Luminescence properties of M2TiO4:Eu3+, Li+ (M:Mg, Ca) and MgAl2O4:RE3+ (RE3+:Ho3+, Sm3+, and Yb3+)
- 282 Downloads
- 4 Citations
Abstract
In this study, we aimed to prepare perovskite-related and Eu3+-activated Mg2TiO4, Ca2TiO4 and (Mg, Ca)2TiO4 doped with Eu3+, Li+, and spinel-oxide-type MgAl2O4 doped with Ho3+, Sm3+, and Yb3+ through a solid-state reaction method under open atmosphere. The thermal behaviors of the samples were characterized by DTA/TG. The phase properties were characterized by X-ray diffraction and the effects of rare-earth ions (Eu3+, Ho3+, Sm3+, and Yb3+) on the luminescence properties of the hosts were investigated using a photoluminescence spectrometer. The morphology and elemental analysis of each sample were determined by SEM/EDX.
Keywords
Spinel structure Solid-state reaction method Open atmosphere Luminescence Rare-earth ionsNotes
Acknowledgements
The authors would like to thank Karamanoglu Mehmetbey University, Scientific Research Projects Commission (BAP), project number: 48-M-12.
References
- 1.Çırçır E, Ozpozan Kalaycioglu N. Host-sensitized phosphorescence of Mn4+, Pr3+, 4+ and Nd3+ in MgAl2Si2O8. Mat Res Bul. 2012;47(5):1138–41.CrossRefGoogle Scholar
- 2.Karacaoglu E, Karasu B. The effects of re-firing process under oxidizing atmosphere and temperatures on the properties of strontium aluminate phosphors. Mat Res Bul. 2013;48:3702–6.CrossRefGoogle Scholar
- 3.Skvortsova V, Mironova-Ulmane N, Ulmanis U. Neutron irradiation influence on magnesium aluminium spinel inversion. Nucl Instr Meth Phy Res B. 2002;191:256–60.CrossRefGoogle Scholar
- 4.Tan TTY. Rare Earth Nanotechnology. Singapore: Pan Stanford Publishing Pte. Ltd; 2012. p. 208–9.CrossRefGoogle Scholar
- 5.Kumar S, Kumar R, Koo BH, Choi H, Kim DU, Lee CG. Structural and electrical properties of Mg2TiO4. J Ceram Soc Jpn. 2009;117(1365):689–92.CrossRefGoogle Scholar
- 6.Lu Z, Le Z, Xu NC, Wang LX, Zhang QT. Luminescent properties of Eu3+ doped layered perovskite structure M2TiO4 (M = Ca, Sr, Ba) red-emitting phosphors. spectrosc Spectr An. 2012;32(10):2632–6.Google Scholar
- 7.Hosseini SM. Structural, electronic and optical properties of spinel MgAl2O4 oxide. Phys Status Sol (b). 2008;245(12):2800–7.CrossRefGoogle Scholar
- 8.Zhou L, Zhang L, Xu NC, Wang LX, Zhang QT. Luminescent Properties of Eu3+ doped layered perovskite structure M2TiO4 (M = Ca, Sr, Ba) red-emitting phosphors. Spectrosc and Spectr An. 2012;32(10):2632–6.Google Scholar
- 9.Lee EY, Kim YJ. Optical excitation and emission spectra of YNb4O:Eu3+. J Korean Electrochem Soc. 2009;12(3):234–8.CrossRefGoogle Scholar
- 10.Loan TT, Ha LH, Long NN. Optical transition of Eu3+ in Mg(Al1-xEux)2O4. VNU J Sci Math-Phys. 2007;23:84–91.Google Scholar
- 11.Boyer JC, Vetrone F, Capobianco JA, Speghini A, Bettinelli M. Optical transitions and upconversion properties of Ho3+ doped ZnO–TeO2 glass. J App Phys. 2003;93:9460.CrossRefGoogle Scholar
- 12.Wang Z, Yin Y, Yuan D. Optical transitions in Ho3+-doped La3Ga5SiO14 crystals. J Alloys Compd. 2007;436:364–8.CrossRefGoogle Scholar
- 13.Ðordevic V, Nikolic MG, Antic Ž, Mitric M, Dramicanin MD. LaYO3:Sm3+ nanocrystalline phosphor: preparation and emission properties. Acta Phys Pol A. 2011;120:2.Google Scholar
- 14.Patra A, Reisfeld R, Minti H. Influence of aluminium oxide on intensities of Sm3+ and Pr3+ spectral transitions in sol–gel glasses. Mater Lett. 1998;37:325–9.CrossRefGoogle Scholar
- 15.Baur F, Katelnikovas A, Petry R, Pöttgen R, Jüstel T. A Novel Sm3 + Activated Orange Emitting Molybdate. Germany: Rare Earths Elem Conf; 2013.Google Scholar
- 16.Rudramadevi BH, Buddhudu S. Spectral and thermal analysis of Sm3+ and Dy3+:B2O3-BaO-LiF/AlF3 Glasses. Indian Pure App Phys. 2008;46:825–32.Google Scholar
- 17.Del Cacho VD, Kassab LRP, de Oliveira SL, Morimoto NI. Blue cooperative emission in Yb3+-doped GeO2–PbO glasses. Mater Res. 2006;9(N1):21–4.CrossRefGoogle Scholar