Plasma Chemistry and Plasma Processing

, Volume 35, Issue 5, pp 863–878 | Cite as

Characterization of Physical, Mechanical and Chemical Properties of Quiscal Fibres: The Influence of Atmospheric DBD Plasma Treatment

  • Catia Relvas
  • Gastón Castro
  • Sohel Rana
  • Raul Fangueiro
Original Paper

Abstract

This paper reports the first attempt of characterizing various physical, mechanical and chemical properties of Quiscal fibres, used by the native communities in Chile and investigating the influence of atmospheric dielectric barrier discharge plasma treatment on various properties such as diameter and linear density, fat, wax and impurity%, moisture regain, chemical elements and groups, thermal degradation, surface morphology, etc. According to the experimental observations, Quiscal fibre has lower tenacity than most of the technical grade natural fibres such as sisal, hemp, flax, etc., and plasma treatment at optimum dose improved its tenacity to the level of sisal fibres. Plasma treatment also reduced the amount of fat, wax and other foreign impurities present in Quiscal fibres as well as removed lignin and hemicellulose partially from the fibre structure. Plasma treatment led to functionalization of Quiscal fibre surface with chemical groups, as revealed from attenuated total reflection spectroscopy and also confirmed from the elemental analysis using energy dispersive X-ray technique and pH and conductivity measurements of fibre aqueous extract. The wetting behavior of Quiscal fibre also improved considerably through plasma treatment. However, untreated and plasma treated Quiscal fibres showed similar thermal degradation behavior, except the final degradation stage, in which plasma treated fibres showed higher stability and incomplete degradation unlike the untreated fibres. The experimental results suggested that the plasma treated Quiscal fibres, like other technical grade natural fibres, can find potential application as reinforcement of composite materials for various industrial applications.

Keywords

Quiscal fibre Mechanical properties Plasma treatment Thermal degradation Surface morphology 

References

  1. 1.
    Ragoubia M, Bienaiméb D, Molinaa S, Georgea B, Merlina A (2010) Impact of corona treated hemp fibres onto mechanical properties of polypropylene composites made thereof. Ind Crops Prod 31:344–349CrossRefGoogle Scholar
  2. 2.
    Rana S, Pichandi S, Parveen S, Fangueiro R (2014) Natural plant fibers: production, processing, properties and their sustainability parameters. In: Muthu SS (ed) Roadmap to sustainable textiles and clothing: eco-friendly raw materials, technologies, and processing methods. Springer, Singapore, pp 1–35Google Scholar
  3. 3.
    Rana S, Pichandi S, Parveen S, Fangueiro R (2014) Regenerated cellulosic fibers and their implications on sustainability. In: Muthu SS (ed) Roadmap to sustainable textiles and clothing: eco-friendly raw materials, technologies, and processing methods. Springer, Singapore, pp 239–276Google Scholar
  4. 4.
    Rana S, Pichandi S, Parveen S, Fangueiro R (2014) Biosynthetic fibers: production, processing, properties and their sustainability parameters. In: Muthu SS (ed) Roadmap to sustainable textiles and clothing: eco-friendly raw materials, technologies, and processing methods. Springer, Singapore, pp 109–138Google Scholar
  5. 5.
    Rana S, Pichandi S, Parveen S, Fangueiro R (2014) Biodegradation studies of textiles and clothing products. In: Muthu SS (ed) Roadmap to sustainable textiles and clothing: environmental and social aspects of textiles and clothing supply chain. Springer, Singapore, pp 83–123Google Scholar
  6. 6.
    Rana S, Pichandi S, Karunamoorthy S, Bhattacharyya A, Parveen S, Fangueiro R (2015) Carbon footprint of textile and clothing products. In: Muthu SS (ed) Handbook of sustainable apparel production. CRC Press, Boca RatonGoogle Scholar
  7. 7.
    Xie Y, Hill CAS, Xiao Z, Militz H, Mai C (2010) Silane coupling agents used for natural fiber/polymer composites: a review. Compos Part A-Appl Sci Manuf 41:806–819CrossRefGoogle Scholar
  8. 8.
    Morent R, De Geyter N, Verschuren J, De Clerck K, Kiekens P, Leys C (2008) Non-thermal plasma treatment of textiles. Surf Coat Technol 202:3427–3449CrossRefGoogle Scholar
  9. 9.
    Kamlangkla K, Hodak SK, Levalois-Grützmacher J (2011) Multifunctional silk fabrics by means of the plasma induced graft polymerization (PIGP) process. Surf Coat Technol 205:3755–3762CrossRefGoogle Scholar
  10. 10.
    Tsafack MJ, Levalois-Grützmacher J (2006) Plasma-induced graft-polymerization of flame retardant monomers onto PAN fabrics. Surf Coat Technol 200:3503–3510CrossRefGoogle Scholar
  11. 11.
    Tsafack MJ, Levalois-Grützmacher J (2007) Towards multifunctional surfaces using the plasma-induced graft-polymerization (PIGP) process: flame and waterproof cotton textiles. Surf Coat Technol 201:5789–5795CrossRefGoogle Scholar
  12. 12.
    Fangueiro R, Moreno EV, Klingler GC, Reategui JV, Ramos JB (2010) Characterization of natural fibres used by native communities in Latin America, Autex 2010 World Textile Conference, 21–23 June, 2010, Vilnius, LithuaniaGoogle Scholar
  13. 13.
    Fangueiro R, Oliveira F, Erkens L, Souto A (2012) Surface modification of banana fibers by DBD plasma treatment. Plasma Chem Plasma Process. doi:10.1007/s11090-012-9354-3 Google Scholar
  14. 14.
    Rahman M, Nur MG (2014) Feasible application of modern eco-friendly treatment of wool fabric before coloration. Int J Sci Res Publ 4(7):1–7Google Scholar
  15. 15.
    Huh YI, Bismark M, Kim S, Lee HK, Nah C (2012) Effects of plasma treatment on mechanical properties of jute fibers and their composites with polypropylene. Elastom Compos 47(4):310–317CrossRefGoogle Scholar
  16. 16.
    Sinha E (2009) Effect of cold plasma treatment on macromolecular structure, thermal and mechanical behavior of jute fiber. J Ind Text 38(4):317–339CrossRefGoogle Scholar
  17. 17.
    Barra B, Paulo B, Alves C Jr, Savastano H Jr, Ghavami K (2012) Effects of methane cold plasma in sisal fibers. Key Eng Mater 517:458–468CrossRefGoogle Scholar
  18. 18.
    Khalil HPSA, Suraya NL (2011) Anhydride modification of cultivated kenaf bast fibres: morphological, spectroscopic and thermal studies. BioResources 6:1122–1135Google Scholar
  19. 19.
    George M, Mussone PG, Bressler DC (2014) Surface and thermal characterization of natural fibres treated with enzymes. Ind Crops Prod 53:365–373CrossRefGoogle Scholar
  20. 20.
    Elenga RG, Djemia P, Tingaud D, Chauveau T, Maniongui JG, Dirras GF (2013) Effects of alkali treatment on the microstructure, composition, and properties of the Raffia textilis fiber. BioResources 8(2):2934–2949CrossRefGoogle Scholar
  21. 21.
    Fan M, Dai D, Huang B (2012) Fourier transform infrared spectroscopy for natural fibres. In: Salih S (ed) Fourier transform–materials analysis. InTech, pp 45–68. doi:10.5772/35482
  22. 22.
    Ganan P et al (2005) Surface modification of sisal fibers: effects on the mechanical and thermal properties of their epoxy composites. Polym Compos 26(2):121–127CrossRefGoogle Scholar
  23. 23.
    Elkhaoulani A et al (2013) Mechanical and thermal properties of polymer composite based on natural fibers: Moroccan hemp fibers/polypropylene. Mater Des 49:203–208CrossRefGoogle Scholar
  24. 24.
    Yuan XW, Jayaraman K, Bhattacharyya D (2004) Effects of plasma treatment in enhancing the performance of woodfibre-polypropylene composites. Compos Part A-Appl Sci Manuf 35:1363–1374CrossRefGoogle Scholar
  25. 25.
    Mwaikambo LY, Ansell MP (1999) The effect of chemical treatment on the properties of hemp, sisal, jute and kapok fibres for composite reinforcement. Die Angew Makromol Chem 272(1):108–116CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 2015

Authors and Affiliations

  • Catia Relvas
    • 1
  • Gastón Castro
    • 2
  • Sohel Rana
    • 1
  • Raul Fangueiro
    • 1
  1. 1.Fibrous Materials Research Group, School of EngineeringUniversity of MinhoGuimaraesPortugal
  2. 2.Faculty of Architecture, Design and Urban StudiesPontifical Catholic University of ChileSantiagoChile

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