Reaction Kinetics, Mechanisms and Catalysis

, Volume 120, Issue 1, pp 81–94 | Cite as

Kinetic studies and optimization of abies wood fractionation by hydrogen peroxide under mild conditions with TiO2 catalyst

  • B. N. Kuznetsov
  • I. G. Sudakova
  • N. V. Garyntseva
  • L. Djakovitch
  • C. Pinel
Article
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Abstract

The kinetic study of abies wood delignification by H2O2 in the medium acetic acid–water was first carried out in the presence of TiO2 catalyst under mild conditions: temperatures 70–100 °C, atmospheric pressure. The oxidative delignification process is described satisfactory by the first order equation in all temperature range. The rate constants varied between 0.80 and 12.3 × 10−3 min−1 and the activation energy was near 81 ± 0.21 kJ mol−1. The optimal parameters of the delignification process, providing the effective fractionation of abies wood on microcrystalline cellulose and soluble lignin, were established by experimental and numerical methods.

Keywords

Abies wood Oxidative fractionation Hydrogen peroxide TiO2 catalyst Kinetics Optimization 
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Notes

Acknowledgements

The reported study was supported by the Russian Science Foundation (Grant No. 16-13-10326).NMR experiments were conducted on BrukerAvance III spectrometer at Krasnoyarsk Regional Centre of Research Equipment SB RAS. The authors wish to thank Alexander Kondrasenko for the help with NMR experiments.

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Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2016

Authors and Affiliations

  • B. N. Kuznetsov
    • 1
    • 2
  • I. G. Sudakova
    • 1
  • N. V. Garyntseva
    • 1
  • L. Djakovitch
    • 3
  • C. Pinel
    • 3
  1. 1.Institute of Chemistry and Chemical Technology SB RASFederal Research Center KSC SB RASKrasnoyarskRussia
  2. 2.Siberian Federal UniversityKrasnoyarskRussia
  3. 3.IRCELYONVilleurbanne Cedex, LyonFrance

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