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Materials Science

, Volume 55, Issue 1, pp 9–16 | Cite as

Influence of High-Energy Milling in Hydrogen on the Structural-Phase State of Alloys Based on the Laves Phases

  • Yu. B. Basaraba
  • Т. М. ZasadnyiEmail author
  • Т. І. Lutsyshyn
  • І. E. Marchuk
Article
  • 6 Downloads

The influence of high-energy milling in a planetary mill in the atmosphere of hydrogen on the structure and phase composition of alloys based on the Laves phases is analyzed. We study ZrMn2 and ZrCrNi alloys containing an MgZn2 -type hexagonal Laves phase in the initial state. The changes in the phase-and-structural states of these alloys after milling in hydrogen and thermal treatment in a vacuum are studied with the help of scanning electron microscopy, electron-probe microanalysis, and X-ray phase-diffraction analysis. It is shown that, under the conditions of milling in hydrogen, the main phases of the ZrMn2 and ZrCrNi alloys decompose into zirconium hydride and manganese and into zirconium hydride and chromium, respectively. As the duration of milling increases, the iron content of the samples becomes higher as a result of wear of the milling balls. Depending on the duration of milling, the phases with MgZn2- or Th6Mn23 -type structures are formed in the ZrMn2 alloy after heat treatment in a vacuum. At the same time, the Mg Cu2 - and Th6Mn23 -type phases are formed in the ZrCrNi alloy.

Keywords

zirconium alloys hydrogen Laves phases high-energy milling hydrides intermetallic compounds 

References

  1. 1.
    F. Stein, M. Palm, and G. Sauthoff, “Structure and stability of Laves phases. P. I. Critical assessment of factors controlling Laves phase stability,” Intermetallics,12, 713–720 (2004).CrossRefGoogle Scholar
  2. 2.
    F. Stein, M. Palm, and G. Sauthoff, “Structure and stability of Laves phases. P. II. Structure type variations in binary and ternary systems,” Intermetallics,13, 1056–1074 (2005).CrossRefGoogle Scholar
  3. 3.
    N. Das, P. Sengupta, S. Roychowdhury, G. Sharma, P. S. Gawde, A. Arya, V. Kain, U. D. Kulkarni, J. K. Chakravartty, and G. K. Dey, “Metallurgical characterizations of Fe–Cr–Ni–Zr base alloys developed for geological disposal of radioactive hulls,” J. Nucl. Mater.,420, 559–574 (2012).CrossRefGoogle Scholar
  4. 4.
    W.-K. Hu, X.-P. Gao, Y. Kiros, E. Middelman, and D. Noreus, “Zr-based AB2 -type hydrogen storage alloys as dual catalysts of gas-diffusion electrodes in an alkaline fuel cell,” J. Phys. Chem.,108, 8756–8758 (2004).CrossRefGoogle Scholar
  5. 5.
    K. Young, T. Ouchi, J. Koch, and M. A. Fetcenko, “Compositional optimization of vanadium-free hypo-stoichiometric AB2 metal hydride alloy for Ni/MH battery application,” J. Alloys Comp.,510, 97–106 (2012).CrossRefGoogle Scholar
  6. 6.
    F. C. Ruiz, H. A. Peretti, A. Visintin, and W. E. Triaca, “A study on ZrCrNiPtx alloys as negative electrode components for NiMH batteries,” Int. J. Hydrogen Energy,36, 901–906 (2011).CrossRefGoogle Scholar
  7. 7.
    A. Visintin, H. A. Peretti, C. A. Tori, and W. E. Triaca, “Hydrogen absorption characteristics and electrochemical properties of Ti substituted Zr-based AB2 alloys,” Int. J. Hydrogen Energy,26, 683–689 (2001).CrossRefGoogle Scholar
  8. 8.
    X. Chen, J. Zou, X. Zeng, and W. Ding, “Hydrogen storage properties of a Mg–La–Fe–H nanocomposite prepared through reactive ball milling” J. Alloys Comp.,701, 208–214 (2017).CrossRefGoogle Scholar
  9. 9.
    J. Ankur, A. Shivani, and I. P. Jain, “Correlation between the milling time and hydrogen-storage properties of nanostructured ZrFeNi ternary alloy,” J. Alloys Comp.,480, 325–328 (2009).CrossRefGoogle Scholar
  10. 10.
    I. I. Buluk, Yu. B. Basaraba, and V. I. Markovych, “Production of functional nanocrystalline materials in hydrogen,” Mater. Sci.,39, 841–848 (2003).CrossRefGoogle Scholar
  11. 11.
    T. P. Yadav, R. M. Yadav, and D. P. Singh, “Mechanical milling: a top down approach for the synthesis of nanomaterials and nanocomposites,” Nanosci. Nanotechnol.,2, 22–48 (2012).CrossRefGoogle Scholar
  12. 12.
    I. I. Buluk, Yu. B. Basaraba, and A. M. Trostianchyn, “Features of the HDDR process in ZrT2 (T = Cr, Mn, Fe, Co) compounds,” J. Alloys Comp.,367, 283–288 (2004).CrossRefGoogle Scholar
  13. 13.
    M. E. Schlesinger, “The Mn–Zr (manganese-zirconium) system,” J. Phase Equilibr. Diffusion,20, 79–83 (1999).CrossRefGoogle Scholar
  14. 14.
    H. Okamoto, “Fe–Zr (Iron-Zirconium),” J. Phase Equilibr. Diffusion,27, 543–544 (2006).CrossRefGoogle Scholar
  15. 15.
    N. Mani, R. Sivakumar, and S. Ramaprabhu, “Hydrogen storage properties of ZrMnFe1−xNix (x = 0.2; 0.4; 0.5 and 0.6) alloys,” J. Alloys Comp.,337, 148–154 (2002).CrossRefGoogle Scholar
  16. 16.
    J. E. Larson, J. K. Cook, R. J. Wermer, and G. D. Tuggle, “Nitriding reaction with a Zr–Mn–Fe metal getter,” J. Alloys Comp.,330–332, 897–901 (2002).CrossRefGoogle Scholar
  17. 17.
    E. Teliza, J. Dieza, R. Facciob, F. Ruizcd, F. Zinolaa, and V. Díaz, “Molybdenum incorporation on AB2 alloys. Part I. Metallurgical and electrochemical characterization: Electrocatalytic behavior,” J. Alloys Comp.,744, 583–590 (2018).CrossRefGoogle Scholar
  18. 18.
    D. P. Abraham and N. L. Dietz, “Role of Laves intermetallics in nuclear waste disposal,” Mater. Sci. Eng., A,329–331, 610–615 (2002).CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  • Yu. B. Basaraba
    • 1
  • Т. М. Zasadnyi
    • 2
    Email author
  • Т. І. Lutsyshyn
    • 1
  • І. E. Marchuk
    • 3
  1. 1.Ivano-Frankivs’k National Technical University of Oil and GasIvano-Frankivs’kUkraine
  2. 2.Karpenko Physicomechanical InstituteUkrainian National Academy of SciencesLvivUkraine
  3. 3.I. Franko Lviv National UniversityLvivUkraine

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