Oxidation of Metals

, Volume 88, Issue 5–6, pp 565–582 | Cite as

Effect of CeO2 Coating on the Isothermal Oxidation Behaviour of Ni-Based Alloy 230

Original Paper
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Abstract

Ceria coating was deposited on alloy 230 using an electro-deposition process in a cerium nitrate electrolyte. Reactive element effects were investigated by comparing the oxidation behaviour of the samples with and without the ceria coating. The prepared ceria coating reduced the oxidation rate and improved the adherence of the oxide layer. A thicker oxide layer with large spallation areas formed on the uncoated sample, while a thin and protective oxide layer was found on the coated sample after oxidation for 1000 h at 900 °C. The oxidation mechanisms of alloy 230 with and without ceria coating were discussed. Furthermore, as the ceria coating changed the grain shapes of chromium oxides from columnar to an equiaxed structure, discussion also advanced proposals regarding the mechanisms of formation of these different oxides. The equiaxed grains enhanced the adhesion of the oxide to the alloy surface.

Keywords

High-temperature oxidation Ni-based superalloy Electro-deposition Reactive element effect (REE) Electron back-scattering diffraction (EBSD) 
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Notes

Acknowledgement

The authors gratefully acknowledge the financial support from Canadian National Science and Engineering Research Council (NSERC). The author Xu Wang acknowledges with gratitude the financial support from China Scholarship Council (CSC). The authors also would like to thank Chunyu Zhou’s help for measuring the oxidation kinetics of the whole oxidation test and Fan Fan’s support for preparing all the samples.

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Copyright information

© Springer Science+Business Media New York 2017

Authors and Affiliations

  1. 1.Department of Mechanical EngineeringUniversity of SaskatchewanSaskatoonCanada

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