Sb2O3 microrods: self-assembly phenomena, luminescence and phase transition

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Sb2O3 microrods of the orthorhombic phase have been grown by evaporation deposition with Sb powder as precursor. The rods, of rectangular cross section, are composed of weakly bonded stacks of tiny plates of few hundreds of nanometres, which self-assembled during the growth process parallel to the growth axis. Photoluminescence (PL) spectra show resonance peaks in the ultraviolet-blue region related to optical cavity modes across the cross sections of the rods. Local phase transformation from the orthorhombic to the cubic Sb2O3 phase has been induced by long irradiation with the 325 nm laser light, as confirmed by Raman spectroscopy and PL.

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  1. Cebriano T, Méndez B, Piqueras J (2012a) Study of luminescence and optical resonances in Sb2O3 micro- and nanotriangles. J Nanopart Res 14:1215

  2. Cebriano T, Méndez B, Piqueras J (2012b) Micro- and nanostructures of Sb2O3 grown by evaporation deposition: self assembly phenomena, fractal and dendritic growth. Mat. Chem. Phys. 135:1096–1103

  3. Deng Z, Tang F, Chen D, Meng X, Cao L, Zou B (2006) A simple solution route to single-crystalline Sb2O3 nanowires with rectangular cross sections. J Phys Chem B 110:18225–18230

  4. Deng Z, Chen D, Tang F, Meng X, Ren J, Zhang L (2007) Orientated attachment assisted self-assembly of Sb2O3 nanorods and nanowires: end-to-end versus side-by-side. J Phys Chem C 111:5325–5330

  5. Deng Z, Chen D, Tang F, Ren J, Muscat AJ (2009) Synthesis and purple-blue emission of antimony trioxide single-crystalline nanobelts with elliptical cross section. Nano Res 2:151–160

  6. Fan G, Huang Z, Chai C, Liao D (2011) Synthesis of micro-sized Sb2O3 hierarchical structures by carbothermal reduction method. Mat Lett 65:1141–1144

  7. Hidalgo P, Méndez B, Piqueras J (2008) Sn doped GeO2 nanowires with waveguiding behavior. Nanotechnology 19:455705

  8. Hu CH, Shi SQ, Surya C, Woo CH (2007) Synthesis of antimony oxide nano-particles by vapor transport and condensation. J Mater Sci 42:9855–9858

  9. Jones SA, Fenerty J, Pearce J (1987) The enantiotropic phase transition of antimony (III) oxide. Thermochim Acta 114:61–66

  10. Li L, Zhang YX, Fang XS, Zhai TY, Liao MY, Wang HQ, Li GH, Koide Y, Bando Y, Goldberg D (2011) Sb2O3 nanobelt networks for excellent visible-light-range photodetectors. Nanotechnology 22:165704

  11. Liu J, Lee S, Lee K, Ahn YH, Park JY, Koh KH (2008) Bending and bundling of metal-free vertically aligned ZnO nanowires due to electrostatic interaction. Nanotechnology 19:186607

  12. López I, Nogales E, Méndez B, Piqueras J (2012) Resonant cavity modes in gallium oxide microwires. Appl Phys Lett 100:261910

  13. Lu X, Wen Z, Li J (2006) Hydroxyl-containing antimony oxide bromide nanorods combined with chitosan for biosensors. Biomaterials 27:5740–5747

  14. Naidu BS, Pandey M, Sudarsan V, Vatsa RK, Tewari R (2009) Photoluminescence and Raman spectroscopic investigations of morphology assisted effects in Sb2O3. Chem Phys Lett 474:180–184

  15. Ormand RG, Holland D (2007) Thermal phase transitions in antimony (III) oxides. J Sol State Chem 180:2587–2596

  16. Ortega Y, Fernández P, Piqueras J (2009) Self-assembled tin-doped ZnO nanowire and nanoplate structures grown by thermal treatment of ZnS powder. J Cryst Growth 311:3231–3234

  17. Ortega Y, Fernández P, Piqueras J (2011) Self-assembled three-dimensional Al-doped ZnO nanorod networks. Semicond Sci Technol 26:085035

  18. Sahoo NK, Apparao KVSR (1996) Process-parameter optimization of Sb2O3 films in the ultraviolet and visible region for interferometric applications. Appl Phys A 63:195–202

  19. Som T, Karmakar B (2010) Structure and properties of low-phonon antimony glasses and nano glass-ceramics in K2O–B2O3–Sb2O3 system. J Non-Cryst Solids 356:987–999

  20. Svensonn C (1974) The crystal structure of orthorhombic antimony trioxide, Sb2O3. Acta Cryst B 30:458–461

  21. Svensonn C (1975) Refinement of the crystal structure of cubic antimony trioxide, Sb2O3. Acta Cryst B 31:2016–2018

  22. Tigau N, Ciupina V, Prodan G (2005) The effect of substrate temperature on the optical properties of polycrystalline Sb2O3 thin films. J Cryst Growth 277:529–535

  23. Vila M, Díaz-Guerra C, Piqueras J (2012) Laser irradiation-induced α to δ phase transformation in Bi2O3 ceramics and nanowires. Appl Phys Lett 101:071905

  24. Wang X, Summers CJ, Wang ZL (2005) Self-attraction among aligned Au/ZnO nanorods under electron beam. Appl Phys Lett 86:013111

  25. Wang Q, Ge S, Shao Q, Zhao Y (2011) Self-assembly of Sb2O3 nanowires into microspheres: synthesis and characterization. Phys B 406:731–736

  26. Zeng DW, Xie CS, Zhu BL, Song WL (2004) Characteristics of Sb2O3 nanoparticles synthesized from antimony by vapor condensation method. Mat Lett 58:312–315

  27. Zhang Y, Li G, Zhang J, Zhang L (2004) Shape-controlled growth of one-dimensional Sb2O3 nanomaterials. Nanotechnology 15:762–765

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This study has been supported by Spanish MICINN through projects MAT 2009-07882, MAT 2012-31959 and Consolider 2010-00013.

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Correspondence to Bianchi Méndez.

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Cebriano, T., Méndez, B. & Piqueras, J. Sb2O3 microrods: self-assembly phenomena, luminescence and phase transition. J Nanopart Res 15, 1667 (2013) doi:10.1007/s11051-013-1667-5

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  • Antimony oxide
  • Luminescence
  • Phase transition