Structural analysis of Zn2TiO4 doped with MgO
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The starting mixtures of ZnO, TiO2, and MgO (0, 1.25, and 2.5 wt.%) powders are mechanically activated in a high-energy planetary mill for 15 min and then sintered between 800 and 1100°C for 2 h. The influence of MgO addition on the structure of the samples obtained is analyzed with X-ray diffraction and infrared reflection spectroscopy. Room-temperature far-infrared reflectivity spectra of the samples doped with MgO (0, 1.25, and 2.5 wt.%) and sintered at 1100°C in the frequency range between 100 and 1200 cm–1 are measured and analyzed. Optical parameters are determined for seven oscillators belonging to the spinel structure using the four-parameter model of coupled oscillators. Born effective charges are calculated from the transversal/longitudinal splitting.
Keywordszinc titanate magnesium oxide powders sintering mechanical activation X-ray diffraction infrared reflection spectroscopy structure
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- 1.N. N. Lysova, L. P. Shapavalova, and V. P. Luk’yanenko, Inorg. Mater., 27, 542–544 (1991).Google Scholar
- 2.K. S. Walton and R. K. Datta, Ceram. Trans., 61, 637–644 (1995).Google Scholar
- 3.M. M. Mikhailov and M. I. Dvoretskii, Inorg. Mater., 27, 2021–2025 (1991).Google Scholar
- 9.R. L. Millard, R. C. Peterson, and B. K. Hunter, Am. Mineralogist, 80, 885–896 (1995).Google Scholar
- 11.A. C. Larson and R. B. Von Dreele, General Structure Analysis System (GSAS): Report LAUR 86-748, Los Alamos National Laboratory (2004).Google Scholar
- 13.S. C. Abrahams and J. L. Bernstein, Acta Crystallog., B25, 1233–1236 (1969).Google Scholar