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Mechanics of Composite Materials

, Volume 54, Issue 3, pp 333–340 | Cite as

Effect of a Nanodisperse Graphite on the Viscoelastic Properties of Polyvinyl Chloride

  • B. B. Kolupaev
  • B. S. Kolupaev
  • V. V. Levchuk
  • B. D. Nechyporuk
  • Yu. R. Maksimtsev
  • V. A. Sidletskii
Article
  • 2 Downloads

In the absence of segregation of nanodisperse graphite particles, obtained by electrolysis as a new filler of polyvinyl chloride (PVC), the viscoelastic phenomena dependent on the structural changes of a composite are investigated. The shear modulus and the volume compressibility caused by deviations of elements of the structure from the quasi-equilibrium state under the action of ultrasonic vibrations (ω = 0.4·106 0.4 · 10 s–1) are calculated at filler concentrations 0 ≤ φ ≤ 10.0 vol.% and temperatures 298 K ≤ T ≤ (Tg + 10) K. It is shown that the volume density of internal energy depends on the expectation time for the transition of structural elements through the energy barrier, the dynamic viscosity of the material, and temperature. The results of calculations serve as the basis for producing PVC systems with controllable of properties.

Keywords

nanodispersion viscoelastic moduli structural element 

References

  1. 1.
    H. R. and M. Salehi, “Experimental study on the mechanical, creep, and viscoelastic behavior of TiO2/glass/epoxy hybrid nanocomposites,” Mech. Compos. Mater., 52, No. 5, 623-636 (2016).CrossRefGoogle Scholar
  2. 2.
    V. V. Zuev, S. V. Kostromin, and A. V. Shlykov, “ The effect of fullerene fillers on the mechanical properties of polymer nanocomposites,” Mech. Compos. Mater., 46, No. 2, 147-154 (2010).CrossRefGoogle Scholar
  3. 3.
    B. B. Kolupaev, “Study on the viscoelastic properties of metal-filler PVC on the basis of the potential of inter- and intramolecular interaction,” Inzh.-Fiz. Zhurn., 80, No.1, 178-185 (2007).Google Scholar
  4. 4.
    M. M. Shokri and R. Rafiee, “A review of the mechanical properties of isolated carbon nanotubes and carbon nanotube composites,” Mech. Compos. Mater., 46, No. 2, 155-172 (2010).CrossRefGoogle Scholar
  5. 5.
    B. B. Кolupaev, V. V. Klepko, and E. V. Lebedev, “The relaxation processes of a nanofilled PVC in sound range frequency,” Acoustic Bulletin, 15, No. 2,. 43-48 (2012).Google Scholar
  6. 6.
    S. K. Nechaev, “Problems of probalistic topology: statistics of nodes and noncommutative random walk,” Ispekhi Fiz. Nauk, 168, No. 4, 369-405 (1998).CrossRefGoogle Scholar
  7. 7.
    A. Dixit and Harlal Singh Mali, “Modeling techniques for predicting the mechanical properties of woven-fabric textile composites,” Mech. Compos. Mater., 49, No. 1, 3-30 (2013).CrossRefGoogle Scholar
  8. 8.
    V. F. Kuropatenko, “Model of a multicomponent medium,” Dokl. RAN, 403, No. 6, 761-763 (2005).Google Scholar
  9. 9.
    S. Ya. Frenkel, I. M. Tsigel’nyi, and B. S. Kolupaev, Molecular Cybernetics [in Russian], L., Svit (1990).Google Scholar
  10. 10.
    G. M. Bartenev and S. Ya. Frenkel, Polymer Physics [in Russian], L., Khimia (1990).Google Scholar
  11. 11.
    B. S. Kolupaev, Relaxation and Thermal Properties of Filled Polymer Systems [in Russian], eds. S. Ya. Frenkel, L., LGU (1980).Google Scholar
  12. 12.
    M. I. Ojovan, “Thermodynamic parameters of bonds in glassy materials from viscosity-temperature relationships,” J. Phys: Condensed Matter., 19, No. 41, 41-51 (2007).Google Scholar
  13. 13.
    Patent No. 92078 Ukraine, IPC C22B19/00, C01G9/00. Method of electrolytic preparation of fine zinc oxide / Yu. P. Lavorik, B. D. Nechiporuk, M. Yu. Novoselytsky, B. P. Rudik, V. V. Filonenko, O. V. Parasyuk. No. 200812571; stated on Oct. 27, 2008; publ. Feb. 25, 2009, Bull. No. 4.Google Scholar
  14. 14.
    A. L. Volynskii, Structural Self-Organization of Amorphous Polymers [in Russian], M., Fizmatlit (2005).Google Scholar

Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  • B. B. Kolupaev
    • 1
  • B. S. Kolupaev
    • 2
  • V. V. Levchuk
    • 2
  • B. D. Nechyporuk
    • 2
  • Yu. R. Maksimtsev
    • 2
  • V. A. Sidletskii
    • 2
  1. 1.S.Demyanchuk Institute of Cybernetics of the Rovno International EconomicHumanitarian UniversityRovnoUkraine
  2. 2.Rovno State Humanitarian UniversityRovnoUkraine

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