Journal of Thermal Analysis and Calorimetry

, Volume 102, Issue 2, pp 729–737 | Cite as

Microcalorimetric determination of effect of the antioxidant (Quercetin) on polymer/surfactant interactions

Article

Abstract

Isothermal titration calorimetry (ITC) and batch calorimetry techniques have been used to evaluate the effect of added antioxidant (Quercetin, QN) on the binding between a polymer/surfactant complex, namely the sodium salt of polystyrene sulfonate (PSS) and typical anionic surfactant sodium dodecylsulfate (SDS). An indirect isotherm approximation method and the Satake–Yang model have been used to evaluate the binding parameter (Ku), adsorption cooperativity (u), and the Gibbs free energy of cooperative and non-cooperative binding (ΔGC and ΔGN) from the ITC data. The enthalpy of dissolution of QN into various PSS/water and PSS/SDS/water solutions has been evaluated from batch calorimetry to study the energetics of the polymer/surfactant binding in the presence of QN.

Keywords

Isothermal titration calorimetry (ITC) Batch calorimetry Polymer/surfactant Antioxidant Quercetin 

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Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2010

Authors and Affiliations

  1. 1.Department of ChemistrySt Francis Xavier UniversityAntigonishCanada

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