Characterization of airborne particle release from nanotechnology-enabled clothing products
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This study investigated airborne particle release from 17 nanotechnology-enabled clothing items, including 10 items that were advertised as containing silver nanoparticles and 1 item with silver materials. Clothing wear was simulated using an abrader, where the rotating clothing samples came in contact with felt abrader wheels, and size distribution and concentration of the released particles were measured using a scanning mobility particle sizer and aerodynamic particle sizer. Through the use of inductively coupled plasma mass spectrometry, silver was detected in all 11 products advertised as containing silver, and its concentration varied from approximately 1 ppm to ~ 1.5 × 105 ppm depending on the product. Nano-sized particles, as well as larger agglomerates, were released from all investigated products with concentrations as high as ~ 2 × 104 particles/cm3; the concentration and size distribution varied substantially from product to product, and silver-based clothing tended to release smaller and higher number concentrations of particles than products where fibers were formulated using nanotechnology. Examination of the released particles using TEM confirmed the presence of manufactured nanoparticles; airborne sample analysis using SEM/EDS showed that the released particles contained Ag as well as other metals. This study can be valuable for the risk assessment of nanotechnology-based consumer goods, especially clothing containing silver.
KeywordsNanotechnology-enabled consumer products Nanoparticles Nanotechnology Nanotechnology-enabled clothing Nanotechnology-enabled fabrics Particle release Exposure Silver nanoparticles
This work was supported by the NSF (CBET-1236508), the NIH-NIEHS (1T32ES019854), the NIH-NIEHS Center for Environmental Exposures and Disease (CEED) at Rutgers University (P30 ES005022), and the New Jersey Agriculture and Experiment Station (NJAES) at Rutgers University.
Compliance with ethical standards
Conflict of interest
The authors declare that they have no conflict of interest.
- Davidovic S, Miljkovic M, Lazic V, Jovic D, Jokic B, Dimitrijevic S, Radetic M (2015) Impregnation of cotton fabric with silver nanoparticles synthesized by dextran isolated from bacterial species Leuconostoc mesenteroides T3. Carbohydr Polym 131:331–336. https://doi.org/10.1016/j.carbpol.2015.06.024 CrossRefGoogle Scholar
- Mitrano DM, Rimmle E, Wichser A, Erni R, Height M, Nowack B (2014) Presence of nanoparticles in wash water from conventional silver and nano-silver textiles. Am Chem Soc 8:7208–7219Google Scholar
- Nazarenko Y, Zhen H, Han T, Lioy PJ, Mainelis G (2012a) Nanomaterial inhalation exposure from nanotechnology-based cosmetic powders: a quantitative assessment. J Nanopart Res 14. https://doi.org/10.1007/s11051-012-1229-2
- Özdil N, Kayseri GÖ, Mengüç GS (2012) Abrasion resistance of materials. In: Adamiak M (ed). pp 119-146. https://doi.org/10.5772/29784
- Ozdil N, Kayseri GO, Mengüç GS (2012) Analysis of abrasion characteristics in textiles. INTECH Chapter 7Google Scholar
- Perera S, Bhushan B, Bandara R, Rajapakse G, Rajapakse S, Bandara C (2013) Morphological, antimicrobial, durability, and physical properties of untreated and treated textiles using silver-nanoparticles. Colloids Surf A Physicochem Eng Asp 436:975–989. https://doi.org/10.1016/j.colsurfa.2013.08.038 CrossRefGoogle Scholar
- Reed RB, Zaikova T, Barber A, Simonich M, Lankone R, Marco M, Hristovski K, Herckes P, Passantino L, Fairbrother DH, Tanguay R, Ranville JF, Hutchison JE, Westerhoff PK (2016) Potential environmental impacts and antimicrobial efficacy of silver- and nanosilver-containing textiles. Environ Sci Technol 50:4018–4026. https://doi.org/10.1021/acs.est.5b06043 CrossRefGoogle Scholar
- Soane DS, Offord DA (2002) Oil-and water-repellent finishes for textiles, United States Patent o. 6,472,476 B1., October 29, 2002Google Scholar
- von Goetz N, Lorenz C, Windler L, Nowack B, Heuberger M, Hungerbuhler K (2013) Migration of Ag- and TiO2-(Nano)particles from textiles into artificial sweat under physical stress: experiments and exposure modeling. Environ Sci Technol 47:9979–9987. https://doi.org/10.1021/es304329w CrossRefGoogle Scholar