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Reaction Kinetics, Mechanisms and Catalysis

, Volume 124, Issue 2, pp 741–755 | Cite as

A novel sulfamic acid functionalized nano-catalyst on the basis of calix[4]resorcinarene for the green one-pot synthesis of 2H-indazolo[2,1-b]phthalazine-triones under thermal solvent-free conditions

  • Arash Mouradzadegun
  • Mahsa Alsadat Mostafavi
  • Mohammad Reza Ganjali
Article
  • 80 Downloads

Abstract

N-propyl sulfamic acid supported nano-catalyst on the basis of calix[4]resorcinarene was prepared via the efficient and facile reaction of amine functionalized polycalix[4]resorcinarene with chlorosulfonic acid. The achieved catalytic system was characterized using some spectroscopic techniques such as Fourier transform Infrared (FT-IR) spectroscopy, field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), and CHNS elemental analysis. This newly developed acidic catalyst was employed efficiently in a one-pot three-component condensation reaction of aromatic aldehydes, dimedone and phthalhydrazide for the synthesis of 2H-indazolo[2,1-b]phthalazine-trione derivatives through an easy and eco-friendly methodology. The catalyst was easily separated from the reaction mixture by simple filtration and the desired products were achieved in good to excellent yields in short reaction times.

Keywords

N-propyl sulfamic acid functionalized nano-catalyst Heterogeneous catalysis Multi-component reactions Solvent-free One-pot condensation 2H-indazolo[2,1-b]phthalazine-triones 

Notes

Acknowledgements

This work was supported by the Research Council at the University of Shahid Chamran.

Supplementary material

11144_2018_1363_MOESM1_ESM.pdf (1.9 mb)
Supplementary material 1 (PDF 1954 kb)

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Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2018

Authors and Affiliations

  • Arash Mouradzadegun
    • 1
    • 2
  • Mahsa Alsadat Mostafavi
    • 1
  • Mohammad Reza Ganjali
    • 2
    • 3
  1. 1.Department of Chemistry, Faculty of ScienceShahid Chamran UniversityAhvazIran
  2. 2.Center of Excellence in Electrochemistry, Faculty of ChemistryUniversity of TehranTehranIran
  3. 3.Biosensor Research Center, Endocrinology & Metabolism Molecular-Cellular Sciences InstituteTehran University of Medical SciencesTehranIran

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