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Journal of Thermal Analysis and Calorimetry

, Volume 113, Issue 3, pp 1421–1429 | Cite as

Thermal, spectral, magnetic and antimicrobial behaviour of new Ni(II), Cu(II) and Zn(II) complexes with a hexaazamacrocyclic ligand

  • Florentina Pătraşcu
  • Mihaela Badea
  • Maria Nicoleta Grecu
  • Nicolae Stanică
  • Luminiţa Măruţescu
  • Dana Marinescu
  • Cezar Spînu
  • Cristian Tigae
  • Rodica Olar
Article

Abstract

New species of type MLCl2·nH2O (M:Ni, n = 6; M:Cu, n = 1.5 and M:Zn, n = 1; L: 1,8-bis(3′-ketopyridil)-1,3,6,8,10,13-hexaazacyclotetradecane, ligand resulted by 1,2-diaminoethane, nicotinamide and formaldehyde template condensation) were synthesised. The compounds were characterised by chemical analysis, ESI–MS, IR, NMR, UV–Vis-NIR and EPR spectroscopy as well as magnetic data at room temperature. The modifications in the IR and NMR spectra are in accordance with the condensation process. Electronic spectra indicate that Ni(II) adopts an octahedral stereochemistry while the surrounding of Cu(II) is square-pyramidal. The proposed stereochemistry was furthermore confirmed by magnetic moments and EPR spectrum at room temperature. The water is eliminated in one or two steps, respectively, while the oxidative degradation of the ligand and chloride decomposition occur in two steps. The final residues consist of the most stable metallic oxides as X-ray powder diffraction indicates. The newly synthesised compounds were evaluated for their antimicrobial effect against different bacterial and fungal strains.

Keywords

Azamacrocyclic ligand Formaldehyde Nicotinamide One pot Thermal stability 

Notes

Acknowledgements

This paper was supported by the Sectorial Operational Programme Human Resources Development (SOP HRD), financed by the European Social Fund and by the Romanian Government under the contract number SOP HRD/107/1.5/S/82514. Support of the EU (ERDF) and Romanian Government that allowed the acquisition of the research infrastructure under POS-CCE O 2.2.1 project INFRANANOCHEM—Nr. 19/01.03.2009 is gratefully acknowledged.

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Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2013

Authors and Affiliations

  • Florentina Pătraşcu
    • 1
  • Mihaela Badea
    • 1
  • Maria Nicoleta Grecu
    • 2
  • Nicolae Stanică
    • 3
  • Luminiţa Măruţescu
    • 4
  • Dana Marinescu
    • 1
  • Cezar Spînu
    • 5
  • Cristian Tigae
    • 5
  • Rodica Olar
    • 1
  1. 1.Department of Inorganic Chemistry, Faculty of ChemistryUniversity of BucharestBucharestRomania
  2. 2.National Institute of Materials PhysicsMăgurele-IlfovRomania
  3. 3.Romanian Academy“Ilie Murgulescu” Physical Chemistry InstituteBucharestRomania
  4. 4.Department of Microbiology, Faculty of BiologyUniversity of BucharestBucharestRomania
  5. 5.Department of Chemistry, Faculty of Exact SciencesUniversity of CraiovaCraiovaRomania

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