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Supramolecular assembly of single-walled carbon nanotubes at air-solid interface

  • Monika Poonia
  • R. K. Gupta
  • V. Manjuladevi
  • Sanjeev K. Gupta
  • Jamil Akhtar
Research Paper

Abstract

We formed a stable and reversible Langmuir film (LF) of bundles of unfunctionalized single-walled carbon nanotubes (SWCNTs) at the air–water interface. The film exhibits gas-like and liquid-like phases. The Raman spectrograph of Langmuir–Blodgett (LB) film of single layer of SWCNTs on Si/SiO2 substrate shows the characteristic G, D, and radial breathing mode frequencies of the single-walled carbon nanotubes. Using atomic force microscope (AFM) in spreading resistance imaging mode, we obtained a dependence of target surface pressure on the assembly of SWCNTs in the LB films. The film deposited at very low surface pressure (0.5 mN/m) exhibited an assembly wherein the long axis of the nanotube bundles aligned in the direction of deposition. The LB films deposited in the liquid-like phase of the SWCNTs exhibited supramolecular donut structure. The average width of the SWCNTs was around 30 nm. The current–voltage characterization of the local structures of the LB films using the conducting AFM probe indicates semi-metallic and metallic nature of the donut and the hole in the donut (nanopore), respectively. Such supramolecular assembly of the SWCNTs can find application in the fabrication of the devices like sensors, photochemical cells, batteries, etc.

Keywords

Langmuir film Langmuir–Blodgett films Single-walled carbon nanotubes Atomic force microscopy Supramolecular donut structure Two-dimensional nanostructure 

Notes

Acknowledgments

Authors from BITS Pilani are thankful the University Grants Commission, India for its support through Special Assistance Programme. Thanks are also due to Department of Science and Technology, India. We are thankful to Dr. Chandra Shekhar, Director CSIR-CEERI Pilani for his kind approval for carrying out this collaborative work.

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Copyright information

© Springer Science+Business Media Dordrecht 2014

Authors and Affiliations

  • Monika Poonia
    • 1
  • R. K. Gupta
    • 1
  • V. Manjuladevi
    • 1
  • Sanjeev K. Gupta
    • 2
    • 3
  • Jamil Akhtar
    • 2
  1. 1.Department of PhysicsBirla Institute of Technology and SciencePilaniIndia
  2. 2.CSIR-Central Electronics Engineering Research Institute (CEERI)PilaniIndia
  3. 3.International Co-operation Division, Department of Electronics and Information Technology (DEITY)Ministry of Communications and Information TechnologyNew DelhiIndia

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