Journal of Thermal Analysis and Calorimetry

, Volume 91, Issue 1, pp 189–193 | Cite as

Thermal decomposition kinetics of the synthetic complex Pb(1,4-BDC)·(DMF)(H2O)

  • J. Zhang
  • J. L. Zeng
  • Y. Y. Liu
  • L. X. Sun
  • F. Xu
  • W. S. You
  • Y. Sawada
Regular Papers Organics/Polymers
First Online:
Received:
Accepted:

Abstract

Pb(1,4-BDC)·(DMF)(H2O) (1,4-BDC=1,4-benzenedicarboxylate; DMF=dimethylformamide) has been synthesized and investigated by elemental analysis, FTIR spectroscopy, thermogravimetry (TG), derivative thermogravimetry (DTG). TG-DTG curves show that the thermal decomposition occurs in four stages and the corresponding apparent activation energies were calculated with the Ozawa-Flynn-Wall (OFW) and the Friedman methods. The most probable kinetic model function of the dehydration reaction of the compound has been estimated by the Coats-Redfern integral and the Achar-Bridly-Sharp differential methods in this study.

Keywords

apparent activation energy kinetic model TG-DTG thermal decomposition 
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Copyright information

© Springer Science+Business Media LLC 2007

Authors and Affiliations

  • J. Zhang
    • 1
    • 2
  • J. L. Zeng
    • 1
    • 2
  • Y. Y. Liu
    • 1
    • 2
  • L. X. Sun
    • 1
  • F. Xu
    • 1
  • W. S. You
    • 3
  • Y. Sawada
    • 4
  1. 1.Materials and Thermochemistry Laboratory, Dalian Institute of Chemical PhysicsChinese Academy of SciencesDalianP.R. China
  2. 2.Graduate School of the Chinese Academy of SciencesBeijingP.R. China
  3. 3.Fac. Chem. and Chem. Engn.Liaoning Nomal Univ.DalianP.R. China
  4. 4.Department of Nanochemistry, Faculty of EngineeringTokyo Polytechnic UniversityKanagawaJapan

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