Journal of Thermal Analysis and Calorimetry

, Volume 106, Issue 2, pp 399–405 | Cite as

Thermal analysis of hair treated with oxidative hair dye under influence of conditioners agents

  • Robson Miranda da Gama
  • Tatiana Santana Balogh
  • Simone França
  • Tânia Cristina Sá Dias
  • Valcinir Bedin
  • André Rolim Baby
  • Jivaldo do Rosário Matos
  • Maria Valéria Robles Velasco
Article
First Online:

Abstract

This research aimed the effect on Caucasian hair tresses treated with oxidative hair dye, either incorporated or not with conditioners agents, analyzed by Differential Scanning Calorimetry (DSC) and Thermogravimetric analysis (TG). The formulations of hair dyes were emulsions oil-in-water with light blond color containing or not the conditioners agents: silanetriol and panthenol; PEG-12 dimethicone; hydrolyzed silk, hydrolyzed milk protein, and lactose. Each dye (1.5 g) was applied in the hair tress (2.0 g/20.0 cm of length of Caucasian light-brown), previously treated, more 1.5 g of hydrogen peroxide 20 vol during 40 min. Evaluation of mass loss of the different hair sample demonstrates that these chemical hair treatments impair the hair fibers, reduced their moisture content with respect to the untreated hair. The incorporation of conditioners agents (silanetriol and panthenol; PEG-12 dimethicone; hydrolyzed silk, hydrolyzed milk protein, and lactose) in oxidative hair dyes types did not decrease the damage caused on the tresses by the coloring process quantified by TG/DTG. However, the DSC curves demonstrated those conditioners agents (silanetriol and panthenol; PEG-12 dimethicone) dislocated the beginning of the third event in 20 °C and they inhibited the presence of the fourth event, having characterized thermal protection to the hair.

Keywords

Oxidative hair dye Conditioners agents Hair properties Thermal analysis 
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Notes

Acknowledgements

The authors acknowledge CAPES (Coordenação de Aperfeiçoamento de Pessoal de Nível Superior) of the Brazilian Ministry of Education.

References

  1. 1.
    Longo VM, Monteiro VF, Pinheiro AS, Terci D, Vasconcelos JS, Paskocimas CA, Leite ER, Longo E, Varela JA. Charge density alterations in human hair fibers: an investigation using electrostatic force microscopy. Int J Cosmet Sci. 2006;28:95–101.CrossRefGoogle Scholar
  2. 2.
    Velasco MVR, Dias TCS, Freitas AZ, Vieira Junior ND, Pinto CASO, Kaneko TM, Baby AR. Hair fiber characteristics and methods to evaluate hair physical and mechanical properties. Braz J Pharm Sci. 2009;45:153–62.CrossRefGoogle Scholar
  3. 3.
    Zanh H. Progress report on keratin research. Int J Cosmet Sci. 2002;24:163–9.CrossRefGoogle Scholar
  4. 4.
    Schueller R, Romanowski P. Inside the hair: in advanced hair biology model. Cosmet Toilet. 2005;120:53–6.Google Scholar
  5. 5.
    Robbins CR, Crawford RJ. Cuticle damage and the tensile properties of human hair. J Soc Cosmet Chem. 1991;42:49–58.Google Scholar
  6. 6.
    Wagner RC, Kiyohara PK, Silveira M, Joekes I. Electron microscopic observation of human hair medulla. J Microsc. 2007;226:54–63.CrossRefGoogle Scholar
  7. 7.
    Harrison S, Sinclair R. Hair colouring, permanent styling and hair structure. J Cosmet Dermatolol. 2004;2:180–5.CrossRefGoogle Scholar
  8. 8.
    Pinheiro AS, Terci D, Gonçalves DAC, Pereira M, Oliveira PS, Alencastre J, Maia AC, Monteiro V, Longo E. Mecanismos de degradação da cor de cabelos tingidos: um novo modelo de proteção. Cosmet Toilet (Ed Port). 2002;14:68–77.Google Scholar
  9. 9.
    Gama RM, Balogh TS, França S, Dias TCS, Bedin V, Consiglieri VO, Kaneko TM, Baby AR, Velasco MVR. Evaluation of hair damage after treatments with light brown and light blond permanent dyes: hair protein loss determination. Braz J Pharm Sci. 2009;45(Suppl 1):24.Google Scholar
  10. 10.
    Dias TCS, Baby AR, Kaneko TM, Velasco MVR. Relaxing/straightening of afro-ethnic hair: historical overview. J Cosmet Dermatol. 2007;6:2–5.CrossRefGoogle Scholar
  11. 11.
    Oshimura E. Hair and amino acids. Cosmet Toilet. 2008;123:61–8.Google Scholar
  12. 12.
    Butler H. Poucher’s perfumes, cosmetics and soaps. 10th ed. Boston: Kluwer academic publishers; 2000. p. 255.Google Scholar
  13. 13.
    O’Lenick AJ, O’Lenick TG. Silicone compounds—new formulation possibilities. Cosmet Toilet. 2005;120:95–102.Google Scholar
  14. 14.
    Wendlandt WW. Thermal analysis. 3rd ed. New York: Wiley; 1986. p. 1.Google Scholar
  15. 15.
    Silva EC, Velasco-de-Paola MVR, Matos JR. Análise térmica aplicada à cosmetologia. Rev Bras Cien Farm. 2007;43:347–56.Google Scholar
  16. 16.
    Monteiro VF, Maciel AP, Longo E. Thermal analysis of Caucasian human hair. J Therm Anal Calorim. 2005;79:289–93.CrossRefGoogle Scholar
  17. 17.
    Barba C, Méndez S, Martí M, Coderch PL. Water content of hair and nails. Termochim Acta. 2009;494:136–40.CrossRefGoogle Scholar
  18. 18.
    Wortmann FJ, Springob C, Sendelbach G. Investigations of cosmetically treated human hair by differential scanning calorimetry in water. J Cosmet Sci. 2002;53:219–28.Google Scholar
  19. 19.
    Belleti KMS, Fererman IH, Mendes TRO, Piacekeski AD, Monteiro VF, Carreño NV, Valentini A, Leite ER, Longo E. Evaluation of hair fiber hydration by differential scanning calorimetry, gas chromatography and sensory analysis. J Cosmet Sci. 2003;54:527–35.Google Scholar
  20. 20.
    Cao J. Melting study of the α-form crystallites in human hair keratin by DSC. Termochim Acta. 1999;335:5–9.CrossRefGoogle Scholar
  21. 21.
    Wortmann FJ, Stapels M, Elliott R, Chandra L. The effect of water on the glass transition of human hair. Biopolymers. 2006;81:371–5.CrossRefGoogle Scholar

Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2011

Authors and Affiliations

  • Robson Miranda da Gama
    • 1
    • 2
  • Tatiana Santana Balogh
    • 1
  • Simone França
    • 1
  • Tânia Cristina Sá Dias
    • 1
  • Valcinir Bedin
    • 3
  • André Rolim Baby
    • 1
  • Jivaldo do Rosário Matos
    • 4
  • Maria Valéria Robles Velasco
    • 1
  1. 1.Laboratory of Cosmetology, School of Pharmaceutical SciencesUniversity of São PauloSão PauloBrazil
  2. 2.Laboratory School of Semi Industrial of Pharmacy (LESIFAR), School of PharmacyUniversity of Santo AmaroSão PauloBrazil
  3. 3.Healthy Skin Foundation and Hair and Skin Research and Treatment InstituteSão PauloBrazil
  4. 4.Laboratory of Thermal Analysis Ivo Giolito (LATIG), Chemistry InstituteUniversity of São PauloSão PauloBrazil

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