Plasma Chemistry and Plasma Processing

, Volume 34, Issue 1, pp 93–109

Nitric Oxide Conversion and Ozone Synthesis in a Shielded Sliding Discharge Reactor with Positive and Negative Streamers

Original Paper

DOI: 10.1007/s11090-013-9497-x

Cite this article as:
Malik, M.A. & Schoenbach, K.H. Plasma Chem Plasma Process (2014) 34: 93. doi:10.1007/s11090-013-9497-x


Positive and negative streamer discharges in atmospheric pressure air were generated in a shielded sliding discharge reactor at operating voltages as low as 5 kV for a gap length of 1.6 cm. In this reactor, electrodes are placed on top of a dielectric layer and one of the electrodes, generally the one on ground potential, is connected to a conductive layer on the opposite side of the dielectric. The energy per pulse, at the same applied voltage, was more than a factor of seven higher than that of pulsed corona discharges, and more than a factor of two higher than that of sliding discharges without a shield. It is explained on the basis of enhanced electric fields, particularly at the plasma emitting electrode. Specific input energy required for 50 % removal from ~1,000 ppm initial NO could be reduced to ~18 eV/molecule when ozone in the exhaust of negative streamers was utilized. For sliding discharges and pulsed corona discharges this value was ~25 eV/molecule and it was 35 eV/molecule for positive shielded sliding discharges. Also, the ozone energy yield from dry air was up to ~130 g/kW h and highest for negative streamer discharges in shielded sliding discharge reactors. The high energy density in negative streamer discharges in the shielded discharge reactor at the relatively low applied voltages might not only allow expansion of basic studies on negative streamers, but also open the path to industrial applications, which have so far been focused on positive streamer discharges.


Non-thermal plasma Pulsed corona discharges Sliding discharges Shielded sliding discharges Positive streamer discharges Negative streamer discharges Nitric oxide conversion Ozone generation 

Copyright information

© Springer Science+Business Media New York 2013

Authors and Affiliations

  1. 1.Frank Reidy Research Center for BioelectricsOld Dominion UniversityNorfolkUSA

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