Journal of Thermal Analysis and Calorimetry

, Volume 110, Issue 1, pp 37–41 | Cite as

Dehydration investigations of a refractory concrete using DTA method

  • N. Obradović
  • A. Terzić
  • Lj. Pavlović
  • S. Filipović
  • V. Pavlović


The base mix refractory concrete is corundum-based, containing corundum as refractory aggregate and CAC as hydraulic binder, with a spinel as an additive. The authors investigated the dehydration reactions which occur from the moment when water is added (at the beginning of components mixing), to the moment when installed refractory concrete lining is put into the service. Sintering process kinetic of low-cement content refractory concrete was investigated by means of differential thermal analysis at four different heating rates (5, 10, 20, and 30 °C/min). Thus, temperature was increased from 20 to 1100 °C. It was noticed that first dehydration step occurs at lower temperatures, indicating at a desorption of physically adsorbed and interlayer water molecules. Second dehydration step, at higher temperatures is due to dehydroxylation of the lattices and decomposition of the interlayer anions.


Sintering kinetics DTA Refractory concrete 



The authors would like to thank Dr. Miodrag Mitrić for the XRD measurements. This study has been supported by Serbian Ministry of Science under projects 172057 and 45008 and by the Serbian Academy of Sciences and Arts under project F7.


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Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2011

Authors and Affiliations

  • N. Obradović
    • 1
  • A. Terzić
    • 2
  • Lj. Pavlović
    • 2
  • S. Filipović
    • 1
  • V. Pavlović
    • 1
  1. 1.Institute of Technical Sciences-SASABelgradeSerbia
  2. 2.Institute for Technology of Nuclear and Other Raw MaterialsBelgradeSerbia

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