Journal of Thermal Analysis and Calorimetry

, Volume 130, Issue 2, pp 799–812 | Cite as

Effect of functional groups on the thermal degradation of phosphorus- and phosphorus/nitrogen-containing functional polymers

  • Rasim Alosmanov
  • Karol Wolski
  • Georg Matuschek
  • Abel Magerramov
  • Abdulsaid Azizov
  • Ralf Zimmermann
  • Elvin Aliyev
  • Szczepan Zapotoczny
Article
First Online:
Received:
Accepted:

Abstract

In the present study the thermal behavior of phosphorus- and phosphorus/nitrogen-containing functional polymers was studied. The polymers were synthesized via oxidative chlorophosphorylation reaction of butadiene rubber and were subsequently subjected to hydrolysis, aminolysis and/or alcoholysis in order to introduce appropriate functionalities. The successful modifications of the polymer and presences of the respective functional groups were determined using Fourier transform infrared spectroscopy. It was found that the product of hydrolysis of the modified butadiene rubber contains acidic groups in its structure while the products of aminolysis and alcoholysis contain both acidic and amine and/or alcohol-derived moieties. The kinetic analyses of the thermal decomposition reaction were evaluated using thermogravimetric analysis and subsequently Friedman and Ozawa–Flynn–Wall methods revealing three-stage degradation process. Calorimetric measurements were performed for the studied polymers, and mass spectrometric analyses were used to identify the decomposition products for phosphorus-containing polymer. The overall results allowed to reveal the influence of the attached phosphorus- and phosphorus/nitrogen-containing functional groups to the thermal degradation of the cross-linked polymers.

Keywords

Butadiene rubber Functional groups Thermal behavior Kinetic parameters of degradation 
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Notes

Acknowledgements

The authors would like to thank German Academic Exchange Service (DAAD) and German Research Center for Environmental Health, Helmholtz Zentrum München, Joint Mass Spectrometry Centre, Cooperation Group “Comprehensive Molecular Analytics” for financial support and work statement of the research. Part of research was done in the group of prof. Szczepan Zapotoczny (Faculty of Chemistry, Jagiellonian University) under Erasmus Mundus Electra program. Authors would like to thank Gülcin Abbaszade as well.

Supplementary material

10973_2017_6464_MOESM1_ESM.docx (1.1 mb)
Supplementary material 1 (DOCX 1100 kb)

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Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2017

Authors and Affiliations

  • Rasim Alosmanov
    • 1
    • 2
  • Karol Wolski
    • 2
  • Georg Matuschek
    • 3
  • Abel Magerramov
    • 1
  • Abdulsaid Azizov
    • 1
  • Ralf Zimmermann
    • 3
    • 4
  • Elvin Aliyev
    • 1
    • 5
  • Szczepan Zapotoczny
    • 2
  1. 1.Chemistry DepartmentBaku State UniversityBakuAzerbaijan
  2. 2.Faculty of ChemistryJagiellonian UniversityKrakowPoland
  3. 3.Joint Mass Spectrometry Centre, Cooperation Group “Comprehensive Molecular Analytics”German Research Center for Environmental Health (GmbH), Helmholtz Zentrum MünchenOberschleißheimGermany
  4. 4.Joint Mass Spectrometry Centre, Institute of ChemistryUniversity of RostockRostockGermany
  5. 5.Institute of Polymer ResearchHelmholtz-Zentrum GeesthachtGeesthachtGermany

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