Journal of Thermal Analysis and Calorimetry

, Volume 115, Issue 1, pp 55–62 | Cite as

Pyrolysis kinetics and pathway of polysiloxane conversion to an amorphous SiOC ceramic

  • Xiujun Wang
  • Jiquan Wu
  • Yongming Li
  • Chuanjian Zhou
  • Caihong Xu


The pyrolytic conversion of vinyl-terminated poly[hydridomethylsiloxane-co-vinylmethylsiloxane] (PSO) into SiOC ceramic at various heating rates has been investigated by thermogravimetry coupled with mass spectrometry. Kinetic analysis on pyrolysis process of PSO has been conducted by peak-fitting method. The results show that all the experimental derivative thermogravimetric curves recorded at five different heating rates can be best fitted by four Gaussian functions. The activation energy for each peak was determined by an isoconversional method, and kinetic models for Peaks 1 and 2 were investigated on the basis of Master plots. The results show that Peak 1 was governed by R2-type mechanisms, while Peak 2 followed diffusion-type transport mechanisms. Plausible chemical pathways for the evolved gases within these peaks are also discussed. The release of a large amount of carbon-containing species was identified in the temperature ranges corresponding to Peak 2 and 4, which are associated with the mineralization and ceramization steps, respectively. The transition from mineralization to ceramization process occurs in the region of Peak 3, and is accompanied by the evolution of H2.


Polysiloxane Pyrolytic process Kinetic analysis Peak fitting 



The authors acknowledge the final supports from the National Science Foundation of China (50973114, 50973113), the Ministry of Science and Technology of China (2010CB934705, 2012CB933200) and the Chinese Academy of Sciences.


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Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2013

Authors and Affiliations

  • Xiujun Wang
    • 1
    • 2
  • Jiquan Wu
    • 1
    • 2
  • Yongming Li
    • 1
  • Chuanjian Zhou
    • 3
  • Caihong Xu
    • 1
  1. 1.Institute of ChemistryChinese Academy of SciencesBeijingChina
  2. 2.University of Chinese Academy of SciencesBeijingChina
  3. 3.Research Institute of Polymer MaterialsShandong UniversityJinanChina

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