Abstract
In this study, the CO2 adsorption properties of different metal mixed oxides (MMO) obtained by calcination of different layered double hydroxides (LDH) are addressed. Four types of LDH, with composition \(\left[{{\text{M}}_ {1 - {\text{x}}}^{2 +} {\text{M}}_{\text{x}}^{3 +} \left({\text{OH}} \right)_{2}} \right]^{{\text{x} +}} \cdot[{\text{A}}_{\text{x/n}}^{{\text{n} -}} \cdot {m}{\text{H}}_{2} {\text{O}}]^{{\text{x} -}},\) where M2+=Zn, Cu, Ni, M3+=Al, x = 0.33, n = 2 and A = CO 2−3 , were studied by X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy and thermogravimetric analysis coupled with mass spectrometry (TG-MS). Different thermal behaviors upon heating were observed depending on the LDH composition, resulting in the exploitation of different calcination temperatures to convert LDH into mixed metal oxides (MMO). MMO were exposed to ambient air or pure carbon dioxide atmosphere to evaluate CO2 adsorption properties. Aging in ambient condition leads to adsorption of both CO2 and water, from ambient moisture, with variable ratios depending on the MMO composition. Furthermore, all the MMO were demonstrated to be able to adsorb CO2 in pure gas stream, in the absence of moisture. In both ambient and pure CO2 conditions, the performance of MMO is strongly dependent on the metal composition of MMO. In particular, the presence of Cu in the structure turned out to be beneficial in terms of adsorption capacity, with a maximum mass gain for CuAl MMO of 4 and 15% in pure CO2 and in atmospheric conditions, respectively.
Similar content being viewed by others
Notes
This temperature was selected as the lowest possible temperature for the instrument and is sufficiently close to the ambient temperature.
For the detailed description of the method, see Experimental section.
References
Leung DY, Caramanna G, Maroto-Valer MM. An overview of current status of carbon dioxide capture and storage technologies. Renew Sustain Energy Rev. 2014;39:426–43.
Silva JA, Schumann K, Rodrigues AE. Sorption and kinetics of CO2 and CH4 in binderless beads of 13X zeolite. Microporous Mesoporous Mater. 2012;158:219–28.
Wang L, Liu Z, Li P, Yu J, Rodrigues AE. Experimental and modeling investigation on post-combustion carbon dioxide capture using zeolite 13X-APG by hybrid VTSA process. Chem Eng J. 2012;197:151–61.
Cheung O, Liu Q, Bacsik Z, Hedin N. Silicoaluminophosphates as CO2 sorbents. Microporous Mesoporous Mater. 2012;156:90–6.
Yang R, Liu G, Li M, Zhang J, Hao X. Preparation and N2, CO2 and H2 adsorption of super activated carbon derived from biomass source hemp (Cannabis sativa L.) stem. Microporous Mesoporous Mater. 2012;158:108–16.
Vargas DP, Giraldo L, Moreno-Piraján JC. CO2 adsorption on activated carbon honeycomb-monoliths: a comparison of Langmuir and Toth models. Int J Mol Sci. 2012;13(7):8388–97.
Correia LB, Fiuza RA, de Andrade RC, Andrade HM. CO2 capture on activated carbons derived from mango fruit (Mangifera indica L.) seed shells. J Therm Anal Calorim. 2017;131:1–8.
Giraldo L, Moreno-Piraján JC. CO2 adsorption on activated carbon prepared from mangosteen peel. J Therm Anal Calorim. 2017. https://doi.org/10.1007/s10973-017-6725-2.
Yu J, Xie L-H, Li J-R, Ma Y, Seminario JM, Balbuena PB. CO2 capture and separations using MOFs: computational and experimental studies. Chem Rev. 2017;117(14):9674–754.
Qi G, Fu L, Choi BH, Giannelis EP. Efficient CO2 sorbents based on silica foam with ultra-large mesopores. Energy Environ Sci. 2012;5(6):7368–75.
Forano C, Hibino T, Leroux F, Taviot-Gueho C. 1 layered double hydroxides. Dev Clay Sci. 2006;1:1021–95.
Hibino T, Yamashita Y, Kosuge K, Tsunashima A. Decarbonation behavior of Mg–Al–CO3 hydrotalcite-like compounds during heat treatment. Clays Clay Miner. 1995;43(4):427–32.
Kloprogge JT, Frost RL. Fourier transform infrared and Raman spectroscopic study of the local structure of Mg-, Ni-, and Co-hydrotalcites. J Solid State Chem. 1999;146(2):506–15.
Stanimirova T, Kirov G. Cation composition during recrystallization of layered double hydroxides from mixed (Mg, Al) oxides. Appl Clay Sci. 2003;22(6):295–301.
Hutson ND, Speakman SA, Payzant EA. Structural effects on the high temperature adsorption of CO2 on a synthetic hydrotalcite. Chem Mater. 2004;16(21):4135–43.
Kloprogge JT, Hickey L, Frost RL. FT-Raman and FT-IR spectroscopic study of synthetic Mg/Zn/Al-hydrotalcites. J Raman Spectrosc. 2004;35(11):967–74.
Porta P, Morpurgo S. Cu/Zn/Co/Al/Cr-containing hydrotalcite-type anionic clays. Appl Clay Sci. 1995;10(1–2):31–44.
Costantino U, Marmottini F, Sisani M, Montanari T, Ramis G, Busca G, et al. Cu–Zn–Al hydrotalcites as precursors of catalysts for the production of hydrogen from methanol. Solid State Ion. 2005;176(39):2917–22.
Valente JS, Hernandez-Cortez J, Cantu MS, Ferrat G, López-Salinas E. Calcined layered double hydroxides Mg–Me–Al (Me: Cu, Fe, Ni, Zn) as bifunctional catalysts. Catal Today. 2010;150(3):340–5.
Di Fronzo A, Pirola C, Comazzi A, Galli F, Bianchi C, Di Michele A, et al. Co-based hydrotalcites as new catalysts for the Fischer–Tropsch synthesis process. Fuel. 2014;119:62–9.
Węgrzyn A, Rafalska-Łasocha A, Majda D, Dziembaj R, Papp H. The influence of mixed anionic composition of Mg–Al hydrotalcites on the thermal decomposition mechanism based on in situ study. J Therm Anal Calorim. 2009;99(2):443–57.
Tao Q, He H, Frost RL, Yuan P, Zhu J. Thermal decomposition of silylated layered double hydroxides. J Therm Anal Calorim. 2010;101(1):153–9.
León M, Díaz E, Bennici S, Vega A, Ordónez S, Auroux A. Adsorption of CO2 on hydrotalcite-derived mixed oxides: sorption mechanisms and consequences for adsorption irreversibility. Ind Eng Chem Res. 2010;49(8):3663–71.
Klemkaite K, Prosycevas I, Taraskevicius R, Khinsky A, Kareiva A. Synthesis and characterization of layered double hydroxides with different cations (Mg Co, Ni, Al), decomposition and reformation of mixed metal oxides to layered structures. Open Chem. 2011;9(2):275–82.
Othman M, Helwani Z, Fernando W. Synthetic hydrotalcites from different routes and their application as catalysts and gas adsorbents: a review. Appl Organomet Chem. 2009;23(9):335–46.
Gupta S, Agarwal DD, Banerjee S. Synthesis and characterization of hydrotalcites: Potential thermal stabilizers for PVC. Indian J Chem. 2008;47A:1004–8.
Kovanda F, Jirátová K, Rymeš J, Koloušek D. Characterization of activated Cu/Mg/Al hydrotalcites and their catalytic activity in toluene combustion. Appl Clay Sci. 2001;18(1):71–80.
Jabłońska M, Chmielarz L, Węgrzyn A, Guzik K, Piwowarska Z, Witkowski S, et al. Thermal transformations of Cu–Mg (Zn)–Al(Fe) hydrotalcite-like materials into metal oxide systems and their catalytic activity in selective oxidation of ammonia to dinitrogen. J Therm Anal Calorim. 2013;114(2):731–47.
Ram Reddy M, Xu Z, Lu G, Diniz da Costa J. Layered double hydroxides for CO2 capture: structure evolution and regeneration. Ind Eng Chem Res. 2006;45(22):7504–9.
Hutson ND, Attwood BC. High temperature adsorption of CO2 on various hydrotalcite-like compounds. Adsorption. 2008;14(6):781–9.
Ficicilar B, Dogu T. Breakthrough analysis for CO2 removal by activated hydrotalcite and soda ash. Catal Today. 2006;115(1):274–8.
Yong Z, Mata V, Rodrigues AE. Adsorption of carbon dioxide onto hydrotalcite-like compounds (HTlcs) at high temperatures. Ind Eng Chem Res. 2001;40(1):204–9.
Zhu X, Shi Y, Cai N. High-pressure carbon dioxide adsorption kinetics of potassium-modified hydrotalcite at elevated temperature. Fuel. 2017;207:579–90.
Wang Q, Wu Z, Tay HH, Chen L, Liu Y, Chang J, et al. High temperature adsorption of CO2 on Mg–Al hydrotalcite: effect of the charge compensating anions and the synthesis pH. Catal Today. 2011;164(1):198–203. https://doi.org/10.1016/j.cattod.2010.10.042.
Wang Q, Tay HH, Ng DJW, Chen L, Liu Y, Chang J, et al. The effect of trivalent cations on the performance of Mg–M–CO3 layered double hydroxides for high-temperature CO2 capture. Chemsuschem. 2010;3(8):965–73.
Costantino U, Marmottini F, Nocchetti M, Vivani R. New synthetic routes to hydrotalcite-like compounds-characterisation and properties of the obtained materials. Eur J Inorg Chem. 1998;1998(10):1439–46.
Basąg S, Kovanda F, Piwowarska Z, Kowalczyk A, Pamin K, Chmielarz L. Hydrotalcite-derived Co-containing mixed metal oxide catalysts for methanol incineration. J Therm Anal Calorim. 2017;129(3):1301–11.
Kloprogge JT, Wharton D, Hickey L, Frost RL. Infrared and Raman study of interlayer anions CO32–, NO3–, SO42– and ClO4– in Mg/Al-hydrotalcite. Am Miner. 2002;87(5–6):623–9.
Shannon RD. Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Acta Crystallogr Sect A Cryst Phys Diffr Theor Gen Crystallog. 1976;32(5):751–67.
Costantino U, Curini M, Montanari F, Nocchetti M, Rosati O. Hydrotalcite-like compounds as catalysts in liquid phase organic synthesis: I. Knoevenagel condensation promoted by [Ni0.73Al0.27(OH)2](CO3)0.135. J Mol Catal A Chem. 2003;195(1):245–52.
Segal SR, Anderson KB, Carrado KA, Marshall CL. Low temperature steam reforming of methanol over layered double hydroxide-derived catalysts. Appl Catal A. 2002;231(1):215–26.
Lwin Y, Yarmo MA, Yaakob Z, Mohamad AB, Daud WRW. Synthesis and characterization of Cu–Al layered double hydroxides. Mater Res Bull. 2001;36(1):193–8.
Neves V, Costa M, Senra J, Aguiar L, Malta L. Thermal behavior of LDH 2CuAl. CO3 and 2CuAl. CO3/Pd. J Therm Anal Calorim. 2017;130(2):689–94.
Cavani F, Trifirò F, Vaccari A. Hydrotalcite-type anionic clays: preparation, properties and applications. Catal Today. 1991;11(2):173–301.
Resini C, Montanari T, Barattini L, Ramis G, Busca G, Presto S, et al. Hydrogen production by ethanol steam reforming over Ni catalysts derived from hydrotalcite-like precursors: catalyst characterization, catalytic activity and reaction path. Appl Catal A. 2009;355(1):83–93.
Goh K-H, Lim T-T, Dong Z. Application of layered double hydroxides for removal of oxyanions: a review. Water Res. 2008;42(6):1343–68.
Basąg S, Piwowarska Z, Kowalczyk A, Węgrzyn A, Baran R, Gil B, et al. Cu-Mg-Al hydrotalcite-like materials as precursors of effective catalysts for selective oxidation of ammonia to dinitrogen—the influence of Mg/Al ratio and calcination temperature. Appl Clay Sci. 2016;129:122–30.
Alejandre A, Medina F, Rodriguez X, Salagre P, Cesteros Y, Sueiras J. Cu/Ni/Al layered double hydroxides as precursors of catalysts for the wet air oxidation of phenol aqueous solutions. Appl Catal B. 2001;30(1):195–207.
Alejandre A, Medina F, Salagre P, Correig X, Sueiras J. Preparation and study of Cu–Al mixed oxides via hydrotalcite-like precursors. Chem Mater. 1999;11(4):939–48.
Seftel E, Popovici E, Mertens M, De Witte K, Van Tendeloo G, Cool P, et al. Zn–Al layered double hydroxides: synthesis, characterization and photocatalytic application. Microporous Mesoporous Mater. 2008;113(1):296–304.
Porta P, De Rossi S, Ferraris G, Jacono ML, Minelli G, Moretti G. Structural characterization of malachite-like coprecipitated precursors of binary CuO–ZnO catalysts. J Catal. 1988;109(2):367–77.
Behrens M, Girgsdies F, Trunschke A, Schlögl R. Minerals as model compounds for Cu/ZnO catalyst precursors: structural and thermal properties and IR spectra of mineral and synthetic (zincian) malachite, rosasite and aurichalcite and a catalyst precursor mixture. Eur J Inorg Chem. 2009;2009(10):1347–57.
Smoláková L, Frolich K, Troppová I, Kutálek P, Kroft E, Čapek L. Determination of basic sites in Mg–Al mixed oxides by combination of TPD-CO2 and CO2 adsorption calorimetry. J Therm Anal Calorim. 2017;127(3):1921–9.
Acknowledgements
This research work was funded by “ITACA” project of the POR-FESR “Competitività regionale e occupazione” 2007/2013, Asse 1, Misura I.1.1, “Piattaforme innovative” of the Piedmont Region (Italy). Prof. Matteo Pavese at Politecnico di Torino is acknowledged for providing access to TG-MS equipment. Authors gratefully acknowledge A. Petracci and R. Spogli at Prolabin & Tefarm S.r.l for SEM analysis and the useful discussions. Furthermore, Prof. Giovanni Camino at Politecnico di Torino is gratefully acknowledged for discussion and interpretation of results.
Author information
Authors and Affiliations
Corresponding author
Electronic supplementary material
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Colonna, S., Bastianini, M., Sisani, M. et al. CO2 adsorption and desorption properties of calcined layered double hydroxides. J Therm Anal Calorim 133, 869–879 (2018). https://doi.org/10.1007/s10973-018-7152-8
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10973-018-7152-8