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Doping carbon networks with phosphorus for supporting Pd in catalyzing selective oxidation of benzyl alcohol

  • Wenyao Guo
  • Shuo Niu
  • Xiaobo Ji
  • Weizhen Yu
  • Tsung-Wu Lin
  • Yifei Wu
  • Yitong Li
  • Lidong ShaoEmail author
Research Paper
  • 167 Downloads

Abstract

A new kind of phosphorus-doped porous carbon framework (P-PCF) was synthesized using a simple and low-cost method and was used as a support material for loading Pd nanoparticles with an average diameter of 5~7 nm (Pd/P-PCF) for benzyl alcohol oxidation. Enhanced activity, selectivity, and stability were achieved over Pd/P-PCF in comparison to the undoped counterpart catalyst (Pd/PCF). Surface analysis of the fresh and reacted catalysts revealed that the selective oxidation of benzyl alcohol is favored using the Pd/P-PCF catalyst because of the modified electronic properties of Pd nanoparticles, the metal-support interactions, as well as the hydrophobic and basic surface properties of the catalyst, which originates from the phosphorus doping.

Graphical abstract

Keywords

Phosphorus doping Porous carbon framework Palladium nanoparticle Selective oxidation Benzyl alcohol Nanostructured catalysts 

Notes

Funding

This work was supported by the National Natural Science Foundation of China (grant number 21403137).

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflict of interest.

Supplementary material

11051_2018_4279_MOESM1_ESM.doc (384 kb)
ESM 1 (DOC 384 kb)

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Copyright information

© Springer Nature B.V. 2018

Authors and Affiliations

  1. 1.Shanghai Key Laboratory of Materials Protection and Advanced Materials in Electric PowerShanghai University of Electric PowerShanghaiPeople’s Republic of China
  2. 2.College of Chemistry and Chemical EngineeringCentral South UniversityChangshaPeople’s Republic of China
  3. 3.Department of ChemistryTunghai UniversityTaichung CityTaiwan
  4. 4.Research & Development DepartmentNewford Technology Co. LtdHangzhouPeople’s Republic of China

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