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Journal of Thermal Analysis and Calorimetry

, Volume 133, Issue 2, pp 1143–1148 | Cite as

Thermodynamic properties of tetraphenylantimony 1-adamantanecarboxylate

  • D. V. Lyakaev
  • A. V. Markin
  • N. N. Smirnova
  • V. V. Sharutin
  • O. K. Sharutina
Article
  • 123 Downloads

Abstract

In the present work for the first time, the temperature dependence of the heat capacity \(C_{\text{p}}^{\text{o}}\) = f(T) of tetraphenylantimony (1-adamantanecarboxylate) was determined in the range 5.6–456 K by methods adiabatic vacuum calorimetry and differential scanning calorimetry. The compound fuses in the range 414–446 K without decomposition, and thermodynamic characteristics of fusion were defined and analyzed. Multifractal treatment of low-temperature heat capacity was made as a result topological structure of the compound was established. The complex of standard thermodynamic functions (enthalpy, entropy, the Gibbs energy) was given for crystal and liquid states in the range from T → 0 to 456 K. Also, standard entropy of formation of a substance in the crystalline state at T = 298.15 K was calculated. Comparison of thermodynamic properties was made for the derivatives of antimony studied in the present work and earlier.

Keywords

Tetraphenylantimony 1-adamantanecarboxylate Adiabatic vacuum calorimetry DSC Thermogravimetric analysis Heat capacity Thermodynamic functions 

Notes

Acknowledgements

This work was financially supported by the Ministry of Education and Science of The Russian Federation (Organization of Scientific Research, No. 4.6138.2017/6.7).

Supplementary material

10973_2017_6803_MOESM1_ESM.docx (37 kb)
Supplementary material 1 (DOCX 36 kb)

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Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2017

Authors and Affiliations

  • D. V. Lyakaev
    • 1
  • A. V. Markin
    • 1
  • N. N. Smirnova
    • 1
  • V. V. Sharutin
    • 2
  • O. K. Sharutina
    • 2
  1. 1.Lobachevsky UniversityNizhny NovgorodRussia
  2. 2.South Ural State University National ResearchChelyabinskRussia

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