Materials Science

, Volume 50, Issue 6, pp 870–876 | Cite as

Analysis of Multicomponent Systems for the Contents of Iridium and Palladium

  • L. V. Lozyns’ka
  • O. S. Tymoshuk
  • T. Ya. Vrublevs’ka
Article
  • 28 Downloads

The interactions of Ir(IV) with 5-hydroxyimino-4-imino-1,3-thiazolidin-2-one and Pd(II) with 4-[N′ -(4-imino-2-oxo-thiazolidin-5-ylidene)-hydrazino]-benzenesulfonic acid are studied for the first time. The optimal conditions for the formation of these compounds and their metrological characteristics are established. On the basis of the obtained results, some new methods for the evaluation of the contents of iridium and palladium are developed and approved by analyzing the intermetallic compounds (Tb2 Ir 3 Al 9, Gd2 Ir 3 Al 9, Yb40 Pd 40 Ga 20, and Yb40 Pd 38 Sn 22) and a SP5-35B resistor (S r ≤ 0.02).

Keywords

palladium (ІІ) iridium (IV) azolidones spectrophotometry intermetallic compounds resistor 

References

  1. 1.
    S. I. Ginzburg, N. A. Ezerskaya, I. V. Prokof’ev, et al., Analytical Chemistry of Platinum Metals [in Russian], Nauka, Moscow (1972).Google Scholar
  2. 2.
    Yu. A. Zolotov, G. M. Varshal, and V. M. Ivanov (editors), Analytical Chemistry of Metals of the Platinum Group [in Russian], Editorial URSS, Moscow (2003).Google Scholar
  3. 3.
    V. S. Sulyma, Electroradiomaterials [in Ukrainian], UIPA, Kharkiv (2004).Google Scholar
  4. 4.
    M. Syverud, J. E. Dahl, H. Hero, and E. Morisbak, “Corrosion and biocompatibility testing of palladium alloy castings,” Dent. Mater., 17, No. 1, 7–13 (2001).CrossRefGoogle Scholar
  5. 5.
    J. B. Sha and Y. Yamabe-Mitarai, “Ultrahigh strength of Ir–Hf–Nb ternary alloys with an fcc/L l2 microstructure at 1950°C,” Intermetallics, 32, No. 1, 145–150 (2013).CrossRefGoogle Scholar
  6. 6.
    K. Kovnir, M. Armbrüster, D. Teschner, et al., “In-situ surface characterization of the intermetallic compound PdGa – A highly selective hydrogenation catalyst,” Surf. Sci., 603, No. 10–12, 1784–1792 (2009).CrossRefGoogle Scholar
  7. 7.
    L. He, Ya. Huang, X. Ya. Liu, et al., “Structural and catalytic properties of supported Ni–Ir alloy catalysts for H2 generation via hydrous hydrazine decomposition,” Appl. Catal. B., 147, No. 5, 779–788 (2014).CrossRefGoogle Scholar
  8. 8.
    Sh. Chen, B. D. Adams, and A. Chen, “Synthesis and electrochemical study of nanoporous Pd–Ag alloys for hydrogen sorption,” Electrochim. Acta, 56, No. 1, 61–67 (2010).CrossRefGoogle Scholar
  9. 9.
    S. E. Livingstone, The Chemistry of Ruthenium, Rhodium, Palladium, Osmium, Iridium, and Platinum, Pergamon Press, New York (1967).Google Scholar
  10. 10.
    H. R. Naren, A. Tamizhavel, A. K. Nigam, and S. Ramakrishan, “Suppression of electron correlations in the superconducting alloys of Rh17-xIrxS15,” Physica C: Supercond., 470, Nos. 17–18, 682–684 (2010).CrossRefGoogle Scholar
  11. 11.
    A. Amato, B. Roessli, P. Fischer et al., “Magnetic fluctuations and superconductivity in YbPd2Sn,” Physica B: Cond. Matt., 326, No. 1–4, 369–373 (2003).CrossRefGoogle Scholar
  12. 12.
    N. A. Ezerskaya and I. N. Kisileva, “Coulometric determination of iridium in fluoride-chloride solutions,” Zh. Anal. Khim., 56, No. 9, 967–970 (2001).Google Scholar
  13. 13.
    R. F. Gur’eva and S. B. Savvin, “Azorhodanines, azothiopropiorhodanines, and their analytical application,” Usp. Khim., 67, No. 3, 236–251 (1998).Google Scholar
  14. 14.
    R. F. Gur’eva and S. B. Savvin, “Spectrophotometric methods for the detection of noble metals,” Zh. Anal. Khim., 57, No. 11, 1158–1175 (2002).Google Scholar
  15. 15.
    L. Lozynska and O. Tymoshuk, “Spectrophotometric investigation of palladium (II) ions interaction with 5-hydroxyimino-4-imino-1,3-thiazolidin-2-one,” Chem. & Chem. Tech. Chem., 7, No. 4, 391–395 (2013).Google Scholar
  16. 16.
    Yu. Lutsyshyn, Ya. Tokaichuk, P. Demchenko, and R. Gladyshevs’kyi, “Refinement of the crystal structure of R2Ir3Al9 (R = Gd, Tb) ternary aluminides,” Visn. L’viv. Univ. Ser. Khim., Issue 51, 52–59 (2010).Google Scholar
  17. 17.
    M. Giovannini, R. Pasero, and A. Saccone, “Phase relationships at 600°C of the Yb–Pd–Sn system from 25 to 100 at.% Yb,” Intermetallics, 18, No. 4, 429–433 (2010).CrossRefGoogle Scholar
  18. 18.
    P. Rogl, Yu. Grin, K. Hiebl, and C. Godart, “Crystal structure and magnetic behavior of ternary YbTGa2 compounds (T = Ni, Pd, Pt) and quaternary solid solutions YbPd1-xAgxGa2,” J. Alloys Comp., 239, No. 2, 127–130 (1996).CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 2015

Authors and Affiliations

  • L. V. Lozyns’ka
    • 1
  • O. S. Tymoshuk
    • 1
  • T. Ya. Vrublevs’ka
    • 1
  1. 1.Franko Lviv National UniversityLvivUkraine

Personalised recommendations