Journal of Thermal Analysis and Calorimetry

, Volume 122, Issue 1, pp 315–322 | Cite as

Interactions between inorganic pigments and rabbit skin glue in reference paint reconstructions

  • Lisa Ghezzi
  • Celia Duce
  • Luca Bernazzani
  • Emilia Bramanti
  • Maria Perla Colombini
  • Maria Rosaria Tiné
  • Ilaria Bonaduce
Article

Abstract

The thermal degradation of rabbit skin glue, a collagen-based proteinaceous material used as a paint binder in paintings, was investigated in this paper. Paint reconstructions of the glue on its own or mixed with azurite (Cu3(CO3)2(OH)2), calcium carbonate (CaCO3), hematite (Fe2O3·nH2O) and red lead (Pb3O4) were analysed using a thermoanalytical approach. This method enabled us to investigate the interactions between the glue and pigments before and after artificial indoor light ageing. The study was carried out using differential scanning calorimetry, thermogravimetry and thermogravimetry/FTIR analysis already successfully employed to characterize the paint binders. The results highlighted that all the inorganic pigments interact with rabbit skin glue, thus decreasing the thermal stability of the binder. Light ageing further decreased the thermal stability of pigmented paint replicas, suggesting a moderate increase in the rate of the degradation.

Keywords

Rabbit skin glue Azurite Calcium carbonate Hematite and red lead Thermogravimetric analysis Differential scanning calorimetry 

Notes

Acknowledgements

This work was supported by PRIN 2008 (Project No. 2008XXAMZT) and PRIN 2010/2011 (Project No. 2010329WPF) funding from the Italian Ministry of University and Research.

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Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2015

Authors and Affiliations

  • Lisa Ghezzi
    • 1
  • Celia Duce
    • 1
  • Luca Bernazzani
    • 1
  • Emilia Bramanti
    • 2
  • Maria Perla Colombini
    • 1
  • Maria Rosaria Tiné
    • 1
  • Ilaria Bonaduce
    • 1
  1. 1.Dipartimento di Chimica e Chimica IndustrialeUniversity of PisaPisaItaly
  2. 2.Istituto di Chimica dei Composti Organo Metallici-ICCOM- UOS PisaNational Research Council of Italy, C.N.R.PisaItaly

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