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Study of Pt and Rh based supported catalysts modified with tetrabutyltin for the selective hydrogenation of 4-methoxyacetophenone

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Abstract

Catalysts based on Pt and Rh modified with Sn(C4H9)4 were studied in the hydrogenation of 4-methoxyacetophenone. The selectivity to 1-(4-methoxyphenyl)ethanol was close to 100% at Sn/(Pt,Rh) = 1.0, however the catalytic activity decreased drastically. With respect to the balance between activity and selectivity the catalyst PtSnOM (Sn/Pt=0.4) showed the best performance.

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Authors and Affiliations

  1. Centro de Investigación y Desarrollo en Ciencias Aplicadas “Dr. Jorge J. Ronco” (CINDECA) (UNLP, CONICET), Facultad de Ciencias Exactas, Universidad Nacional de La Plata, 47 N° 257, 1900, La Plata, Argentina

    Virginia Vetere, Mónica L. Casella & Osmar A. Ferretti

  2. Chemical Research Center, Institute of Surface Chemistry and Catalysis, Hungarian Academy of Sciences, Pusztaszeri út 59-67, Budapest, 1025, Hungary

    Emilia Tálas & Sándor Gőbölös

  3. Facultad de Ingeniería, Universidad Nacional de La Plata, 47 N° 257, 1900, La Plata, Argentina

    Osmar A. Ferretti

Authors
  1. Virginia Vetere
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  2. Mónica L. Casella
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  3. Emilia Tálas
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  4. Sándor Gőbölös
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  5. Osmar A. Ferretti
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Correspondence to Mónica L. Casella.

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Vetere, V., Casella, M.L., Tálas, E. et al. Study of Pt and Rh based supported catalysts modified with tetrabutyltin for the selective hydrogenation of 4-methoxyacetophenone. React Kinet Catal Lett 92, 183–193 (2007). https://doi.org/10.1007/s11144-007-5130-4

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  • DOI: https://doi.org/10.1007/s11144-007-5130-4

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