Journal of Thermal Analysis and Calorimetry

, Volume 111, Issue 1, pp 535–542 | Cite as

TG–DSC–FTIR–MS study of gaseous compounds evolved during thermal decomposition of styrene-butadiene rubber

  • Antonyraj Arockiasamy
  • Hossein Toghiani
  • David Oglesby
  • M. F. Horstemeyer
  • J. L. Bouvard
  • Roger L. King
Article

Abstract

The thermal decomposition behavior of styrene-butadiene rubber was studied using a system equipped with thermogravimetric analysis, differential thermal analysis, Fourier transform infrared spectroscopy, and mass spectroscopy. Two different experiments were conducted. From these experiments, thermogravimetric analysis results indicated a mass loss of 58 % in the temperature range of ~290–480 °C and a mass loss of 39 % in the temperature range beyond 600 °C. Scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy confirmed the presence of oxides, even at 1,000 °C, accounting for the Zn, Mg, Al, Si, and Ca in the original sample.

Keywords

Thermal analytical techniques Styrene-butadiene rubber Compositional analysis 

Notes

Acknowledgements

This material is based upon work supported by the U.S. Army TACOM Life Cycle Command under Contract No. W56HZV-08-C-0236, through a subcontract with Mississippi State University, and was performed for the Simulation Based Reliability and Safety (SimBRS) research program. Any opinions, findings, conclusions, or recommendations expressed in this material are those of the author(s) and do not necessarily reflect the views of the U.S. Army TACOM Life Cycle Command. The authors would also like to acknowledge the support of the Center for Advanced Vehicular Systems (CAVS) at Mississippi State University (MSU).

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Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2012

Authors and Affiliations

  • Antonyraj Arockiasamy
    • 3
    • 1
  • Hossein Toghiani
    • 2
  • David Oglesby
    • 1
  • M. F. Horstemeyer
    • 1
  • J. L. Bouvard
    • 1
  • Roger L. King
    • 1
  1. 1.Center for Advanced Vehicular SystemsMississippi State UniversityStarkvilleUSA
  2. 2.Dave C. Swalm School of Chemical EngineeringMississippi State UniversityMississippi StateUSA
  3. 3.Environmental Health and SafetyThe University of Mississippi Medical CenterJacksonUSA

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