Journal of Thermal Analysis and Calorimetry

, Volume 131, Issue 2, pp 873–885 | Cite as

Influence of high-volume electric furnace nickel slag and phosphorous slag on the properties of massive concrete

Article

Abstract

This study applied high-volume electric furnace nickel slag (FS), phosphorous slag (PS) and a mixture of the two (FP) to massive concrete, and using fly ash (FA) as the control admixture, investigated the effects of FS and PS on the hydration and hardening process of the cementitious materials, the mechanical properties and the durability of the concrete. Two curing conditions were set, namely the standard curing condition and temperature-matched curing condition (or constant 25 and 50 °C). The hydration heat, hydration products, pore size distribution, mechanical properties and ability of the concrete to resist chloride ion penetration were tested. The results show that the activity of PS and FP is higher than that of FA, while that of FS is lower than that of FA; the improvement of FP on the pore structure of the hardened paste is close to that of FA at late ages under the standard curing condition but better than that of FA at all ages under the temperature-matched curing condition; high-volume FP concrete shows similar or even superior mechanical properties and permeability to chloride ions of concrete to high-volume FA concrete at late ages under both curing conditions.

Keywords

Massive concrete Temperature matching curing Electric furnace nickel slag Phosphorous slag 

Notes

Acknowledgements

This work was supported by the Tsinghua University Initiative Scientific Research Program [Grant Number 20161080079] and the Jiangsu Key Laboratory of Construction Materials [Grant Number CM2016-02].

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflict of interest.

References

  1. 1.
    ACI Committee 301–10. Specification for structure concrete. Farmington Hills, MI: American Concrete Institute; 2010.Google Scholar
  2. 2.
    Chu I, Lee Y, Amin MN, Jang B, Kim J. Application of a thermal stress device for the prediction of stresses due to hydration heat in mass concrete structure. Constr Build Mater. 2013;45:192–8.CrossRefGoogle Scholar
  3. 3.
    Li Y, Nie L, Wang B. A numerical simulation of the temperature cracking propagation process when pouring mass concrete. Automat Constr. 2014;37:203–10.CrossRefGoogle Scholar
  4. 4.
    Zhang G, Li G. Effects of mineral admixtures and additional gypsum on the expansion performance of sulphoaluminate expansive agent at simulation of mass concrete environment. Constr Build Mater. 2016;113:970–8.CrossRefGoogle Scholar
  5. 5.
    Du C. Dam construction–concrete temperature control using fly ash. Concr Int. 1996;18:34–6.Google Scholar
  6. 6.
    Langan BW, Weng K, Ward MA. Effect of silica fume and fly ash on heat of hydration of Portland cement. Cement Concr Res. 2002;32(7):1045–51.CrossRefGoogle Scholar
  7. 7.
    Mengxiao S, Qiang W, Zhikai Z. Comparison of the properties between high-volume fly ash concrete and high-volume steel slag concrete under temperature matching curing condition. Constr Build Mater. 2015;98:649–55.CrossRefGoogle Scholar
  8. 8.
    Liu SH, Wang L, Gao YX, Yu BY, Bai Y. Comparing study on hydration properties of various cementitious systems. J Therm Anal Calorim. 2014;118(3):1483–92.CrossRefGoogle Scholar
  9. 9.
    Zhang TS, Yu QJ, Wei JX. Improvement of surface cementitious properties of coarse fly ash by dehydration and rehydration processes. J Therm Anal Calorim. 2012;109(1):265–71.CrossRefGoogle Scholar
  10. 10.
    Wang Q, Yan PY, Feng JJ. Design of high-volume fly ash concrete for a massive foundation slab. Mag Concr Res. 2013;65(2):71–81.CrossRefGoogle Scholar
  11. 11.
    Florida DOT. Standard specifications for road and bridge construction. Tallahassee, FL: Florida Department of Transportation; 2017.Google Scholar
  12. 12.
    Bobkracino CP, Seracino R, Zia P, Edwards A. Crack free mass concrete footings on bridges in coastal environments, NCDOT Project 2012–09 (FHWA/NC/2012-09).: Department of Civil, Construction, and Environmental Engineering, North Carolina State University, 2014.Google Scholar
  13. 13.
    Zhang Z, Zhu Y, Yang T, Li L, Zhu H, Wang H. Conversion of local industrial wastes into greener cement through geopolymer technology: a case study of high-magnesium nickel slag. J Clean Prod. 2017;141:463–71.CrossRefGoogle Scholar
  14. 14.
    Maragkos I, Giannopoulou IP, Panias D. Synthesis of ferronickel slag-based geopolymers. Miner Eng. 2009;22(2):196–203.CrossRefGoogle Scholar
  15. 15.
    Singh NB, Bhattacharjee KN. Phosphorous furnace slag—a potential waste material for the manufacture of cements. Indian J Eng Mater S. 1996;3:41–4.Google Scholar
  16. 16.
    Zhang XW, Yang L, Zhang B. Utilization of phosphorus slag and fly ash for the preparation of ready-mixed mortar. Appl Mech Mater. 2013;423–426:987–92.CrossRefGoogle Scholar
  17. 17.
    Gao PW, Lu XL, Yang CX, Li XY, Shi NN, Jin SC. Microstructure and pore structure of concrete mixed with superfine phosphorous slag and superplasticizer. Constr Build Mater. 2008;22(5):837–40.CrossRefGoogle Scholar
  18. 18.
    Chen X, Fang KH, Yang HQ, Peng H. Hydration kinetics of phosphorus slag–cement paste. J Wuhan Univ Technol. 2011;26(1):142–6.CrossRefGoogle Scholar
  19. 19.
    Li DX, Shen JL, Mao LX, Wu XQ. The influence of admixtures on the properties of phosphorous slag cement. Cement Concr Res. 2000;30(7):1169–73.CrossRefGoogle Scholar
  20. 20.
    Allahverd A, Pilehva S, Mahinroosta M. Influence of curing conditions on the mechanical and physical properties of chemically-activated phosphorous slag cement. Powder Technol. 2016;288:132–9.CrossRefGoogle Scholar
  21. 21.
    Li D, Shen J, Mao L, Wu X. The influence of admixtures on the properties of phosphorous slag cement. Cement Concr Res. 2000;30(7):1169–73.CrossRefGoogle Scholar
  22. 22.
    Kalina L, Bílek V, Novotný R, Mončeková M, Másilko J, Koplík J. Effect of Na3PO4 on the hydration process of alkali-activated blast furnace slag. Materials. 2016;9(5):395.CrossRefGoogle Scholar
  23. 23.
    Dongxu L, Jinlin S, Lin C, Xuequan W. The influence of fast-setting/early-strength agent on high phosphorous slag content cement. Cement Concr Res. 2001;31(1):19–24.CrossRefGoogle Scholar
  24. 24.
    Lee WKW, van Deventer JSJ. Effects of anions on the formation of aluminosilicate gel in geopolymers. Ind Eng Chem Res. 2002;41(18):4550–8.CrossRefGoogle Scholar
  25. 25.
    Allahverdi A, Pilehvar S, Mahinroosta M. Influence of curing conditions on the mechanical and physical properties of chemically-activated phosphorous slag cement. Powder Technol. 2016;288:132–9.CrossRefGoogle Scholar
  26. 26.
    Shi C, Qian J. High performance cementing materials from industrial slags—a review. Resour Conserv Recycl. 2000;29(3):195–207.CrossRefGoogle Scholar
  27. 27.
    Dakhane A, Tweedley S, Kailas S, Marzke R, Neithalath N. Mechanical and microstructural characterization of alkali sulfate activated high volume fly ash binders. Mater Des. 2017;122:236–46.CrossRefGoogle Scholar
  28. 28.
    Ng S, Justnes H. Influence of plasticizers on the rheology and early heat of hydration of blended cements with high content of fly ash. Cem Concr Compos. 2016;65:41–54.CrossRefGoogle Scholar
  29. 29.
    Thongsanitgarn P, Wongkeo W, Chaipanich A, Poon CS. Heat of hydration of Portland high-calcium fly ash cement incorporating limestone powder: effect of limestone particle size. Constr Build Mater. 2014;66:410–7.CrossRefGoogle Scholar
  30. 30.
    Liu SH, Kong YI, Wang L. A comparison of hydration properties of cement—low quality fly ash binder and cement—limestone powder binder. J Therm Anal Calorim. 2014;116(2):937–43.CrossRefGoogle Scholar

Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2017

Authors and Affiliations

  1. 1.Department of Civil EngineeringTsinghua UniversityBeijingChina

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