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Journal of Thermal Analysis and Calorimetry

, Volume 128, Issue 2, pp 745–754 | Cite as

Influence of thermal stability on dielectric properties of SiO2–K2O–CaO–MgO glasses

  • Praveen Jha
  • S. S. Danewalia
  • K. Singh
Article

Abstract

Compositions of 55SiO2–10K2O–(35–x)CaO–xMgO are prepared by melt and quench technique. Thermal parameters of the as-prepared glasses are studied using the differential thermal analyzer under non-isothermal conditions. Kissinger, Augis–Bennett and Lasocka models are employed to investigate the kinetics of crystallization and thermal stability of these glasses. Based on this, it is concluded that CM-15 glass exhibits highest thermal stability. Raman spectroscopy is used to reveal the structural units of the glasses. Dielectric properties are observed through impedance spectroscopy. All the glasses are phase separated. The ratio of CaO/MgO influences the thermal stability, which leads to affect the dielectric properties. The highest dielectric permittivity is observed ~22 at room temperature and 100 Hz for CM-15 glass, where CaO/MgO ratio is ~1.33.

Keywords

Crystallization Nucleation Lasocka Kissinger Thermodynamic stability 

Notes

Acknowledgements

Authors are very thankful to Dr. Gurbinder Kaur and Dr. Paramjyot Kumar Jha for their valuable discussions and suggestions during preparation of the manuscript.

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Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2016

Authors and Affiliations

  1. 1.School of Physics and Materials ScienceThapar UniversityPatialaIndia

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