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Selective hydrogenation of 2-methyl-3-butyn-2-ol catalyzed by embedded polymer-protected PdZn nanoparticles

  • Lyudmila B. OkhlopkovaEmail author
  • Ekaterina V. Matus
  • Igor P. Prosvirin
  • Michail A. Kerzhentsev
  • Zinfer R. Ismagilov
Research Paper

Abstract

PdZn/TiO2 catalysts were synthesized by sol–gel method using a template Pluronic F127. PdZn nanoparticles with the size ranging from 1.7 to 2 nm were prepared by ethylene glycol reduction of ZnCl2 and Pd(CH3COO)2 in the presence of stabilizer and introduced into the matrix by addition into TiO2 sol, followed by different activation procedures. The structure, particles size, and chemical composition of nanoparticles and catalysts were characterized by transmission electron microscopy, X-ray photoelectron spectroscopy, X-ray fluorescence spectroscopy, and energy dispersive spectroscopy. The prepared catalysts have been tested in the selective hydrogenation of 2-methyl-3-butyn-2-ol, and the results have been compared with catalysts prepared by conventional impregnation. The results indicate that bimetallic PdZn nanoparticles-based catalysts show higher selectivity than corresponding monometallic Pd/TiO2. Embedded on titania, bimetallic nanoparticles stabilized with polyvinylpyrrolidone exhibit good activity (1.1–1.8 mol MBY/mol Pd/s−1) and high selectivity to 2-methyl-3-buten-2-ol (81.5–88.9 % at 95 % conversion). The influence of the nature of the stabilizer, the stabilizer/metal molar ratio, and activation conditions on the catalytic behavior of the samples was analyzed. It is shown that the particle size does not significantly affect the catalytic properties in the range of 4.4–6.5 nm. The nature and amount of stabilizer seem to be crucial to prepare efficient catalyst.

Keywords

Mesoporous titania coating Fused silica capillary PdZn nanoparticles Selective hydrogenation Alkyne alcohol Catalytic coating Sol–gel method 

Abbreviations

PVPone

Polyvinylpyrrolidone

PVPine

Polyvinylpyridine

TEM

Transmission electron microscopy

EDS

Energy dispersive spectroscopy

ICP-AES

Inductively coupled plasma atomic emission spectroscopy

XRF

X-ray fluorescence spectroscopy

HRTEM

High resolution TEM

XPS

X-ray photoelectron spectroscopy

MBY

2-Methyl-3-butyn-2-ol

MBE

2-Methyl-3-buten-2-ol

MBA

2-Methyl-2-butanol

TGA

Thermogravimetric analyses

DTA

Differential thermal analyses

Notes

Acknowledgments

Authors are grateful to Dr. Yu. V. Patrushev for a gas-chromatographic analysis and Dr. E. Yu. Gerasimov for investigation of the catalysts by TEM. The support of this work by Russian Federal Agency of Scientific Organizations (Project V45.1.10) and Russian Foundation for Basic Research (Project N15-53-45039) is gratefully acknowledged.

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Copyright information

© Springer Science+Business Media Dordrecht 2015

Authors and Affiliations

  • Lyudmila B. Okhlopkova
    • 1
    Email author
  • Ekaterina V. Matus
    • 1
  • Igor P. Prosvirin
    • 1
    • 2
  • Michail A. Kerzhentsev
    • 1
  • Zinfer R. Ismagilov
    • 1
    • 3
  1. 1.Boreskov Institute of CatalysisNovosibirskRussia
  2. 2.Novosibirsk State UniversityNovosibirskRussia
  3. 3.Institute of Coal Chemistry and Material ScienceKemerovoRussia

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