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Plasma Chemistry and Plasma Processing

, Volume 39, Issue 1, pp 143–163 | Cite as

Effect of the Reaction Temperature on the Removal of Diesel Particulate Matter by Ozone Injection

  • Runlin Fan
  • Yixi Cai
  • Yunxi ShiEmail author
  • Yingxin Cui
Original Paper
  • 72 Downloads

Abstract

This study seeks to investigate the removal efficiency of particulate matter (PM) from the actual diesel exhaust at various reaction temperatures by using non-thermal plasma (NTP). The effect of the reaction temperature on removal efficiency was reflected by the change in the concentration of particles in different modes and the weight fraction of volatile organics in PM. The Arrhenius equation was used to determine the apparent activation energies Ea of the soot in PM. In addition, the difference in the oxidation reaction at various reaction temperatures and the effect of NTP on the properties of PM were discussed. After considering the decreasing ranges of the total concentration and the weight of the PM, it was determined that 120 °C is the optimal temperature choice for PM removal. The decreasing range of the total concentration reached 57.13% and 66.79% of PM was removed when the PM is measured by weight. NTP has better effect on the removal of smaller particles. The weight fraction of the volatile fraction markedly decreases after the reaction and the apparent activation energy of soot noticeably decreased. The oxidizability of the excited species in NTP was enhanced with the increase of the reaction temperature. However, the excited species concentration declined concurrently, resulting in the occurrence of the optimized range of reaction temperature. The particles were removed by the oxidation that occurred on the surface of the primary particle and the disintegration of the structure of the particles.

Keywords

Non-thermal plasma Particulate matter Temperature Oxidative activity Size distribution Thermos-gravimetric analysis 

Notes

Acknowledgements

This research was supported primarily by the National Natural Science Foundation of China (Nos. 51806085, 51676089), the Major projects of natural science research in colleges and universities in Jiangsu Province (No. 16KJA470002), and the Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions (PADA).

Compliance with Ethical Standards

Conflict of interest

The authors declare no competing financial interest.

Supplementary material

11090_2018_9947_MOESM1_ESM.pdf (114 kb)
Supplementary material 1 (PDF 113 kb)

References

  1. 1.
    Babaie M, Davari P, Zare F, Rahman MM, Rahimzadeh H, Ristovski Z et al (2013) Effect of pulsed power on particle matter in diesel engine exhausting a DBD plasma reactor. IEEE Trans Plasma Sci 41(8):2349–2358Google Scholar
  2. 2.
    Bensaid S, Marchisio DL, Fino D (2010) Numerical simulation of soot filtration and combustion within diesel particulate filters. Chem Eng Sci 65(1):357–363Google Scholar
  3. 3.
    Sun Y, Bochmann F, Nold A, Mattenklott M (2014) Diesel exhaust exposure and the risk of lung cancer—a review of the epidemiological evidence. Int J Environ Res Pub Health 11(2):1312–1340Google Scholar
  4. 4.
    Mohankumara S, Senthilkumarb P (2017) Particulate matter formation and its control methodologies for diesel engine: a comprehensive review. Renew Sustain Energy Rev 80:1227–1238Google Scholar
  5. 5.
    Mei C, Mei D, Chen Z, Yuan Y (2017) Characteristics of diesel particulates based on fractal theory and carbon analysis. Trans CSICE 35(2):131–135Google Scholar
  6. 6.
    Mokhri MA, Abdullah NR, Abdullah SA, Kasalong S, Mamat R (2012) Soot filtration recent simulation analysis in diesel particulate filter (DPF). Procedia Eng 41:1750–1755Google Scholar
  7. 7.
    Palma V, Ciambelli P, Meloni E, Sin A (2015) Catalytic DPF microwave assisted active regeneration. Fuel 140:50–61Google Scholar
  8. 8.
    Palma V, Ciambelli P, Meloni E, Sin A (2013) Study of the catalyst load for a microwave susceptible catalytic DPF. Catal Today 216(6):185–193Google Scholar
  9. 9.
    Chen K, Martirosyan KS, Luss D (2011) Counter-intuitive temperature excursions during regeneration of a diesel particulate filter. AIChE J 57(8):2229–2236Google Scholar
  10. 10.
    Beatrice C, Iorio SD, Guido C, Napolitano P (2012) Detailed characterization of particulate emissions of an automotive catalyzed DPF using actual regeneration strategies. Exp Therm Fluid Sci 39(5):45–53Google Scholar
  11. 11.
    Bensaid S, Marchisio DL, Fino D, Saracco G, Specchia V (2009) Modelling of diesel particulate filtration in wall-flow traps. Chem Eng J 154(1–3):211–218Google Scholar
  12. 12.
    Ranji-Burachaloo H, Masoomi-Godarzi S, Khodadadi AA, Mortazavi Y (2016) Synergetic effects of plasma and metal oxide catalysts on diesel soot oxidation. Appl Catal B Environ 182:74–84Google Scholar
  13. 13.
    Pu X, Cai Y, Shi Y, Wang J, Gu L, Tian J et al (2017) Diesel particulate filter (DPF) regeneration using non-thermal plasma induced by dielectric barrier discharge. J Energy Inst.  https://doi.org/10.1016/j.joei.2017.06.004 Google Scholar
  14. 14.
    Ma C, Gao J, Zhong L, Xing S (2016) Experimental investigation of the oxidation behavior and oxidation kinetics of diesel particulate matter with non-thermal plasma. Appl Therm Eng 99:1110–1118Google Scholar
  15. 15.
    Thomas SE, Martin AR, Raybone D, Shawcross J Non thermal Plasma after-treatment of particulates-theoretical limits and impact on reactor design. SAE Technical Paper. 2000-01-1926Google Scholar
  16. 16.
    Kuwahara T, Nakaguchi H, Kuroki T, Okubo M (2016) Continuous reduction of cyclic adsorbed and desorbed NOx in diesel emission using non-thermal plasma. J Hazard Mater 308:216–224Google Scholar
  17. 17.
    Okubo M, Arita N, Kuroki T, Yoshida K, Yamamoto T (2008) Total diesel emission control technology using ozone injection and plasma desorption. Plasma Chem Plasma Process 28(2):173–187Google Scholar
  18. 18.
    Kuwahara T, Nishii S, Kuroki T, Okubo M (2013) Complete regeneration characteristics of diesel particulate filter using ozone injection. Appl Energy 111(11):652–656Google Scholar
  19. 19.
    Yao S, Kodama S, Yamamoto S, Fushimi C (2009) Characterization of an uneven DBD reactor for diesel PM removal. Asia-Pac J Chem Eng 5(5):701–707Google Scholar
  20. 20.
    Shi Y, Cai Y, Li X (2014) Mechanism and method of DPF regeneration by oxygen radical generated by NTP technology. Int J Automot Technol 15(6):871–876Google Scholar
  21. 21.
    Yao S, Shen X, Zhang X, Han J, Wu Z, Tan X et al (2017) Sustainable removal of particulate matter from diesel engine exhaust at low temperature using a plasma-catalytic method. Chem Eng J 327:343–350Google Scholar
  22. 22.
    Mao L, Chen Z, Wu X, Tang X, Yao S, Zhang X et al (2018) Plasma-catalyst hybrid reactor with CeO2/γ-Al2O3 for benzene decomposition with synergetic effect and nano particle by-product reduction. J Hazard Mater 347:150–159Google Scholar
  23. 23.
    Gu L, Cai Y, Shi Y, Wang J, Pu X, Tian J, Fan R (2017) Effect of indirect non-thermal plasma on particle size distribution and composition of diesel engine particles. Plasma Sci Technol 19(11):59–66Google Scholar
  24. 24.
    Babaie M, Davari P, Talebizadeh P, Zare F, Rahimzadeh H, Ristovski Z et al (2015) Performance evaluation of non-thermal plasma on particulate matter ozone and CO2 correlation for diesel exhaust emission reduction. Chem Eng J 276(2):240–248Google Scholar
  25. 25.
    Gao J, Ma C, Xing S, Sun L (2016) Raman characteristics of PM emitted by a diesel engine equipped with a NTP reactor. Fuel 185:289–297Google Scholar
  26. 26.
    Wang P, Gu W, Lei L, Cai Y, Li Z (2015) Micro-structural and components evolution mechanism of particular matter from diesel engines with non-thermal plasma technology. Appl Therm Eng 91:1–10Google Scholar
  27. 27.
    Meng Z, Yang D, Yan Y (2014) Study of carbon black oxidation behavior under different heating rates. J Therm Anal Calorim 118:551–559Google Scholar
  28. 28.
    Seong HJ, Boehman AL (2013) Evaluation of Raman parameters using visible ramanmicroscopy for soot oxidative reactivity. Energy Fuels 27:1613–1624Google Scholar
  29. 29.
    Zhao Y, Wang Z, Liu S, Li RN, Li MD (2015) Experimental study on the oxidation reaction parameters of different carbon structure particles. Environ Prog Sustain Energy 34:1063–1071Google Scholar
  30. 30.
    Vander Wal RL, Yezerets A, Currier NW, Kim DH, Wang CM (2007) HRTEM study of diesel soot collected from diesel particulate filters. Carbon 45:70–77Google Scholar
  31. 31.
    Ye P, Sun C, Lapuerta M, Agudelo J, Vander Wal RL, Boehman A et al (2014) Impact of rail pressure and biodiesel fueling on the particulate morphology and soot nanostructures from a common-rail turbocharged direct injection diesel engine. Int J Engine Res 40:57–65Google Scholar
  32. 32.
    Agudelo JR, Álvarez A, Armas O (2014) Impact of crude vegetable oils on the oxidation reactivity and nanostructure of diesel particulate matter. Combust Flame 161:2904–2915Google Scholar
  33. 33.
    Chien YC, Lu M, Chai M, Boreo FJ (2008) Characterization of biodiesel and biodiesel particulate matter by TG, GC/MS, and FTIR. Energy Fuels 23:202–206Google Scholar
  34. 34.
    Liati A, Spiteri A, Eggenschwiler PD, Vogel-Schäuble N (2012) Microscopic investigation of soot and ash particulate matter derived from biofuel and diesel: implications for the reactivity of soot. J Nanoparticle Res 14:1–18Google Scholar
  35. 35.
    Ruiz FA, Cadrazco M, López AF, Sanchez-Valdepeñas J, Agudelo JR (2015) Impact of dual-fuel combustion with n-butanol or hydrous ethanol on the oxidation reactivity and nanostructure of diesel particulate matter. Fuel 161:18–25Google Scholar
  36. 36.
    Sharma HN, Pahalagedara L, Joshi A, Suib SL, Mhadeshwar AB (2012) Experimental study of carbon black and diesel engine soot oxidation kinetics using thermogravimetric analysis. Energy Fuel 26:5613–5625Google Scholar
  37. 37.
    Marta O, Gómez X, García AI, Morán A (2008) Non-isothermal thermogravimetric analysis of the combustion of two different carbonaceous materials. J Therm Anal Calorim 93(2):619–626Google Scholar
  38. 38.
    Collura S, Chaoui N, Azambre B, Finqueneisel G, Heintz O, Krzton A et al (2005) Influence of the soluble organic fraction on the thermal behaviour, texture and surface chemistry of diesel exhaust soot. Carbon 43:605–613Google Scholar
  39. 39.
    Yagi S, Tanaka M (2001) Mechanism of ozone generation in air-fed ozonizes. J Phys D Appl Phys 9:1509Google Scholar
  40. 40.
    López-Fonseca R, Landa I, Gutiérrez-Ortiz MA, González-Velasco JR (2005) Non-isothermal analysis of the kinetics of the combustion of carbonaceous materials. J Therm Anal Calorim 80(1):65–69Google Scholar
  41. 41.
    Cheng HKF, Chong MF, Liu E, Zhou K, Li L (2014) Thermal decomposition kinetics of multiwalled carbon nanotube/polypropylene nanocomposites. Therm Anal Calorim 117:63–71Google Scholar
  42. 42.
    Kalogirou M, Samaras ZJ (2009) A thermogravimetric kinetic study of uncatalyzed diesel soot oxidation. Therm Anal Calorim 98(1):215–224Google Scholar
  43. 43.
    Yezerets A, Currier NW, Eadler HA (2003) Investigation of the oxidation behavior of diesel particulate matter. Catal Today 88(1):17–25Google Scholar
  44. 44.
    Meng Z, Yang D, Yan Y, Han W (2016) Comparison of oxidation characteristics analysis between diesel soot and carbon black. J Comput Sci Technol 22(1):71–76Google Scholar
  45. 45.
    Alfè M, Apicella B, Rouzaud JN, Tregrossi A, Ciajolo A (2010) The effect of temperature on soot properties in premixed methane flames. Combust Flame 157(10):1959–1965Google Scholar
  46. 46.
    Randy L, Wal Vander (2006) Initial investigation of effects of fuel oxygenation on nanostructure of soot from a direct-injection diesel engine. Energy Fuel 20(6):2364–2369Google Scholar
  47. 47.
    Gao J, Ma C, Xing S, Sun L (2017) Oxidation behaviors of particulate matter emitted by a diesel engine equipped with a NTP device. Appl Therm Eng 119:593–602Google Scholar
  48. 48.
    Ishiguro T, Suzuki N, Fujitani Y, Morimoto H (1991) Microstructural changes of diesel soot during oxidation. Combust Flame 85(1):1–6Google Scholar
  49. 49.
    Song J, Alam M, Boehman AL, Kim U (2006) Examination of the oxidation behavior of biodiesel soot. Combust Flame 146(4):589–604Google Scholar

Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  1. 1.School of Automotive and Traffic EngineeringJiangsu UniversityZhenjiangChina

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