Metal phosphonate coordination networks and frameworks as precursors of electrocatalysts for the hydrogen and oxygen evolution reactions
The hydrogen evolution reaction (HER) and the oxygen evolution reaction (OER) play key roles in the conversion of energy derived from renewable energy sources into chemical energy. Efficient, robust, and inexpensive electrocatalysts are necessary for driving these reactions at high rates at low overpotentials and minimize energetic losses. Recently, electrocatalysts derived from hybrid metal phosphonate compounds have shown high activity for the HER or OER. We review here the utilization of metal phosphonate coordination networks and metal-organic frameworks as precursors/templates for transition-metal phosphides, phosphates, or oxyhydroxides generated in situ in alkaline solutions, and their electrocatalytic performance in HER or OER.
KeywordsMetal phosphonate Water splitting Electrocatalysis
R.Z. acknowledges the fellowship from the China Scholarship Council (CSC). P.A.R. acknowledges the support from the DFG (RU2012/2-1).
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Conflict of interest
The authors declare that they have no conflict of interest.
- Clearfield A (1998b) Metal phosphonate chemistry. In: Karlin KD (Ed) Progress in inorganic chemistry, vol. 47. John Wiley & Sons, Inc., New York, pp 371–510. https://doi.org/10.1002/9780470166482.ch4
- Clearfield A, Demandis K (eds) (2011) Metal phosphonate chemistry: from synthesis to applications RSC publishing. UK. https://doi.org/10.1039/9781849733571
- Liu Y, Guo S-X, Bond AM, Zhang J, Du S (2013) Cobalt(II) phosphonate coordination polymers: synthesis, characterization and application as oxygen evolution electrocatalysts in aqueous media and water-saturated hydrophobic 1-butyl-3-methylimidazolium hexafluorophosphate ionic liquid. Electrochim Acta 101:201–208. https://doi.org/10.1016/j.electacta.2012.09.093 CrossRefGoogle Scholar
- Polarz S, Smarsly B, Bronstein L, Antonietti M (2001) From cyclodextrin assemblies to porous materials by silica templating. Angew Chem Int Ed 40:4417–4421. https://doi.org/10.1002/1521-3773(20011203)40:23<4417::AID-ANIE4417>3.0.CO;2-P CrossRefGoogle Scholar
- Pramanik M, Tsujimoto Y, Malgras V, Dou SX, Kim JH, Yamauchi Y (2015) Mesoporous iron phosphonate electrodes with crystalline frameworks for lithium-ion batteries. Chem Mater, 27:1082–1089. https://doi.org/10.1021/cm5044045
- Risch M, Shevchenko D, Anderlund MF, Styring S, Heidkamp J, Lange KM, Thapper A, Zaharieva I (2012) Atomic structure of cobalt-oxide nanoparticles active in light-driven catalysis of water oxidation. Int J Hydrogen Energy 37:8878–8888. https://doi.org/10.1016/j.ijhydene.2012.01.138 CrossRefGoogle Scholar
- Wang R, Dong XY, Du J, Zhao JY, Zang SQ (2017) MOF-derived bifunctional Cu3P nanoparticles coated by a N,P-codoped carbon shell for hydrogen evolution and oxygen reduction. Adv Mater 30. https://doi.org/10.1002/adma.201703711
- Wang R, Dong X-Y, Du J, Zhao J-Y, Zang S-Q MOF-derived bifunctional Cu3P nanoparticles coated by a N,P-codoped carbon shell for hydrogen evolution and oxygen reduction. Adv Mater 1703711 doi: https://doi.org/10.1002/adma.201703711, 2018
- Zhang R, Russo PA, Buzanich AG, Jeon T, Pinna N (2017b) Hybrid organic–inorganic transition-metal phosphonates as precursors for water oxidation electrocatalysts. Adv Funct Mater 27. https://doi.org/10.1002/adfm.201703158
- Zhu Y-P, Xu X, Su H, Liu Y-P, Chen T, Yuan Z-Y (2015b) Ultrafine metal phosphide nanocrystals in situ decorated on highly porous heteroatom-doped carbons for active electrocatalytic hydrogen evolution. ACS Appl Mater Interfaces 7:28369–28376. https://doi.org/10.1021/acsami.5b09092 CrossRefGoogle Scholar