic chemistry II. From elements to applications, vol 7. Elsevier, Amsterdam, pp 559–586CrossRefGoogle Scholar
  5. 5.
    Corma A, Iborra S, Velty A (2007) Chem Rev 107:2411–2502CrossRefGoogle Scholar
  6. 6.
    Murzin DYu, Mäki-Arvela P, Simakova IL (2012) Kirk-Othmer encyclopedia of chemical technology. Wiley, New York.  https://doi.org/10.1002/0471238961.trigmurz.a01 Google Scholar
  7. 7.
    Simakova IL, Murzin DYu (2016) J Energy Chem 25:208–224CrossRefGoogle Scholar
  8. 8.
    Kupareva A, Mäki-Arvela P, Murzin DYu (2013) J Chem Technol Biotechnol 88:1780–1793CrossRefGoogle Scholar
  9. 9.
    Murzin DYu (2018) Chemical product technology. DeGruyter, BerlinCrossRefGoogle Scholar
  10. 10.
    IG Farben (1939) Patent GB 506678 19390602Google Scholar
  11. 11.
    Curtis RG, Dobson AG, Hatt HH (1947) J Soc Chem Ind Trans Commun 66:402–407CrossRefGoogle Scholar
  12. 12.
    Corma A, Renz M, Schaverien C (2008) ChemSusChem 1:739–741CrossRefGoogle Scholar
  13. 13.
    Oliver-Tomas B, Renz M, Corma A (2017) Ind Eng Chem Res 56:12870–12877CrossRefGoogle Scholar
  14. 14.
    Back O, Leroy R, Marion P (2018) PCT international applications WO 2018087181 A1 20180517Google Scholar
  15. 15.
    Renz M (2005) Eur J Org Chem 2005:979–988CrossRefGoogle Scholar
  16. 16.
    Pham TN, Sooknoi T, Crossley SP, Resasco DE (2013) ACS Catal 3:2456–2473CrossRefGoogle Scholar
  17. 17.
    Pham TN, Shi D, Resasco DE (2014) Top Catal 57:706–714CrossRefGoogle Scholar
  18. 18.
    Pham TN, Shi D, Resasco DE (2014) J Catal 314:149–158CrossRefGoogle Scholar
  19. 19.
    Gaertner CA, Serrano-Ruiz JC, Braden DJ, Dumesic JA (2010) Ind Eng Chem Res 49:6027–6033CrossRefGoogle Scholar
  20. 20.
    Murzin DYu, Salmi T (2016) Catalytic kinetics. Elsevier, AmsterdamGoogle Scholar
  21. 21.
    Haario H (2001) Modest 6.0—a user’s guide. ProfMath, HelsinkiGoogle Scholar

Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2018

Authors and Affiliations

  • Dmitry Yu. Murzin
    • 1
    Email author
  • Andreas Bernas
    • 1
  • Johan Wärnå
    • 1
  • Jukka Myllyoja
    • 2
  • Tapio Salmi
    • 1
  1. 1.Johan Gadolin Process Chemistry CentreÅbo Akademi UniversityÅbo/TurkuFinland
  2. 2.Neste CorpPorvooFinland

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