Properties of amorphous alloys of Al–REM–Ni and Al–REM–Ni–Fe systems with nanocrystalline structure
Article
First Online:
Received:
- 63 Downloads
- 1 Citations
We have investigated the influence of annealing on the physicochemical properties of amorphous alloys based on aluminum. It has been established that, after annealing at the temperature of the first stage of crystallization, an X-ray amorphous structure with an insignificant volume fraction of a disordered nanocrystalline phase forms. In this case, the polarization resistance of the surface of the alloys in a 0.5 М aqueous solution of NaOH increases substantially, and the free potential shifts in the direction to anode potentials. In structural transformations under these conditions, the microhardness of the alloys increases to a maximum degree.
Keywords
amorphous metallic alloys nanocrystallization microhardness electric resistance corrosionReferences
- 1.A. P. Tsai, A. Inoue, and T. Masumoto, “Ductile Al-Ni-Zr amorphous alloys with high mechanical strength,” J. Mater. Sci. Lett., 7, 805–807 (1988).CrossRefGoogle Scholar
- 2.L. N. Larikov, “Diffusion processes in nanocrystalline materials,” Metallofiz. Noveish. Tekhnol., 11, No. 1, 69–72 (1995).Google Scholar
- 3.S. Mudry, L. Bednarska, B. Kotur, and O. Hertsyk, “Temperatures changes of structure in Al87Ni8Y5 amorphous alloy,” Arch. Mater. Sci., 25, No. 4, 373–378 (2004).Google Scholar
- 4.J. Basu and S. Ranganathan, “Crystallization in Al-ETM-LTM-La metallic glasses,” Intermetallics, 12, No. 10–11, 1045–1050 (2004).CrossRefGoogle Scholar
- 5.A. Inoue, “New aluminum base alloys,” in: Advances in Physical Metallurgy, Gordon & Breach, Amsterdam (1996), pp. 127–134.Google Scholar
- 6.C. Monticelli, F. Zucchi, G. Brunoro, and G. Trabanelli, “Corrosion and corrosion inhibition of alumina particulate/aluminum alloys metal matrix composites in neutral chloride solutions,” J. Appl. Electrochem., 27, 325–334 (1997).CrossRefGoogle Scholar
- 7.S. I. Mudryi, A. V. Korolyshyn, B. Ya. Kotur, L. M. Bednars’ka, O. M. Hertsyk, and M. O. Kovbuz, “Evaluation of the volume fraction of the crystalline phase in amorphous alloys,” Fiz.-Khim. Mekh. Mater., 41, No. 3, 126–128 (2005); English translation: Mater. Sci., 41, No. 3, 427–432 (2005)Google Scholar
- 8.O. Hertsyk, M. Kovbuz, L. Bednars’ka, and T. Pereverzeva, “Influence of рН of the environment on the corrosion resistance of the Al87.0Gd5.0Ni8.0 amorphous metallic alloy,” Visn. L’viv. Univ. Ser. Khimiya., 51, 329–334 (2010).Google Scholar
- 9.T. Mika, M. Karolus, G. Haneczok, et al., “Influence of Gd and Fe on crystallization of Al87Y5Ni8 amorphous alloy,” J. Non-Cryst. Sol., 354, No. 27, 3099–3106 (2008).CrossRefGoogle Scholar
- 10.M. Munoz-Morris, S. Surinach, M. Gich, et al., “Crystallization of a Al–4Ni–6Ce glass and its influence on mechanical properties,” Acta Mater., 51, 1067–1077 (2003).CrossRefGoogle Scholar
- 11.L. Bednarska, M. Kovbuz, A. Budniok, et al., “Influence of iron additives on semiconduction properties of Al-based amorphous metallic alloys,” in: Abstracts of the Joint Conferences on Advanced Materials: 6th Workshop on Functional and Nanostructured Materials , 10th Conference on Intermolecular and Magnetic Interactions in Matter (September 27–30, 2009, Sulmona-L’Aquila, Italy), Sulmona-L’Aquila, Italy (2009), p. 139.Google Scholar
- 12.G. E. Abrosimova, A. S. Aronin, I. I. Zver’kova, et al., “Formation, structure, and microhardness of Ni–Mo–B nanocrystalline alloys,” Fiz. Tverd. Tela, 40, No. 1, 10–16 (1998).Google Scholar
Copyright information
© Springer Science+Business Media New York 2013